Chemistry for Engineering Students
4th Edition
ISBN: 9781337398909
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Question
Chapter 4, Problem 4.62PAE
Interpretation Introduction
Interpretation:
To explain why oxygenated fuels increase the extent of combustion.
Concept introduction:
- The extent of reaction relates the total conversion of the reactants.
- Oxygen is required in combustion as well as a fuel.
- Incomplete combustion is typically obtained from low oxygen.
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The airbags that protect people in car crashes are inflated by the extremely rapid decomposition of sodium azide, which produces large volumes of nitrogen gas.
1. Write a balanced chemical equation, including physical state symbols, for the
decomposition of solid sodium azide (NaN,) into solid sodium and gaseous dinitrogen.
2. Suppose 71.0 L of dinitrogen gas are produced by this reaction, at a temperature of
16.0 °C and pressure of exactly 1 atm, Calculate the mass of sodium azide that must
have reacted. Round your answer to 3 significant digits.
Explanation
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1. When, a volume of 200 cm³ of Lithium hydroxide solution of concentration 1.00 mol/dm³
and 200 cm³ of Hydrochloric acid of concentration 100 mol/dm³ were mixed together in a
calorimeter the reaction was investigated to be exothermic.
a) Distinguish between endothermic and exothermic reactions.
b) Based on the information given above in question one (1), calculated the enthalpy
change per mol of water produced, if the heat capacity of the calorimeter was 76 J/K
and the temperature rise was 5.25 K. (State any assumptions made)
Chapter 4 Solutions
Chemistry for Engineering Students
Ch. 4 - Describe the chemical composition of gasoline.Ch. 4 - Write balanced chemical equations for the...Ch. 4 - Prob. 3COCh. 4 - Calculate the amounts of reactants needed in a...Ch. 4 - Prob. 5COCh. 4 - Prob. 6COCh. 4 - Prob. 7COCh. 4 - 4.1 List at least two factors that make it...Ch. 4 - 4.2 What is an alkane?Ch. 4 - 4.3 Explain the difference between complete and...
Ch. 4 - 4.4 Automobile exhaust often contains traces of...Ch. 4 - 4.5 Methane, ethane, and propane are also...Ch. 4 - 4.6 Use the web to research prices of gasoline at...Ch. 4 - For the following reactions, write the ratios that...Ch. 4 - 4.8 In an experiment carried out at very low...Ch. 4 - 4.9 Sulfur, S8, combines with oxygen at elevated...Ch. 4 - 4.10 How many moles of oxygen can be obtained by...Ch. 4 - 4.11 MTBE, C5H12O, is one of the additives that...Ch. 4 - 4.12 In petroleum refining, hydrocarbons are often...Ch. 4 - 4.13 For the following reactions, determine the...Ch. 4 - 4.14 The combustion of liquid chloroethylene,...Ch. 4 - 4.15 What mass of the unknown compound is formed...Ch. 4 - 4.16 Many metals react with halogens to give metal...Ch. 4 - 4.17 Phosgene is a highly toxic gas that has been...Ch. 4 - Prob. 4.18PAECh. 4 - 4.19 How many metric tons of carbon are required...Ch. 4 - 4.20 Assuming a charcoal briquette is composed...Ch. 4 - 4.21 Ammonium nitrate, NH4NO3, will decompose...Ch. 4 - 4.22 Generally, an excess of O2 is needed for the...Ch. 4 - 4.23 In the reaction of arsenic with bromine,...Ch. 4 - 4.24 Ammonia gas can be prepared by the reaction...Ch. 4 - 4.25 When octane is combusted with inadequate...Ch. 4 - 4.26 The equation for one of the reactions in the...Ch. 4 - 4.27 Copper reacts with sulfuric acid according to...Ch. 4 - 4.28 One of the steps in the manufacture of nitric...Ch. 4 - 4.29 When Al(OH)3 reacts with sulfuric acid, the...Ch. 4 - 4.30 Copper reacts with nitric acid via the...Ch. 4 - 4.31 How much HNO3 can be formed in the following...Ch. 4 - 4.32 Hydrogen and oxygen are reacted and the water...Ch. 4 - 4.33 Silicon carbide, an abrasive, is made by the...Ch. 4 - Prob. 4.34PAECh. 4 - Prob. 4.35PAECh. 4 - 4.36 Sometimes students in chemistry labs...Ch. 4 - 4.37 The theoretical yield and the actual yield...Ch. 4 - 4.38 A reaction that produced 4.8 mg of taxol, an...Ch. 4 - Methanol, CH3OH, is used in racing cars because it...Ch. 4 - 4.40 When iron and steam react at high...Ch. 4 - 4.41 The percentage yield of the following...Ch. 4 - 4.42 Sulfur hexafluoride is a very stable gas...Ch. 4 - 4.43 Magnesium nitride forms in a side reaction...Ch. 4 - 4.44 Industrial production of hydrogen gas uses...Ch. 4 - 4.45 If 21 g of H2S is mixed with 38 g of O2 and...Ch. 4 - 4.46 A mixture of 10.0 g of NO and 14.0 g of NO2...Ch. 4 - 4.47 Silicon carbide is, an abrasive used in the...Ch. 4 - 4.48 Elemental phosphorous is used in the...Ch. 4 - 4.49 Small quantities of hydrogen gas can be...Ch. 4 - Prob. 4.50PAECh. 4 - 4.51 What is the role of an indicator in a...Ch. 4 - 4.52 What volume of 0.812 M HCl, in milliliters,...Ch. 4 - Prob. 4.53PAECh. 4 - Prob. 4.54PAECh. 4 - Hydrazine, N2H4, is a weak base and can react with...Ch. 4 - Prob. 4.56PAECh. 4 - Prob. 4.57PAECh. 4 - Prob. 4.58PAECh. 4 - 4.59 Aluminum dissolves in HCI according to the...Ch. 4 - 4.60 Why are fuel additives used?Ch. 4 - 4.61 What is actually measured by the octane...Ch. 4 - Prob. 4.62PAECh. 4 - Prob. 4.63PAECh. 4 - 4.64 Using the web, find information about the...Ch. 4 - 4.65 Using the web, find out how lead “poisons”...Ch. 4 - 4.66 If 3.4 mol Al is mixed with 1.5 times as many...Ch. 4 - 4.67 If 8.4 moles of disilane, Si2H6, are combined...Ch. 4 - 4.68 The pictures below show a molecular-scale...Ch. 4 - 4.69 The pictures below show a molecular-scale...Ch. 4 - 4.70 The particulate scale drawing shown depicts...Ch. 4 - 4.71 The particulate scale drawing shown depict...Ch. 4 - 4.72 The picture shown depicts the species present...Ch. 4 - Prob. 4.73PAECh. 4 - Prob. 4.74PAECh. 4 - Prob. 4.75PAECh. 4 - Prob. 4.76PAECh. 4 - You have 0.954 g of an unknown acid, H2A, which...Ch. 4 - Prob. 4.78PAECh. 4 - 4.79 Phosphoric add (H3PO4) is important in the...Ch. 4 - 4.80 The reaction shown below is used to destroy...Ch. 4 - Prob. 4.81PAECh. 4 - One way of determining blood alcohol levels is by...Ch. 4 - Prob. 4.83PAECh. 4 - 4.84 Aluminum chloride (AlCl3) is used as a...Ch. 4 - 4.85 In the cold vulcanization of rubber, disulfur...Ch. 4 - Prob. 4.86PAECh. 4 - Prob. 4.87PAECh. 4 - 4.88 A quality control technician needs to...Ch. 4 - Prob. 4.89PAECh. 4 - 4.90 Iron metal can be refined (rom the mineral...Ch. 4 - Prob. 4.91PAECh. 4 - Prob. 4.92PAECh. 4 - 4.93 A mixture of methane (CH4) and propane (C3H8)...Ch. 4 - Prob. 4.94PAECh. 4 - Prob. 4.95PAECh. 4 - Prob. 4.96PAECh. 4 - Prob. 4.97PAECh. 4 - Prob. 4.98PAECh. 4 - Prob. 4.99PAECh. 4 - Prob. 4.100PAECh. 4 - Prob. 4.101PAECh. 4 - Prob. 4.102PAECh. 4 - Prob. 4.103PAECh. 4 - 4.104 When 2.750 g of the oxide Pb3O4 is heated to...Ch. 4 - Prob. 4.105PAECh. 4 - 4.106 An ore sample with a mass of 670 kg contains...Ch. 4 - 4.107 Existing stockpiles of the refrigerant...Ch. 4 - 4.108 Elemental analysis is sometimes carried out...Ch. 4 - Prob. 4.109PAECh. 4 - 4.110 Write the balanced chemical equation lot the...Ch. 4 - 4.111 Aluminum metal reacts with sulfuric acid to...Ch. 4 - 4.112 A metallurgical firm wishes to dispose of...
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