Concept explainers
(a)
Interpretation:
The Haworth projection (including with dash-wedge notation) for the given line structure of a disubstituted cyclohexane is to be drawn.
Concept introduction:
In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane.
(b)
Interpretation:
The Haworth projection (including with dash-wedge notation) for the given line structure of a disubstituted cyclohexane is to be drawn.
Concept introduction:
In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane.
(c)
Interpretation:
The line structure (including with dash-wedge notation) for the given Haworth projection of a disubstituted cyclohexane is to be drawn.
Concept introduction:
In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane. To draw the line structure from its Haworth projection, view the molecule either from the top of the plane or from the bottom of the plane.
(d)
Interpretation:
The line structure (including with dash-wedge notation) for the given Haworth projection of a disubstituted cyclohexane is to be drawn.
Concept introduction:
In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane. To draw the line structure from its Haworth projection, view the molecule either from the top of the plane or from the bottom of the plane.

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Chapter 4 Solutions
ORGANIC CHEMISTRY PRINCIPLES & MECHANISM
- Could you please explain whether my thinking is correct or incorrect regarding how I solved it? Please point out any mistakes in detail, with illustrations if needed.arrow_forwardWhat are the most proper reagents to achieve these products? سد 1. 2. OH ○ 1. BrMgC6H6; 2. H+ ○ 1. BrMgCH2CH2CH2CH2CH3; 2. H+ O 1. CH3CH2CHO; 2. H+ O 1. BrMgCH2CH3; 2. H+arrow_forwardProvide the IUPAC (systematic) name only for the following compound. Dashes, commas, and spaces must be correct. Harrow_forward
- Please use the nernst equation to genereate the Ion Selective Electrode Analysis standard curve within my excel spread sheet. Nernst Equation: E = Eo + m (ln a) Link: https://mnscu-my.sharepoint.com/:x:/g/personal/vi2163ss_go_minnstate_edu/EaREe1-PfGNKq1Cbink6kkYB5lBy05hEaE3mbGPUb22S6w?rtime=zQaSX3xY3Ugarrow_forwarda) b) c) H NaOH heat, dehydration + KOH heat, dehydration NaOH + (CH3)3CCHO heat, dehydration Pharrow_forwardshow mechanismarrow_forward
- Please draw by handarrow_forward3. Predict the major product and give a mechanism for the following reactions: (CH3)3COH/H₂SO4 a) b) NC CH₂O c) LOCH, (CH3)3COH/H2SO4 H,SO -OHarrow_forwardIndicate if the aldehyde shown reacts with the provided nucleophiles in acid or base conditions. a NaBH4 be Li eli -NH2 P(Ph3) f KCN g OH excess h CH3OH i NaCHCCH3arrow_forward
- Predict the major products of the following organic reaction: + A ? Some important notes: • Draw the major product, or products, of the reaction in the drawing area below. • If there aren't any products, because no reaction will take place, check the box below the drawing area instead. • Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers. Explanation Check Click and drag to start drawing a structure. C © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Centearrow_forwardPolar solutes are most likely to dissolve into _____, and _____ are most likely to dissolve into nonpolar solvents. A. nonpolar solutes; polar solvents B. nonpolar solvents; polar solvents C. polar solvents; nonpolar solutes D. polar solutes; nonpolar solventsarrow_forwardDeducing the Peactants Can the molecule on the right-hand side of this organic reaction be made in good yield from no more than two reactants, in one step, by moderately heating the reactants? ? Δ If your answer is yes, then draw the reactant or reactants in the drawing area below. You can draw the reactants in any arrangement you like. If your answer is no, check the box under the drawing area instead. Explanation Check Click and drag to start drawing a structure. © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center Xarrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
