CHEMISTRY 1111 LAB MANUAL >C<
1st Edition
ISBN: 9781307092097
Author: Chang
Publisher: MCG/CREATE
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Textbook Question
Chapter 4, Problem 4.2QP
What is the difference between a nonelectrolyte and an electrolyte? Between a weak electrolyte and a strong electrolyte?
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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 4 Solutions
CHEMISTRY 1111 LAB MANUAL >C<
Ch. 4.1 - Prob. 1RCCh. 4.2 - Classify the following ionic compounds as soluble...Ch. 4.2 - Predict the precipitate produced by mixing an...Ch. 4.2 - Which of the diagrams (a)(c) accurately describes...Ch. 4.3 - Which of the diagrams (a)(c) best represents a...Ch. 4.3 - Classify each of the following species as a...Ch. 4.3 - Write a molecular equation, an ionic equation, and...Ch. 4.4 - Assign oxidation numbers to all the elements in...Ch. 4.4 - Prob. 6PECh. 4.4 - Which of the following combination reactions is...
Ch. 4.5 - Prob. 7PECh. 4.5 - Prob. 8PECh. 4.5 - Prob. 9PECh. 4.5 - Prob. 1RCCh. 4.6 - A sample of 0.3220 g of an ionic compound...Ch. 4.6 - Prob. 1RCCh. 4.7 - How many grams of KHP are needed to neutralize...Ch. 4.7 - Prob. 12PECh. 4.8 - Prob. 13PECh. 4.8 - If a solution of a reducing agent is titrated with...Ch. 4 - Define solute, solvent, and solution by describing...Ch. 4 - What is the difference between a nonelectrolyte...Ch. 4 - Describe hydration. What properties of water...Ch. 4 - What is the difference between the following...Ch. 4 - Water is an extremely weak electrolyte and...Ch. 4 - Sodium sulfate (Na2SO4) is a strong electrolyte....Ch. 4 - Prob. 4.7QPCh. 4 - Prob. 4.8QPCh. 4 - Identify each of the following substances as a...Ch. 4 - Identify each of the following substances as a...Ch. 4 - The passage of electricity through an electrolyte...Ch. 4 - Predict and explain which of the following systems...Ch. 4 - You are given a water-soluble compound X. Describe...Ch. 4 - Explain why a solution of HCl in benzene does not...Ch. 4 - What is the difference between an ionic equation...Ch. 4 - What is the advantage of writing net ionic...Ch. 4 - Two aqueous solutions of AgNO3 and NaCl are mixed....Ch. 4 - Two aqueous solutions of KOH and MgCl2 are mixed....Ch. 4 - Characterize the following compounds as soluble or...Ch. 4 - Characterize the following compounds as soluble or...Ch. 4 - Write ionic and net ionic equations for the...Ch. 4 - Write ionic and net ionic equations for the...Ch. 4 - Which of the following processes will likely...Ch. 4 - Prob. 4.24QPCh. 4 - List the general properties of acids and bases.Ch. 4 - Give Arrheniuss and Brnsteds definitions of an...Ch. 4 - Give an example of a monoprotic acid, a diprotic...Ch. 4 - What are the characteristics of an acid-base...Ch. 4 - What factors qualify a compound as a salt? Specify...Ch. 4 - Prob. 4.30QPCh. 4 - Prob. 4.31QPCh. 4 - Identify each of the following species as a...Ch. 4 - Balance the following equations and write the...Ch. 4 - Balance the following equations and write the...Ch. 4 - Prob. 4.35QPCh. 4 - True or false: All combustion reactions are redox...Ch. 4 - Prob. 4.37QPCh. 4 - Prob. 4.38QPCh. 4 - How is the activity series organized? How is it...Ch. 4 - Use the following reaction to define redox...Ch. 4 - Prob. 4.41QPCh. 4 - What is the requirement for an element to undergo...Ch. 4 - For the complete redox reactions given here, (i)...Ch. 4 - Prob. 4.44QPCh. 4 - Arrange the following species in order of...Ch. 4 - Phosphorus forms many oxoacids. Indicate the...Ch. 4 - Give the oxidation number of the underlined atoms...Ch. 4 - Give the oxidation number for the following...Ch. 4 - Give oxidation number for the underlined atoms in...Ch. 4 - Give the oxidation number of the underlined atoms...Ch. 4 - Nitric acid is a strong oxidizing agent. State...Ch. 4 - Which of the following metals can react with...Ch. 4 - On the basis of oxidation number considerations,...Ch. 4 - Predict the outcome of the reactions represented...Ch. 4 - Classify the following redox reactions. (a)...Ch. 4 - Classify the following redox reactions. (a)...Ch. 4 - Which of the following are redox processes?...Ch. 4 - Of the following, which is most likely to be the...Ch. 4 - Write the equation for calculating molarity. Why...Ch. 4 - Describe the steps involved in preparing a...Ch. 4 - Calculate the mass of KI in grams required to...Ch. 4 - Describe how you would prepare 250 mL of a 0.707 M...Ch. 4 - Prob. 4.63QPCh. 4 - Prob. 4.64QPCh. 4 - Calculate the molarity of each of the following...Ch. 4 - Calculate the molarity of each of the following...Ch. 4 - Calculate the volume in milliliters of a solution...Ch. 4 - Prob. 4.68QPCh. 4 - What volume of 0.416 M Mg(NO3)2 should be added to...Ch. 4 - Barium hydroxide, often used to titrate weak...Ch. 4 - Describe the basic steps involved in diluting a...Ch. 4 - Write the equation that enables us to calculate...Ch. 4 - Describe how to prepare 1.00 L of 0.646 M HCl...Ch. 4 - Water is added to 25.0 mL of a 0.866 M KNO3...Ch. 4 - How would you prepare 60.0 mL of 0.200 M HNO3 from...Ch. 4 - You have 505 mL of a 0.125 M HCl solution and you...Ch. 4 - A 35.2-mL, 1.66 M KMnO4 solution is mixed with...Ch. 4 - A 46.2-mL, 0.568 M calcium nitrate [Ca(NO3)2]...Ch. 4 - Describe the basic steps involved in gravimetric...Ch. 4 - Distilled water must be used in the gravimetric...Ch. 4 - If 30.0 mL of 0.150 M CaCl2 is added to 15.0 mL of...Ch. 4 - A sample of 0.6760 g of an unknown compound...Ch. 4 - How many grams of NaCl are required to precipitate...Ch. 4 - The concentration of sulfate in water can be...Ch. 4 - Describe the basic steps involved in an acid-base...Ch. 4 - How does an acid-base indicator work?Ch. 4 - Prob. 4.87QPCh. 4 - Would the volume of a 0.10 M NaOH solution needed...Ch. 4 - A quantity of 18.68 mL of a KOH solution is needed...Ch. 4 - Calculate the concentration (in molarity) of a...Ch. 4 - Calculate the volume in milliliters of a 1.420 M...Ch. 4 - What volume of a 0.500 M HCl solution is needed to...Ch. 4 - What are the similarities and differences between...Ch. 4 - Explain why potassium permanganate (KMnO4) and...Ch. 4 - Iron(II) can be oxidized by an acidic K2Cr2O7...Ch. 4 - The SO2 present in air is mainly responsible for...Ch. 4 - Prob. 4.97QPCh. 4 - The concentration of a hydrogen peroxide solution...Ch. 4 - Oxalic acid (H2C2O4) is present in many plants and...Ch. 4 - Prob. 4.100QPCh. 4 - Iodate ion, IO3, oxidizes SO32 in acidic solution....Ch. 4 - Calcium oxalate (CaC2O4), the main component of...Ch. 4 - Prob. 4.103QPCh. 4 - Prob. 4.104QPCh. 4 - Prob. 4.105QPCh. 4 - A 5.00 102 mL sample of 2.00 M HCl solution is...Ch. 4 - Shown are two aqueous solutions containing various...Ch. 4 - Shown are two aqueous solutions containing various...Ch. 4 - Calculate the volume of a 0.156 M CuSO4 solution...Ch. 4 - Prob. 4.110QPCh. 4 - A 3.664-g sample of a monoprotic acid was...Ch. 4 - Prob. 4.112QPCh. 4 - A 15.00-mL solution of potassium nitrate (KNO3)...Ch. 4 - When a 2.50-g zinc strip was placed in a AgNO3...Ch. 4 - Calculate the mass of the precipitate formed when...Ch. 4 - Calculate the concentration of the acid (or base)...Ch. 4 - (a) Describe a preparation for magnesium hydroxide...Ch. 4 - A 1.00-g sample of a metal X (that is known to...Ch. 4 - Prob. 4.119QPCh. 4 - The molecular formula of malonic acid is C3H4O4....Ch. 4 - Prob. 4.121QPCh. 4 - A 60.0-mL 0.513 M glucose (C6H12O6) solution is...Ch. 4 - An ionic compound X is only slightly soluble in...Ch. 4 - Prob. 4.124QPCh. 4 - Prob. 4.125QPCh. 4 - Prob. 4.126QPCh. 4 - The molar mass of a certain metal carbonate, MCO3,...Ch. 4 - Prob. 4.128QPCh. 4 - You are given a soluble compound of unknown...Ch. 4 - Prob. 4.130QPCh. 4 - Prob. 4.131QPCh. 4 - Prob. 4.132QPCh. 4 - Prob. 4.133QPCh. 4 - Prob. 4.134QPCh. 4 - Prob. 4.135QPCh. 4 - Prob. 4.136QPCh. 4 - Describe in each case how you would separate the...Ch. 4 - Prob. 4.138QPCh. 4 - Prob. 4.139QPCh. 4 - A 0.8870-g sample of a mixture of NaCl and KCl is...Ch. 4 - Prob. 4.141QPCh. 4 - Prob. 4.142QPCh. 4 - Prob. 4.143QPCh. 4 - A useful application of oxalic acid is the removal...Ch. 4 - Prob. 4.145QPCh. 4 - A 0.9157-g mixture of CaBr2 and NaBr is dissolved...Ch. 4 - Prob. 4.147QPCh. 4 - A 325-mL sample of solution contains 25.3 g of...Ch. 4 - Prob. 4.149QPCh. 4 - Prob. 4.150QPCh. 4 - Prob. 4.151QPCh. 4 - Prob. 4.152QPCh. 4 - Prob. 4.153QPCh. 4 - Prob. 4.154QPCh. 4 - Prob. 4.155QPCh. 4 - Prob. 4.156QPCh. 4 - Prob. 4.157QPCh. 4 - Prob. 4.158QPCh. 4 - Prob. 4.159QPCh. 4 - Prob. 4.160QPCh. 4 - The following cycle of copper experiment is...Ch. 4 - A quantity of 25.0 mL of a solution containing...Ch. 4 - Prob. 4.163QPCh. 4 - Prob. 4.165QPCh. 4 - Prob. 4.166QPCh. 4 - Prob. 4.167QPCh. 4 - Many proteins contain metal ions for structural...Ch. 4 - Prob. 4.170IMECh. 4 - Prob. 4.171IMECh. 4 - Prob. 4.172IMECh. 4 - Muriatic acid, a commercial-grade hydrochloric...Ch. 4 - Because acid-base and precipitation reactions...
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- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
- • Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forwardNonearrow_forward
- Draw the curved-arrow mechanism with the drawings of the molecules, not just abbreviations. -NO₂ Sn, HCl (aq) E D H (CH3CO)₂O -NH2 CH3arrow_forwardWhat is/are the product(s) of the following reaction? Select all that apply. * HI A B C OD OH A B OH D Carrow_forwardIn the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forward
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