Organic Chemistry
Organic Chemistry
4th Edition
ISBN: 9780073402772
Author: Janice G. Smith
Publisher: MCG
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Chapter 4, Problem 4.10P

Give the IUPAC name for each compound.

a. ( CH 3 ) 3 CCH 2 CH ( CH 2 CH 3 ) 2

b. CH 3 ( CH 2 ) 3 CH ( CH 2 CH 2 CH 3 ) CH ( CH 3 ) 2

c.Chapter 4, Problem 4.10P, Give the IUPAC name for each compound. a. (CH3)3CCH2CH(CH2CH3)2 b. CH3(CH2)3CH(CH2CH2CH3)CH(CH3)2 c. , example  1

d.Chapter 4, Problem 4.10P, Give the IUPAC name for each compound. a. (CH3)3CCH2CH(CH2CH3)2 b. CH3(CH2)3CH(CH2CH2CH3)CH(CH3)2 c. , example  2

Expert Solution
Check Mark
Interpretation Introduction

(a)

Interpretation: The IUPAC name of the given compound is to be stated.

Concept introduction: The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

1. First identify the longest carbon chain.

2. The next step is to identify the groups attached to the longest chain.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

4. Use prefix di, tri, tetra if same type of substituent is present.

5. Name the substituents in alphabetical order.

Answer to Problem 4.10P

The IUPAC name of the given compound is 4-ethyl-2, 2-dimethylhexane.

Explanation of Solution

The given compound is (CH3)3CCH2CH(CH2CH3)2. The skeletal structure of the given compound is,

Organic Chemistry, Chapter 4, Problem 4.10P , additional homework tip  1

Figure 1

One should follow the given four steps to give the IUPAC name of a compound.

The first step is naming of longest parent chain.

Organic Chemistry, Chapter 4, Problem 4.10P , additional homework tip  2

Figure 2

The second step is numbering of chain.

Organic Chemistry, Chapter 4, Problem 4.10P , additional homework tip  3

Figure 3

The third step is naming and numbering of substituents.

Organic Chemistry, Chapter 4, Problem 4.10P , additional homework tip  4

Figure 4

The fourth step is combining of all parts.

Substituentsnameandnumbers+Parent+Suffix4-ethyl-2, 2-dimethyl+hex+ane(Alphabeticalorder:'e'forethyl,then'm'formethyl)6C'sanalkane

Thus, the IUPAC name of the given compound is 4-ethyl-2, 2-dimethylhexane.

Conclusion

The IUPAC name of the given compound is 4-ethyl-2, 2-dimethylhexane.

Expert Solution
Check Mark
Interpretation Introduction

(b)

Interpretation: The IUPAC name of the given compound is to be stated.

Concept introduction: The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

1. First identify the longest carbon chain.

2. The next step is to identify the groups attached to the longest chain.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

4. Use prefix di, tri, tetra if same type of substituent is present.

5. Name the substituents in alphabetical order.

Answer to Problem 4.10P

The IUPAC name of the given compound is 4-isopropyloctane.

Explanation of Solution

The given compound is CH3(CH2)3CH(CH2CH2CH3)CH(CH3)2. The skeletal structure of the given compound is,

Organic Chemistry, Chapter 4, Problem 4.10P , additional homework tip  5

Figure 9

One should follow the given four steps to give the IUPAC name of a compound.

The first step is naming of longest parent chain.

Organic Chemistry, Chapter 4, Problem 4.10P , additional homework tip  6

Figure 10

The second step is numbering of chain.

Organic Chemistry, Chapter 4, Problem 4.10P , additional homework tip  7

Figure 11

The third step is naming and numbering of substituents.

Organic Chemistry, Chapter 4, Problem 4.10P , additional homework tip  8

Figure 12

The fourth step is combining of all parts.

Substituentsnameandnumbers+Parent+Suffix4-isopropyl+oct+ane8C'sanalkane

Thus, the IUPAC name of the given compound is 4-isopropyloctane.

Conclusion

The IUPAC name of the given compound is 4-isopropyloctane.

Expert Solution
Check Mark
Interpretation Introduction

(c)

Interpretation: The IUPAC name of the given compound is to be stated.

Concept introduction: The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

1. First identify the longest carbon chain.

2. The next step is to identify the groups attached to the longest chain.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

4. Use prefix di, tri, tetra if same type of substituent is present.

5. Name the substituents in alphabetical order.

Answer to Problem 4.10P

The IUPAC name of the given compound is 3-ethyl-2, 5-dimethylheptane.

Explanation of Solution

The given compound is,

Organic Chemistry, Chapter 4, Problem 4.10P , additional homework tip  9

Figure 5

One should follow the given four steps to give the IUPAC name of a compound.

The first step is naming of longest parent chain.

Organic Chemistry, Chapter 4, Problem 4.10P , additional homework tip  10

Figure 6

The second step is numbering of chain.

Organic Chemistry, Chapter 4, Problem 4.10P , additional homework tip  11

Figure 7

The third step is naming and numbering of substituents.

Organic Chemistry, Chapter 4, Problem 4.10P , additional homework tip  12

Figure 8

The fourth step is combining of all parts.

Substituentsnameandnumbers+Parent+Suffix3-ethyl-2, 5-dimethyl+hept+ane(Alphabeticalorder:'e'forethyl,then'm'formethyl)7C'sanalkane

Thus, the IUPAC name of the given compound is 3-ethyl-2, 5-dimethylheptane.

Conclusion

The IUPAC name of the given compound is 3-ethyl-2, 5-dimethylheptane.

Expert Solution
Check Mark
Interpretation Introduction

(d)

Interpretation: The IUPAC name of the given compound is to be stated.

Concept introduction: The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

1. First identify the longest carbon chain.

2. The next step is to identify the groups attached to the longest chain.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

4. Use prefix di, tri, tetra if same type of substituent is present.

5. Name the substituents in alphabetical order.

Answer to Problem 4.10P

The IUPAC name of the given compound is 5-sec-butyl-3-ethyl-2, 7-dimethyldecane.

Explanation of Solution

The given compound is,

Organic Chemistry, Chapter 4, Problem 4.10P , additional homework tip  13

Figure 13

One should follow the given four steps to give the IUPAC name of a compound.

The first step is naming of longest parent chain.

Organic Chemistry, Chapter 4, Problem 4.10P , additional homework tip  14

Figure 14

The second step is numbering of chain.

Organic Chemistry, Chapter 4, Problem 4.10P , additional homework tip  15

Figure 15

The third step is naming and numbering of substituents.

Organic Chemistry, Chapter 4, Problem 4.10P , additional homework tip  16

Figure 16

The fourth step is combining of all parts.

Substituentsnameandnumbers+Parent+Suffix5-sec-butyl-3-ethyl-2, 7-dimethyl+dec+ane(Alphabeticalorder:bforbutyl,then'e'forethyl,and'm'formethyl)10C'sanalkane

Thus, the IUPAC name of the given compound is 5-sec-butyl-3-ethyl-2, 7-dimethyldecane

Conclusion

The IUPAC name of the given compound is 5-sec-butyl-3-ethyl-2, 7-dimethyldecane.

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Chapter 4 Solutions

Organic Chemistry

Ch. 4 - Problem 4.9 Give the structure corresponding to...Ch. 4 - Prob. 4.12PCh. 4 - Give the IUPAC name for each compound.Ch. 4 - Give the structure corresponding to each IUPAC...Ch. 4 - Arrange the following compounds in order of...Ch. 4 - Problem 4.14 Draw the staggered and eclipsed...Ch. 4 - Prob. 4.17PCh. 4 - a.Draw the three staggered and three eclipsed...Ch. 4 - Problem 4.19 Consider rotation around the...Ch. 4 - Calculate the destabilization present in each...Ch. 4 - Problem 4.21 Classify the ring carbons as up or...Ch. 4 - Draw a second chair conformation for each...Ch. 4 - Prob. 4.23PCh. 4 - Problem 4.25 Draw the structure for each compound...Ch. 4 - For cis-1, 3-diethylcyclobutane, draw a a...Ch. 4 - Prob. 4.26PCh. 4 - Problem 4.28 Consider . Draw structures f or the...Ch. 4 - Problem 4.29 Draw a chair conformation of...Ch. 4 - Prob. 4.29PCh. 4 - Draw the products of each combustion reaction.Ch. 4 - Explain why beeswax is insoluble in H2O, slightly...Ch. 4 - Prob. 4.32PCh. 4 - Name each alkane using the ball-and-stick model,...Ch. 4 - Consider the substituted cyclohexane shown in the...Ch. 4 - Prob. 4.35PCh. 4 - 3.31 For each alkane: (a) classify each carbon...Ch. 4 - Prob. 4.37PCh. 4 - Prob. 4.38PCh. 4 - Give the IUPAC name for each compound. a. h.k....Ch. 4 - 4.39 Give the structure and IUPAC name for each of...Ch. 4 - 4.40 Draw the structure corresponding to each...Ch. 4 - Prob. 4.42PCh. 4 - Prob. 4.43PCh. 4 - 4.42 Give the IUPAC name for each compound. a....Ch. 4 - Prob. 4.45PCh. 4 - Prob. 4.46PCh. 4 - 4.45 Which conformation in each pair is higher in...Ch. 4 - Considering rotation around the bond highlighted...Ch. 4 - Prob. 4.49PCh. 4 - Prob. 4.50PCh. 4 - 4.49 Label the sites of torsional and steric...Ch. 4 - Prob. 4.52PCh. 4 - 4.51 The eclipsed conformation of is less...Ch. 4 - (a) Draw the anti and gauche conformations for...Ch. 4 - For each compound drawn below: a.Label each OH,Br...Ch. 4 - Draw the two possible chair conformations for...Ch. 4 - For each compound drawn below: a. Draw...Ch. 4 - 4.56 Convert each of the following structures into...Ch. 4 - Prob. 4.59PCh. 4 - Prob. 4.60PCh. 4 - Classify each pair of compounds as constitutional...Ch. 4 - Prob. 4.62PCh. 4 - Prob. 4.63PCh. 4 - 4.62 Draw the three constitutional isomers having...Ch. 4 - Prob. 4.65PCh. 4 - Prob. 4.66PCh. 4 - 4.65 Hydrocarbons like benzene are metabolized in...Ch. 4 - Which of the following compounds are lipids?Ch. 4 - Prob. 4.69PCh. 4 - Prob. 4.70PCh. 4 - Cyclopropane and cyclobutane have similar strain...Ch. 4 - Prob. 4.72PCh. 4 - Haloethanes (CH3CH2X,X=Cl,Br,I) have similar...Ch. 4 - Prob. 4.74PCh. 4 - Prob. 4.75PCh. 4 - Consider the tricyclic structure B (a) Label each...Ch. 4 - Read Appendix B on naming branched alkyl...Ch. 4 - Read Appendix B on naming bicyclic compounds. Then...
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