Organic Chemistry
Organic Chemistry
4th Edition
ISBN: 9780073402772
Author: Janice G. Smith
Publisher: MCG
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Chapter 4, Problem 4.38P
Interpretation Introduction

(a)

Interpretation: The structure of five constitutional isomers with molecular formula C4H8 has to be drawn.

Concept introduction: Isomers are the compounds having same molecular formula but different structures. Constitutional isomers are the isomers have different connectivity of atoms. The degree of unsaturation in a compound having molecular formula CaHbNcOd is expressed as follows:

Degree of unsaturation =a+1+cb2

Where, a = number of carbon atoms

b = number of hydrogen atoms

c = number of nitrogen atoms

Interpretation Introduction

(b)

Interpretation: The structure of nine constitutional isomers with molecular formula C7H16 has to be drawn.

Concept introduction: Isomers are the compounds having same molecular formula but different structures. Constitutional isomers are the isomers have different connectivity of atoms. The degree of unsaturation in a compound having molecular formula CaHbNcOd is expressed as follows:

Degree of unsaturation =a+1+cb2

Where, a = number of carbon atoms

b = number of hydrogen atoms

c = number of nitrogen atoms

Interpretation Introduction

(c)

Interpretation: The structure of twelve constitutional isomers containing a ring with molecular formula C6H12 has to be drawn.

Concept introduction: Isomers are the compounds having same molecular formula but different structures. Constitutional isomers are the isomers have different connectivity of atoms. The degree of unsaturation in a compound having molecular formula CaHbNcOd is expressed as follows:

Degree of unsaturation =a+1+cb2

Where, a = number of carbon atoms

b = number of hydrogen atoms

c = number of nitrogen atoms

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Draw the structure of all compounds that fit the following descriptions. a. five constitutional isomers having the molecular formula C4H8 b. nine constitutional isomers having the molecular formula C7H16 c. twelve constitutional isomers having the molecular formula C6H12 and containing one ring
Draw the structure of a molecule that fi ts each description: a. a 2 ° alcohol of molecular formula C 6H 14O b. an ether with molecular formula C 6H 14O that has a methyl group bonded to oxygen c. a 3 ° alkyl halide with molecular formula C 5H 11Br
Provide the two isomers of compound A. Please provide the IUPAC name for each. 1st isomer: has quarternary, secondary, and primary carbons 2nd isomer: has secondary and primary carbons

Chapter 4 Solutions

Organic Chemistry

Ch. 4 - Problem 4.9 Give the structure corresponding to...Ch. 4 - Prob. 4.12PCh. 4 - Give the IUPAC name for each compound.Ch. 4 - Give the structure corresponding to each IUPAC...Ch. 4 - Arrange the following compounds in order of...Ch. 4 - Problem 4.14 Draw the staggered and eclipsed...Ch. 4 - Prob. 4.17PCh. 4 - a.Draw the three staggered and three eclipsed...Ch. 4 - Problem 4.19 Consider rotation around the...Ch. 4 - Calculate the destabilization present in each...Ch. 4 - Problem 4.21 Classify the ring carbons as up or...Ch. 4 - Draw a second chair conformation for each...Ch. 4 - Prob. 4.23PCh. 4 - Problem 4.25 Draw the structure for each compound...Ch. 4 - For cis-1, 3-diethylcyclobutane, draw a a...Ch. 4 - Prob. 4.26PCh. 4 - Problem 4.28 Consider . Draw structures f or the...Ch. 4 - Problem 4.29 Draw a chair conformation of...Ch. 4 - Prob. 4.29PCh. 4 - Draw the products of each combustion reaction.Ch. 4 - Explain why beeswax is insoluble in H2O, slightly...Ch. 4 - Prob. 4.32PCh. 4 - Name each alkane using the ball-and-stick model,...Ch. 4 - Consider the substituted cyclohexane shown in the...Ch. 4 - Prob. 4.35PCh. 4 - 3.31 For each alkane: (a) classify each carbon...Ch. 4 - Prob. 4.37PCh. 4 - Prob. 4.38PCh. 4 - Give the IUPAC name for each compound. a. h.k....Ch. 4 - 4.39 Give the structure and IUPAC name for each of...Ch. 4 - 4.40 Draw the structure corresponding to each...Ch. 4 - Prob. 4.42PCh. 4 - Prob. 4.43PCh. 4 - 4.42 Give the IUPAC name for each compound. a....Ch. 4 - Prob. 4.45PCh. 4 - Prob. 4.46PCh. 4 - 4.45 Which conformation in each pair is higher in...Ch. 4 - Considering rotation around the bond highlighted...Ch. 4 - Prob. 4.49PCh. 4 - Prob. 4.50PCh. 4 - 4.49 Label the sites of torsional and steric...Ch. 4 - Prob. 4.52PCh. 4 - 4.51 The eclipsed conformation of is less...Ch. 4 - (a) Draw the anti and gauche conformations for...Ch. 4 - For each compound drawn below: a.Label each OH,Br...Ch. 4 - Draw the two possible chair conformations for...Ch. 4 - For each compound drawn below: a. Draw...Ch. 4 - 4.56 Convert each of the following structures into...Ch. 4 - Prob. 4.59PCh. 4 - Prob. 4.60PCh. 4 - Classify each pair of compounds as constitutional...Ch. 4 - Prob. 4.62PCh. 4 - Prob. 4.63PCh. 4 - 4.62 Draw the three constitutional isomers having...Ch. 4 - Prob. 4.65PCh. 4 - Prob. 4.66PCh. 4 - 4.65 Hydrocarbons like benzene are metabolized in...Ch. 4 - Which of the following compounds are lipids?Ch. 4 - Prob. 4.69PCh. 4 - Prob. 4.70PCh. 4 - Cyclopropane and cyclobutane have similar strain...Ch. 4 - Prob. 4.72PCh. 4 - Haloethanes (CH3CH2X,X=Cl,Br,I) have similar...Ch. 4 - Prob. 4.74PCh. 4 - Prob. 4.75PCh. 4 - Consider the tricyclic structure B (a) Label each...Ch. 4 - Read Appendix B on naming branched alkyl...Ch. 4 - Read Appendix B on naming bicyclic compounds. Then...
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