
Organic Chemistry 3rd.ed. Klein Evaluation/desk Copy
3rd Edition
ISBN: 9781119320524
Author: Klein
Publisher: WILEY
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Chapter 4, Problem 44PP
(a)
Interpretation Introduction
Interpretation:
The compound is needed to found which has more heat of combustion value between the given set of compounds.
Concept introduction:
- Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.
- Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:
- Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.
(b)
Interpretation Introduction
Interpretation:
The compound is needed to found which has more heat of combustion value between the given set of compounds.
Concept introduction:
- Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.
- Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:
- Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.
(c)
Interpretation Introduction
Interpretation:
The compound is needed to found which has more heat of combustion value between the given set of compounds.
Concept introduction:
- Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.
- Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:
- Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.
(d)
Interpretation Introduction
Interpretation:
The compound is needed to found which has more heat of combustion value between the given set of compounds.
Concept introduction:
- Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.
- Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:
- Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.
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Chapter 4 Solutions
Organic Chemistry 3rd.ed. Klein Evaluation/desk Copy
Ch. 4.2 - Prob. 1LTSCh. 4.2 - Prob. 1PTSCh. 4.2 - Prob. 2PTSCh. 4.2 - Prob. 3ATSCh. 4.2 - Prob. 2LTSCh. 4.2 - Prob. 4PTSCh. 4.2 - Prob. 5ATSCh. 4.2 - Prob. 3LTSCh. 4.2 - Prob. 6PTSCh. 4.2 - Prob. 7ATS
Ch. 4.2 - Prob. 4LTSCh. 4.2 - Prob. 8PTSCh. 4.2 - Prob. 9PTSCh. 4.2 - Prob. 10ATSCh. 4.2 - Prob. 5LTSCh. 4.2 - Prob. 11PTSCh. 4.2 - Prob. 12PTSCh. 4.2 - Prob. 13ATSCh. 4.3 - Prob. 6LTSCh. 4.3 - Prob. 14PTSCh. 4.3 - Prob. 15ATSCh. 4.6 - Prob. 7LTSCh. 4.6 - Prob. 16PTSCh. 4.6 - Prob. 17ATSCh. 4.7 - Prob. 18CCCh. 4.8 - Prob. 8LTSCh. 4.8 - Prob. 19PTSCh. 4.8 - Prob. 20ATSCh. 4.11 - Prob. 9LTSCh. 4.11 - Prob. 21PTSCh. 4.11 - Prob. 22ATSCh. 4.11 - Prob. 10LTSCh. 4.11 - Prob. 23PTSCh. 4.11 - Prob. 24ATSCh. 4.12 - Prob. 11LTSCh. 4.12 - Prob. 25PTSCh. 4.12 - Prob. 26ATSCh. 4.12 - Prob. 27CCCh. 4.13 - Prob. 12LTSCh. 4.13 - Prob. 28PTSCh. 4.13 - Prob. 29ATSCh. 4.13 - Prob. 13LTSCh. 4.13 - Prob. 30PTSCh. 4.13 - Prob. 31ATSCh. 4.13 - Prob. 32ATSCh. 4.14 - Prob. 33CCCh. 4.14 - Prob. 34CCCh. 4.14 - Prob. 35CCCh. 4 - Prob. 36PPCh. 4 - Prob. 37PPCh. 4 - Prob. 38PPCh. 4 - Prob. 39PPCh. 4 - Prob. 40PPCh. 4 - Prob. 41PPCh. 4 - Prob. 42PPCh. 4 - Prob. 43PPCh. 4 - Prob. 44PPCh. 4 - Prob. 45PPCh. 4 - Prob. 46PPCh. 4 - Prob. 47PPCh. 4 - Prob. 48PPCh. 4 - Prob. 49PPCh. 4 - Prob. 50PPCh. 4 - Prob. 51PPCh. 4 - Prob. 52PPCh. 4 - Prob. 53PPCh. 4 - Prob. 54PPCh. 4 - Prob. 55PPCh. 4 - Prob. 56PPCh. 4 - Prob. 57PPCh. 4 - Prob. 58PPCh. 4 - Prob. 59PPCh. 4 - Prob. 60PPCh. 4 - Prob. 61IPCh. 4 - Prob. 62IPCh. 4 - Prob. 64IPCh. 4 - Prob. 65IPCh. 4 - Prob. 66IPCh. 4 - Prob. 67IPCh. 4 - Prob. 68IPCh. 4 - Prob. 69IPCh. 4 - Prob. 70IPCh. 4 -
All of the following are representations of...Ch. 4 - Prob. 72IPCh. 4 -
Which of the following is expected to have the...Ch. 4 - Prob. 74IPCh. 4 - Prob. 75CPCh. 4 -
The all-trans-1,2,3,4,5,6-hexaethylcyclohexane...Ch. 4 -
Compounds 1 and 2 were prepared, and the...
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