ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
10th Edition
ISBN: 9781260008562
Author: Carey
Publisher: MCG
expand_more
expand_more
format_list_bulleted
Question
Chapter 4, Problem 33P
Interpretation Introduction
Interpretation:
The structure(s) with which the absolute configuration of
Concept introduction:
An absolute configuration is the three-dimensional spatial arrangement of atoms or groups at the chirality center.
The absolute configuration at the chiral center is assigned on the basis of Cahn-Ingold-Prelog rules. The Cahn-Ingold-Prelog system ranks substituents at the chirality center in the order of decreasing
If this path is clockwise, the absolute configuration is R. If this path is counterclockwise, the absolute configuration is S.
In Fischer projections, the molecule is oriented so that the two vertical bonds at the chirality center are directed away from the viewer and the two horizontal bonds point toward the viewer.
When the connection between absolute configuration and sign of rotation is known, it is a common practice to incorporate both in the name of the compound.
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
Assign these spectrum
If I have 30% H2O2, indicate how to prepare a 6% H2O2 solution.
7)
8)
FCI II
-C-C-C=C-C
||
Br Br
||
-C=C-Br
-CEC-C-C-
10)
11)
F Br
i
OH
مله
12)
Br
i
13)
14)
15)
CH3CHFCHFC=CH
C(OH)Br2CHF(CH2)4CH2CH3
CH3(CH2)3CH=CH(CH2)2CH3
Chapter 4 Solutions
ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
Ch. 4.2 - Examine the following for chirality centers:Ch. 4.2 - Prob. 2PCh. 4.3 - Prob. 3PCh. 4.3 - Prob. 4PCh. 4.4 - Prob. 5PCh. 4.4 - Prob. 6PCh. 4.5 - Does the molecular model shown represent...Ch. 4.6 - Assign absolute configurations as R or S to each...Ch. 4.6 - Draw three-dimensional representations ofCh. 4.7 - Prob. 10P
Ch. 4.7 - Using the Fischer projection of (R)-2-butanol...Ch. 4.8 - Prob. 12PCh. 4.9 - Prob. 13PCh. 4.9 - Prob. 14PCh. 4.10 - Prob. 15PCh. 4.10 - Draw Fischer projections of the four...Ch. 4.10 - Prob. 17PCh. 4.11 - A meso stereoisomer is possible for one of the...Ch. 4.11 - One of the stereoisomers of...Ch. 4.12 - Prob. 20PCh. 4.12 - Prob. 21PCh. 4.13 - Prob. 22PCh. 4.13 - Prob. 23PCh. 4.13 - Prob. 24PCh. 4.14 - Prob. 25PCh. 4 - Prob. 26PCh. 4 - Including stereoisomers, write structural formulas...Ch. 4 - Prob. 28PCh. 4 - Prob. 29PCh. 4 - Prob. 30PCh. 4 - Prob. 31PCh. 4 - Prob. 32PCh. 4 - Prob. 33PCh. 4 - Prob. 34PCh. 4 - Prob. 35PCh. 4 - Prob. 36PCh. 4 - Prob. 37PCh. 4 - Prob. 38PCh. 4 - Prob. 39PCh. 4 - (-)-Menthol is the most stable stereoisomer of...Ch. 4 - Prob. 41PCh. 4 - Prob. 42PCh. 4 - (a) An aqueous solution containing 10 g of...Ch. 4 - Prob. 44DSPCh. 4 - Prob. 45DSPCh. 4 - Consider two chemical changes: one occurring at a...Ch. 4 - Consider two chemical changes: one occurring at a...Ch. 4 - Prob. 48DSPCh. 4 - Consider two chemical changes: one occurring at a...Ch. 4 - Consider two chemical changes: one occurring at a...
Knowledge Booster
Similar questions
- Name 1) 3-fluoro, 1-butene 2) 2-heptene 2,3-difluoro- 1-pentene 4) 6-iodo,4-methyl- 2-decyne 5) 4,4-dibromo- 1,2-butandiol Complete structural formula F -C=C-C-C- Line formula Condensed structural formula N F CH2=CHCHFCH3arrow_forward1. Part 1: Naming Organic Compounds он H₁C-C-CH3 CH3 Br CI CI 2. Br-CH-CH-CH₂ H₂C-CH-C= -CH-CH2-CH3 3. HC-CH-CH-C-OH 5. H₂C-CH-CH₂-OH 7. OH 4. CH CH₂-CH₂ 6. сно CH-CH-CH-CH₂-CH₂ H₁₂C-CH-CH-CH-CH₁₂-CH₁₂ 8. OHarrow_forward11 Organic Chemistry Organic Nomenclature Practice Name/Functional Group n-butane Formula Structural Formula (1) C4tt10 H3C C- (2) CH3CH2CH2 CH 3 H₂ -CH3 Н2 name & functional group (1) and (2) OH H₁₂C Н2 name only (1) and (2) name only (1) and (2) H₁C - = - CH₂ Н2 HC=C-C CH3arrow_forward
- Under aqueous basic conditions, nitriles will react to form a neutral organic intermediate 1 that has an N atom in it first, and then they will continue to react to form the final product 2: NC H₂O он- H₂O 1 2 OH Draw the missing intermediate 1 and the final product 2 in the box below. You can draw the two structures in any arrangement you like. Click and drag to start drawing a structure.arrow_forwardAssign these COSY Spectrumarrow_forwardAssign these C-NMR and H-NMR Spectrumarrow_forward
- Predict the product of this organic reaction: IZ + HO i P+H₂O Specifically, in the drawing area below draw the skeletal ("line") structure of P. If there is no reasonable possibility for P, check the No answer box under the drawing area. No Answer Click and drag to start drawing a structure. ☐ :arrow_forwardPredict the products of this organic reaction: 0 O ----- A + KOH ? CH3-CH2-C-O-CH2-C-CH3 Specifically, in the drawing area below draw the condensed structure of the product, or products, of this reaction. (If there's more than one product, draw them in any arrangement you like, so long as they aren't touching.) If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. No reaction Click anywhere to draw the first atom of your structure. X ⑤ èarrow_forwardPredict the products of this organic reaction: O CH3 + H2O + HCI A A? CH3-CH2-C-N-CH3 Specifically, in the drawing area below draw the condensed structure of the product, or products, of this reaction. If there's more than one product, draw them in any arrangement you like, so long as they aren't touching. If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. No Reaction Click anywhere to draw the first atom of your structure.arrow_forward
- What is the missing reactant in this organic reaction? R+ HO-C-CH2-CH3 0= CH3 CH3 —CH, C−NH—CH CH3 + H₂O Specifically, in the drawing area below draw the condensed structure of R. If there is more than one reasonable answer, you can draw any one of them. If there is no reasonable answer, check the No answer box under the drawing area. Note for advanced students: you may assume no products other than those shown above are formed. No Answer Click anywhere to draw the first atom of your structure. €arrow_forward个 CHEM&131 9267 - $25 - Intro to Mail - Hutchison, Allison (Student x Aktiv Learnin https://app.aktiv.com Draw the product of the reaction shown below. Ignore inorganic byproducts. + Na2Cr2O7 Acetone, H2SO4 Type here to search Dryng OH W Prarrow_forwardPredict the products of this organic reaction: OH + NaOH A? Specifically, in the drawing area below draw the skeletal ("line") structure of the product, or products, of this reaction. (If there's more than one product, draw them in any arrangement you like, so long as they aren't touching.) If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. No reaction Click and drag to start drawing a structure. ✓ Sarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning