CHEMISTRY IN FOCUS W/ OWL (LL)>IP<
6th Edition
ISBN: 9781337306317
Author: Tro
Publisher: CENGAGE L
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Textbook Question
Chapter 4, Problem 45E
The U.S. Food and Drug Administration recommends that you consume less than 2.4 g of sodium per day. How much sodium chloride can you consume and still be within the FDA limit?
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4. (2 pts) Draw the structure of the major component of the Limonene isolated. Explain how
you confirmed the structure.
5. (2 pts) Draw the fragment corresponding to the base peak in the Mass spectrum of
Limonene.
6. (1 pts) Predict the 1H NMR spectral data of R-Limonene.
Proton NMR: 5.3 pon multiplet (H Ring
Part VI.
Ca H 10 O is the molecular formula of compound Tom and gives the
in the table below. Give a possible structure for compound Tom.
13C
Signals summarized
C1
C2
C3
C4
C5
C6
C7
13C shift (ppm)
23.5
27.0
33.0
35.8
127
162
205
DEPT-90
+
DEPT-135
+
+
2. Using the following data to calculate the value of AvapH o of water at 298K. AvapH o of water at
373K is 40.7 kJ/mol; molar heat capacity of liquid water at constant pressure is 75.2J mol-1 K-1 and
molar heat capacity of water vapor at constant pressure is 33.6 J mol-1 K-1.
Chapter 4 Solutions
CHEMISTRY IN FOCUS W/ OWL (LL)>IP<
Ch. 4 - Interpreting Chemical Formulas Determine the...Ch. 4 - Prob. 4.2YTCh. 4 - Prob. 4.3YTCh. 4 - Prob. 4.4YTCh. 4 - Calculating Formula Mass Calculate the formula...Ch. 4 - Using the Molar Mass to Find the Number of...Ch. 4 - Prob. 4.7YTCh. 4 - Chemical Formulas as Conversion Factors (Mass to...Ch. 4 - Prob. 4.9YTCh. 4 - Prob. 4.10YT
Ch. 4 - Using Chemical Equation Coefficients as Conversion...Ch. 4 - Classify each compound as ionic or molecular. LiBr...Ch. 4 - Prob. 2SCCh. 4 - What is wrong with the following compound names?...Ch. 4 - Prob. 4SCCh. 4 - The coefficients in the chemical reaction 2A+3B...Ch. 4 - Prob. 6SCCh. 4 - In Chapter 3, we learned that all matter is...Ch. 4 - Name some common everyday compounds.Ch. 4 - Prob. 3ECh. 4 - Prob. 4ECh. 4 - Prob. 5ECh. 4 - Prob. 6ECh. 4 - Prob. 7ECh. 4 - What is the difference between a common name for a...Ch. 4 - Prob. 9ECh. 4 - Prob. 10ECh. 4 - Prob. 11ECh. 4 - Prob. 12ECh. 4 - Prob. 13ECh. 4 - Prob. 14ECh. 4 - Why must chemical equations be balanced?Ch. 4 - Explain the numerical relationships inherent in a...Ch. 4 - Chemical Formulas Determine the number of each...Ch. 4 - Determine the number of each type of atom in each...Ch. 4 - Classify each compound as ionic or molecular:...Ch. 4 - Classify each compound as ionic or molecular:...Ch. 4 - Prob. 21ECh. 4 - Prob. 22ECh. 4 - Prob. 23ECh. 4 - Prob. 24ECh. 4 - Prob. 25ECh. 4 - Prob. 26ECh. 4 - Give a chemical formula for each compound: a....Ch. 4 - Give a chemical formula for each compound: a....Ch. 4 - Prob. 29ECh. 4 - Calculate the formula mass for each compound:...Ch. 4 - The formula mass of an unknown compound containing...Ch. 4 - The formula mass of an unknown compound containing...Ch. 4 - Mole Conversions How many moles of CO2 are...Ch. 4 - What is the mass of 2.55 moles of water?Ch. 4 - The active ingredient in aspirin is...Ch. 4 - The active ingredient in Tylenol is acetaminophen...Ch. 4 - Calculate the number of water molecules (H2O) in...Ch. 4 - Acetone (C3H6O) is used as nail polish remover. If...Ch. 4 - Determine the number of sugar molecules in 7.5 g...Ch. 4 - One drop of water from a medicine dropper has a...Ch. 4 - How many chlorine atoms are in each of the...Ch. 4 - How many hydrogen atoms are in each of the...Ch. 4 - Prob. 43ECh. 4 - Find the number of moles of nitrogen in each of...Ch. 4 - The U.S. Food and Drug Administration recommends...Ch. 4 - The scientific consensus indicates that adults...Ch. 4 - Determine the mass of iron (in kilograms)...Ch. 4 - Determine the mass of carbon (in kilograms)...Ch. 4 - Balancing Chemical Equations Balance each chemical...Ch. 4 - Prob. 50ECh. 4 - Prob. 51ECh. 4 - Prob. 52ECh. 4 - Water can be synthesized according to the...Ch. 4 - Billions of pounds of urea, CO(NH2)2, are produced...Ch. 4 - Prob. 55ECh. 4 - Prob. 56ECh. 4 - Prob. 57ECh. 4 - Prob. 58ECh. 4 - Prob. 61ECh. 4 - For each space-filling molecular model, write a...Ch. 4 - For each chemical reaction, draw in the missing...
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Part VII. Below are the 'HNMR 13 3 C-NMR, COSY 2D- NMR, and HSQC 20-NMR (Similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H13 O. Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum ли 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 f1 (ppm)arrow_forward3. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-pentene. expanded structure: Condensed structure: Skeletal formula: 4. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-methyl-3-heptene. expanded structure: Condensed structure: Skeletal formula: following structurearrow_forwardPart IV. Propose a plausible Structure w/ the following descriptions: a) A 5-carbon hydrocarbon w/ a single peak in its proton decoupled the DEPT-135 Spectrum shows a negative peak C-NMR spectrum where b) what cyclohexane dione isomer gives the largest no. Of 13C NMR signals? c) C5H120 (5-carbon alcohol) w/ most deshielded carbon absent in any of its DEPT Spectivaarrow_forward
- 13C NMR is good for: a) determining the molecular weight of the compound b) identifying certain functional groups. c) determining the carbon skeleton, for example methyl vs ethyl vs propyl groups d) determining how many different kinds of carbon are in the moleculearrow_forward6 D 2. (1 pt) Limonene can be isolated by performing steam distillation of orange peel. Could you have performed this experiment using hexane instead of water? Explain. 3. (2 pts) Using GCMS results, analyze and discuss the purity of the Limonene obtained from the steam distillation of orange peel.arrow_forwardPart III. Arrange the following carbons (in blue) in order of increasing chemical shift. HO B NH 2 A CIarrow_forward
- 6. Choose the compound that will produce the spectrum below and assign the signals as carbonyl, aryl, or alkyl. 100 ō (ppm) 50 0 7. 200 150 Assign all of the protons on the spectrum below. 8. A B 4 E C 3 ō (ppm) 2 1 0 Choose the compound that will produce the spectrum below and assign the signals to the corresponding protons. OH 6 OH 3 2 1 0 4 ō (ppm)arrow_forwardIn the Thermo Fisher application note about wine analysis (Lesson 3), the following chromatogram was collected of nine components of wine. If peak 3 has a retention time of 3.15 minutes and a peak width of 0.070 minutes, and peak 4 has a retention time of 3.24 minutes and a peak width of 0.075 minutes, what is the resolution factor between the two peaks? [Hint: it will help to review Lesson 2 for this question.] MAU 300 200 T 34 5 100- 1 2 CO 6 7 8 9 0 2.4 2.6 2.8 3.0 3.2 3.4 3.6 3.8 4.0 4.2 4.4 4.6 4.8 5.0 5.2 Minutes 3.22 0.62 1.04 O 1.24arrow_forwardThe diagram shows two metals, A and B, which melt at 1000°C and 1400°C. State the weight percentage of the primary constituent (grains of C) that would be obtained by solidifying a 20% alloy of B. 1000°C a+L L+C 900°С 12 α a+C 45 1200 C L+y 140096 C+Y a+ß 800°C 700°C C+B 96 92 a+B 0 10 20 30 40 50 60 70 80 90 100 A % peso B Barrow_forward
- 8. Choose the compound that will produce the spectrum below and assign the signals to the corresponding protons. 2 4 3 ō (ppm) OH 4 6 6 СОН 2 1 0arrow_forward7. Assign all of the protons on the spectrum below. A B 2 C E 2 1 3 6 4 3 2 1 0arrow_forwarde. If (3R,4R)-3,4-dichloro-2,5-dimethylhexane and (3R,4S)-3,4-dichloro-2,5-dimethylhexane are in a solution at the same concentration, would this solution be expected to rotate plane polarized light (that is, be optically active)? Please provide your reasoning for your answer. [If you read this problem carefully, you will not need to draw out the structures to arrive at your answer...]arrow_forward
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