(a) Interpretation: For the given pair of molecules, it is to be determined whether they are constitutional isomers. Concept introduction: Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Question

(2 pts) What do you expect to happen in a Na2O crystal if a Cl− ion replaces one of the O2−ions in the lattice?

Answer 1

Question

Chapter 4, Problem 4.17P

Interpretation Introduction

(a)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(b)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(c)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(d)

Interpretation:

For the given pair of molecules, whether they are constitutional isomers is to be determined.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(e)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(f)

Interpretation:

For the given pair of molecules, whether they are constitutional isomers is to be determined.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(g)

Interpretation:

For the given pair of molecules, whether they are constitutional isomers is to be determined.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

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(2 pts) What do you expect to happen in a Na2O crystal if a Cl− ion replaces one of the O2−ions in the lattice?

(2 pts) WSe2 is an ionic compound semiconductor that can be made to be p-type or n-type.What must happen to the chemical composition for it to be p-type? What must happen tothe chemical composition for it to be n-type?

8. (2 pts) Silicon semiconductors have a bandgap of 1.11 eV. What is the longest photon wavelength that can promote an electron from the valence band to the conduction band in a silicon-based photovoltaic solar cell? Show all work. E = hv = hc/λ h = 6.626 x 10-34 Js c = 3.00 x 108 m/s 1 eV 1.602 x 10-19 J

Answer 2

Question

Chapter 4, Problem 4.17P

Interpretation Introduction

(a)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(b)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(c)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(d)

Interpretation:

For the given pair of molecules, whether they are constitutional isomers is to be determined.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(e)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(f)

Interpretation:

For the given pair of molecules, whether they are constitutional isomers is to be determined.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(g)

Interpretation:

For the given pair of molecules, whether they are constitutional isomers is to be determined.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

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Answer 3

Question

Chapter 4, Problem 4.17P

Interpretation Introduction

(a)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(b)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(c)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(d)

Interpretation:

For the given pair of molecules, whether they are constitutional isomers is to be determined.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(e)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(f)

Interpretation:

For the given pair of molecules, whether they are constitutional isomers is to be determined.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(g)

Interpretation:

For the given pair of molecules, whether they are constitutional isomers is to be determined.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

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Answer 4

Question

Chapter 4, Problem 4.17P

Interpretation Introduction

(a)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(b)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(c)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(d)

Interpretation:

For the given pair of molecules, whether they are constitutional isomers is to be determined.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(e)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(f)

Interpretation:

For the given pair of molecules, whether they are constitutional isomers is to be determined.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(g)

Interpretation:

For the given pair of molecules, whether they are constitutional isomers is to be determined.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

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Answer 5

Chapter 4, Problem 4.17P

Interpretation Introduction

(a)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(b)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(c)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(d)

Interpretation:

For the given pair of molecules, whether they are constitutional isomers is to be determined.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(e)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(f)

Interpretation:

For the given pair of molecules, whether they are constitutional isomers is to be determined.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Interpretation Introduction

(g)

Interpretation:

For the given pair of molecules, whether they are constitutional isomers is to be determined.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Answer 6

Chapter 4, Problem 4.17P

Interpretation Introduction

(a)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Answer 7

Chapter 4, Problem 4.17P

Interpretation Introduction

(a)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Answer 8

Interpretation Introduction

(b)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Answer 9

Interpretation Introduction

(b)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Answer 10

Interpretation Introduction

(c)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Answer 11

Interpretation Introduction

(c)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Answer 12

Interpretation Introduction

(d)

Interpretation:

For the given pair of molecules, whether they are constitutional isomers is to be determined.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Answer 13

Interpretation Introduction

(d)

Interpretation:

For the given pair of molecules, whether they are constitutional isomers is to be determined.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Answer 14

Interpretation Introduction

(e)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Answer 15

Interpretation Introduction

(e)

Interpretation:

For the given pair of molecules, it is to be determined whether they are constitutional isomers.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Answer 16

Interpretation Introduction

(f)

Interpretation:

For the given pair of molecules, whether they are constitutional isomers is to be determined.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Answer 17

Interpretation Introduction

(f)

Interpretation:

For the given pair of molecules, whether they are constitutional isomers is to be determined.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Answer 18

Interpretation Introduction

(g)

Interpretation:

For the given pair of molecules, whether they are constitutional isomers is to be determined.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Answer 19

Interpretation Introduction

(g)

Interpretation:

For the given pair of molecules, whether they are constitutional isomers is to be determined.

Concept introduction:

Compounds having the same molecular formula and same bonding connectivity are called identical compounds. The compounds having the same molecular formula and connectivities but differing in spatial arrangement are stereoisomers. The compounds having same molecular formula but differing in their connectivity are constitutional isomers.

Answer 20

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Answer 31

Ch. 4 - Prob. 4.1P Ch. 4 - Prob. 4.2P Ch. 4 - Prob. 4.3P Ch. 4 - Prob. 4.4P Ch. 4 - Prob. 4.5P Ch. 4 - Prob. 4.6P Ch. 4 - Prob. 4.7P Ch. 4 - Prob. 4.8P Ch. 4 - Prob. 4.9P Ch. 4 - Prob. 4.10P

Solution Summary: The author explains that identical compounds have the same molecular formula and connectivities but differ in spatial arrangement. The following pair of molecules are constitutional isomers.

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Chapter 4 Solutions