The given half-reaction are to be balanced and the oxidation-reduction half-reactions out of the given equations are to be identified. Concept introduction: The oxidation state or number in a compound is the charge present on the individual atom if the all bonds are assumed to be ionic. The net charge present on a neutral compound is always zero. The charge present on the ionic compound is equal to the some of the charges of all the atoms present in that ionic compound. Oxidation is a process in which there is a loss of electron during a reaction. Reduction is a process in which there is a gain of electron during a reaction The reaction is balanced when the number of atoms and charge are balanced on the both side of the reaction. To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

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Answer 1

Question

Chapter 4, Problem 4.101QP

(a)

Interpretation Introduction

Interpretation: The given half-reaction are to be balanced and the oxidation-reduction half-reactions out of the given equations are to be identified.

Concept introduction: The oxidation state or number in a compound is the charge present on the individual atom if the all bonds are assumed to be ionic. The net charge present on a neutral compound is always zero. The charge present on the ionic compound is equal to the some of the charges of all the atoms present in that ionic compound.

Oxidation is a process in which there is a loss of electron during a reaction.

Reduction is a process in which there is a gain of electron during a reaction

The reaction is balanced when the number of atoms and charge are balanced on the both side of the reaction.

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

b)

Interpretation Introduction

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

(c)

Interpretation Introduction

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

(d)

Interpretation Introduction

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³

fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer

34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Answer 2

Question

Chapter 4, Problem 4.101QP

(a)

Interpretation Introduction

Interpretation: The given half-reaction are to be balanced and the oxidation-reduction half-reactions out of the given equations are to be identified.

Concept introduction: The oxidation state or number in a compound is the charge present on the individual atom if the all bonds are assumed to be ionic. The net charge present on a neutral compound is always zero. The charge present on the ionic compound is equal to the some of the charges of all the atoms present in that ionic compound.

Oxidation is a process in which there is a loss of electron during a reaction.

Reduction is a process in which there is a gain of electron during a reaction

The reaction is balanced when the number of atoms and charge are balanced on the both side of the reaction.

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

b)

Interpretation Introduction

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

(c)

Interpretation Introduction

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

(d)

Interpretation Introduction

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

Expert Solution & Answer

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Answer 3

Question

Chapter 4, Problem 4.101QP

(a)

Interpretation Introduction

Interpretation: The given half-reaction are to be balanced and the oxidation-reduction half-reactions out of the given equations are to be identified.

Concept introduction: The oxidation state or number in a compound is the charge present on the individual atom if the all bonds are assumed to be ionic. The net charge present on a neutral compound is always zero. The charge present on the ionic compound is equal to the some of the charges of all the atoms present in that ionic compound.

Oxidation is a process in which there is a loss of electron during a reaction.

Reduction is a process in which there is a gain of electron during a reaction

The reaction is balanced when the number of atoms and charge are balanced on the both side of the reaction.

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

b)

Interpretation Introduction

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

(c)

Interpretation Introduction

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

(d)

Interpretation Introduction

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

Expert Solution & Answer

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Answer 4

Question

Chapter 4, Problem 4.101QP

(a)

Interpretation Introduction

Interpretation: The given half-reaction are to be balanced and the oxidation-reduction half-reactions out of the given equations are to be identified.

Concept introduction: The oxidation state or number in a compound is the charge present on the individual atom if the all bonds are assumed to be ionic. The net charge present on a neutral compound is always zero. The charge present on the ionic compound is equal to the some of the charges of all the atoms present in that ionic compound.

Oxidation is a process in which there is a loss of electron during a reaction.

Reduction is a process in which there is a gain of electron during a reaction

The reaction is balanced when the number of atoms and charge are balanced on the both side of the reaction.

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

b)

Interpretation Introduction

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

(c)

Interpretation Introduction

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

(d)

Interpretation Introduction

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

Expert Solution & Answer

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Answer 5

Chapter 4, Problem 4.101QP

(a)

Interpretation Introduction

Interpretation: The given half-reaction are to be balanced and the oxidation-reduction half-reactions out of the given equations are to be identified.

Concept introduction: The oxidation state or number in a compound is the charge present on the individual atom if the all bonds are assumed to be ionic. The net charge present on a neutral compound is always zero. The charge present on the ionic compound is equal to the some of the charges of all the atoms present in that ionic compound.

Oxidation is a process in which there is a loss of electron during a reaction.

Reduction is a process in which there is a gain of electron during a reaction

The reaction is balanced when the number of atoms and charge are balanced on the both side of the reaction.

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

b)

Interpretation Introduction

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

(c)

Interpretation Introduction

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

(d)

Interpretation Introduction

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

Answer 6

Chapter 4, Problem 4.101QP

(a)

Interpretation Introduction

Interpretation: The given half-reaction are to be balanced and the oxidation-reduction half-reactions out of the given equations are to be identified.

Concept introduction: The oxidation state or number in a compound is the charge present on the individual atom if the all bonds are assumed to be ionic. The net charge present on a neutral compound is always zero. The charge present on the ionic compound is equal to the some of the charges of all the atoms present in that ionic compound.

Oxidation is a process in which there is a loss of electron during a reaction.

Reduction is a process in which there is a gain of electron during a reaction

The reaction is balanced when the number of atoms and charge are balanced on the both side of the reaction.

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

Answer 7

Chapter 4, Problem 4.101QP

(a)

Interpretation Introduction

Interpretation: The given half-reaction are to be balanced and the oxidation-reduction half-reactions out of the given equations are to be identified.

Concept introduction: The oxidation state or number in a compound is the charge present on the individual atom if the all bonds are assumed to be ionic. The net charge present on a neutral compound is always zero. The charge present on the ionic compound is equal to the some of the charges of all the atoms present in that ionic compound.

Oxidation is a process in which there is a loss of electron during a reaction.

Reduction is a process in which there is a gain of electron during a reaction

The reaction is balanced when the number of atoms and charge are balanced on the both side of the reaction.

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

Answer 8

b)

Interpretation Introduction

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

Answer 9

b)

Interpretation Introduction

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

Answer 10

(c)

Interpretation Introduction

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

Answer 11

(c)

Interpretation Introduction

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

Answer 12

(d)

Interpretation Introduction

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

Answer 13

(d)

Interpretation Introduction

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 4.2 - Prob. 1PE Ch. 4.2 - Prob. 2PE Ch. 4.2 - Prob. 3PE Ch. 4.2 - Prob. 4PE Ch. 4.3 - Prob. 5PE Ch. 4.3 - Prob. 6PE Ch. 4.5 - Prob. 7PE Ch. 4.5 - Prob. 8PE Ch. 4.6 - Prob. 9PE Ch. 4.6 - Prob. 10PE

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To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

To determine: The balanced reaction of the given half reaction and the identification of the oxidation-reduction half-reactions out of the given equation.

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