BURDGE CHEMISTRY VALUE ED (LL)
4th Edition
ISBN: 9781259995958
Author: VALUE EDITION
Publisher: MCG CUSTOM
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Textbook Question
Chapter 4, Problem 1QP
Define solute, solvent, and solution by describing the process of dissolving a solid in a liquid.
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Draw the stepwise mechanism for the reactions
Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Chapter 4 Solutions
BURDGE CHEMISTRY VALUE ED (LL)
Ch. 4.1 - Prob. 1PPACh. 4.1 - Prob. 1PPBCh. 4.1 - Prob. 1PPCCh. 4.1 - Prob. 1CPCh. 4.1 - Soluble molecular compounds are __________. a)...Ch. 4.1 - Which of the following compounds is a weak...Ch. 4.1 - 4.1.4 Which of the following compounds is a strong...Ch. 4.2 - Prob. 1PPACh. 4.2 - Prob. 1PPBCh. 4.2 - Practice Problem CONCEPTUALIZE
Using Tables 4.2...
Ch. 4.2 - Which of the following are water-soluble? (Choose...Ch. 4.2 - Which of the following are water-insoluble?...Ch. 4.2 - 4.2.3 What are the spectator ions in the ionic...Ch. 4.2 - Select the correct net ionic equation for the...Ch. 4.2 - 4.2.5 Which reaction is represented by the net...Ch. 4.2 - Which reaction is represented by the net ionic...Ch. 4.3 - Prob. 1PPACh. 4.3 - Practice Problem BUILD
Write the molecular,...Ch. 4.3 - Prob. 1PPCCh. 4.3 - Identify the Brø�nsted acid in the following...Ch. 4.3 - Identify the Brø�nsted base in the following...Ch. 4.3 - Which of the following is the correct net ionic...Ch. 4.3 - 4.3.4 Which of the following is the correct net...Ch. 4.3 - Which diagram best represents the ions remaining...Ch. 4.3 - Which diagram best represents the ions remaining...Ch. 4.4 - Prob. 1PPACh. 4.4 - Prob. 1PPBCh. 4.4 - Prob. 1PPCCh. 4.4 - Determine the oxidation number of sulfur in each...Ch. 4.5 - Practice Problem ATTEMPT
Assign oxidation numbers...Ch. 4.5 - Practice ProblemBUILD Assign oxidation numbers to...Ch. 4.5 - Practice ProblemCONCEPTUALIZE Write the balanced...Ch. 4.5 - Calculate the molar concentration of a solution...Ch. 4.5 - What mass of glucose (C 6 H 12 O 6 ) in grams must...Ch. 4.5 - What volume in milliliters of a 1 .20 M HCl...Ch. 4.5 - A solution that is 0 .18 M in Na 2 CO 3 is...Ch. 4.5 - Prob. 5CPCh. 4.5 - Prob. 6CPCh. 4.6 - Prob. 1PPACh. 4.6 - Prob. 1PPBCh. 4.6 - Prob. 1PPCCh. 4.6 - What mass of AgCl will be recovered if a solution...Ch. 4.6 - A 10.0-g sample of an unknown ionic compound is...Ch. 4.6 - 4.6.3 Which of the following best represents the...Ch. 4.6 - If 25.0 mL of an H 2 SO 4 solution requires 39 .9...Ch. 4.6 - 4.6.5 What volume of is required to neutralize
Ch. 4.6 - Which of the following best represents the...Ch. 4.7 - Prob. 1PPACh. 4.7 - Prob. 1PPBCh. 4.7 - Prob. 1PPCCh. 4.8 - Practice ProblemATTEMPT For an aqueous solution of...Ch. 4.8 - Prob. 1PPBCh. 4.8 - Prob. 1PPCCh. 4.9 - Practice Problem ATTEMPT
What volume of is...Ch. 4.9 - Prob. 1PPBCh. 4.9 - Prob. 1PPCCh. 4.10 - Practice ProblemATTEMPT Starting with a 6.552-M...Ch. 4.10 - Practice ProblemBUILD Five standard solutions of...Ch. 4.10 - Practice ProblemCONCEPTUALIZE The first diagram...Ch. 4.11 - Practice ProblemATTEMPT Using the square-bracket...Ch. 4.11 - Practice ProblemBUILD Using the square-bracket...Ch. 4.11 - Prob. 1PPCCh. 4.12 - Prob. 1PPACh. 4.12 - Prob. 1PPBCh. 4.12 - Practice ProblemCONCEPTUALIZE Which diagram best...Ch. 4.13 - Prob. 1PPACh. 4.13 - Prob. 1PPBCh. 4.13 - Practice Problem CONCEPTUALIZE
Which diagram best...Ch. 4.14 - Practice ProblemATTEMPT How many milliliters of a...Ch. 4.14 - Practice Problem BUILD
How many milliliters of a ...Ch. 4.14 - Practice ProblemCONCEPTUALIZE Which diagram best...Ch. 4.15 - Prob. 1PPACh. 4.15 - Prob. 1PPBCh. 4.15 - Practice Problem CONCEPTUALIZE
Consider aqueous...Ch. 4.16 - Prob. 1PPACh. 4.16 - Prob. 1PPBCh. 4.16 - Prob. 1PPCCh. 4 - Prob. 1KSPCh. 4 - 4.2
Consider the following net ionic equation: If...Ch. 4 - 4.3
The net ionic equation for the neutralization...Ch. 4 - When steel wool [ Fe ( s ) ] is placed in a...Ch. 4 - Define solute, solvent, and solution by describing...Ch. 4 - what is the difference between a nonelectrolyte...Ch. 4 - What is the difference between the symbols → and ⇄...Ch. 4 - Water is an extremely weak electrolyte and...Ch. 4 - Prob. 5QPCh. 4 - Prob. 6QPCh. 4 - Which of the following diagrams best represents...Ch. 4 - Identify each of the following substances as a...Ch. 4 - 4.9 Identify each of the following substances as a...Ch. 4 - The passage of electricity through an electrolyte...Ch. 4 - Predict and explain which of the following systems...Ch. 4 - You are given a water-soluble compound X. Describe...Ch. 4 - 4.13 Explain why a solution of in benzene does...Ch. 4 - 4.14 Describe hydration. What properties of water...Ch. 4 - 4.15 What is the difference between an ionic...Ch. 4 - 4.16 What is the advantage of writing net ionic...Ch. 4 - Prob. 17QPCh. 4 - Prob. 18QPCh. 4 - 4.19 Characterize the following compounds as...Ch. 4 - Characterize the following compounds as soluble or...Ch. 4 - Write ionic and net ionic equations for the...Ch. 4 - 4.22 Write ionic and net ionic equations for the...Ch. 4 - Which of the following processes will likely...Ch. 4 - 4.24 List the general properties of acids and...Ch. 4 - Give Arrhenius’s and Brø�nsted's definitions of an...Ch. 4 - Give an example of a monoprotic acid, a diprotic...Ch. 4 - What are the products of an acid-base...Ch. 4 - 4.28 what factors qualify a compound as a salt?...Ch. 4 - Prob. 29QPCh. 4 - 4.30 Identify each of the following species as a...Ch. 4 - Prob. 31QPCh. 4 - 4.32 Balance the following equations and write the...Ch. 4 - 4.33 Balance the following equations and write the...Ch. 4 - Prob. 34QPCh. 4 - Prob. 35QPCh. 4 - Prob. 36QPCh. 4 - Prob. 37QPCh. 4 - How is the activity series organized? How is it...Ch. 4 - 4.39 Use the following reaction to define the...Ch. 4 - Prob. 40QPCh. 4 - For the complete redox reactions given here, break...Ch. 4 - For the complete redox reactions given here, write...Ch. 4 - Arrange the following species in order of...Ch. 4 - Phosphorus forms many oxoacids. Indicate the...Ch. 4 - Give the oxidation numbers for the underlined...Ch. 4 - Give the oxidation number for the following...Ch. 4 - Prob. 47QPCh. 4 - Give the oxidation numbers for the underlined...Ch. 4 - Prob. 49QPCh. 4 - Prob. 50QPCh. 4 - Prob. 51QPCh. 4 - Prob. 52QPCh. 4 - Prob. 53QPCh. 4 - Prob. 54QPCh. 4 - Prob. 55QPCh. 4 - Prob. 56QPCh. 4 - Prob. 57QPCh. 4 - 4.58 Write the equation that enables us to...Ch. 4 - Prob. 59QPCh. 4 - 4.60 Describe how you would prepare
Ch. 4 - Prob. 61QPCh. 4 - Prob. 62QPCh. 4 - Prob. 63QPCh. 4 - Prob. 64QPCh. 4 - Calculate the volume in milliliters of a solution...Ch. 4 - 4.66 Determine how many grams of each of the...Ch. 4 - Prob. 67QPCh. 4 - Prob. 68QPCh. 4 - Prob. 69QPCh. 4 - 4.70 You have 505 mL of a solution and you want...Ch. 4 - Prob. 71QPCh. 4 - Prob. 72QPCh. 4 - Determine the resulting nitrate ion concentration...Ch. 4 - Prob. 74QPCh. 4 - Describe the basic steps involved in gravimetric...Ch. 4 - Prob. 76QPCh. 4 - Prob. 77QPCh. 4 - How does an acid-base indicator work?Ch. 4 - A student carried out two titrations using an NaOH...Ch. 4 - Prob. 80QPCh. 4 -
4.81 If 30.0 mL of is added to 15.0 mL of , what...Ch. 4 - Prob. 82QPCh. 4 -
4.83 How many grams of are required to...Ch. 4 -
4.84 Calculate the concentration (in molarity) of...Ch. 4 - Calculate the volume in milliliters of a 1 .420 M...Ch. 4 - Prob. 86QPCh. 4 - Prob. 87QPCh. 4 - Determine the mass of product that will...Ch. 4 - Prob. 89QPCh. 4 - Prob. 90QPCh. 4 - Prob. 91QPCh. 4 - For each of the following pairs of combinations,...Ch. 4 - Prob. 93QPCh. 4 - Prob. 94QPCh. 4 - Prob. 95APCh. 4 - Oxygen ( O 2 ) and carbon dioxide ( CO 2 ) are...Ch. 4 - Prob. 97APCh. 4 - Prob. 98APCh. 4 - Calculate the volume of a 0 .156 M CuSO 4 solution...Ch. 4 - Prob. 100APCh. 4 - Prob. 101APCh. 4 - 4.102 Identify each of the following compounds as...Ch. 4 - Prob. 105APCh. 4 - Prob. 106APCh. 4 - 4.107 A 15.00-mL solution of potassium nitrate was...Ch. 4 - When 2.50 g of a zinc strip was placed in an AgNO...Ch. 4 - Prob. 109APCh. 4 - 4.110 Calculate the concentration of the acid (or...Ch. 4 - Prob. 111APCh. 4 - Prob. 112APCh. 4 - Prob. 113APCh. 4 - Prob. 114APCh. 4 - Prob. 115APCh. 4 - Prob. 116APCh. 4 - Prob. 117APCh. 4 - Prob. 118APCh. 4 - You are given a soluble compound of an unknown...Ch. 4 - Prob. 120APCh. 4 - Prob. 121APCh. 4 - Prob. 122APCh. 4 - Prob. 123APCh. 4 - Prob. 124APCh. 4 - Prob. 125APCh. 4 - Someone spilled concentrated sulfuric acid on the...Ch. 4 - Prob. 127APCh. 4 - Prob. 128APCh. 4 - Prob. 129APCh. 4 - A 0.8870-g sample of a mixture of NaCl and KCl is...Ch. 4 - Prob. 131APCh. 4 - Prob. 132APCh. 4 - Prob. 133APCh. 4 - Because the Acid-base and precipitation reactions...Ch. 4 - Prob. 135APCh. 4 - Prob. 136APCh. 4 - Give a chemical explanation for each of the...Ch. 4 - The recommended procedure for preparing a very...Ch. 4 - A 0.9157-g mixture of CaBr 2 and NaBr is dissolved...Ch. 4 - 4.140 Use the periodic table framework given here...Ch. 4 - A 325-mL sample of solution contains 25 .3 g of...Ch. 4 - Prob. 142APCh. 4 - Prob. 143APCh. 4 - Prob. 144APCh. 4 - Prob. 145APCh. 4 - Prob. 146APCh. 4 - Prob. 147APCh. 4 - Prob. 148APCh. 4 - Prob. 149APCh. 4 - Prob. 150APCh. 4 - 4.151 Potassium superoxide is used in some...Ch. 4 - Prob. 152APCh. 4 - 4.153 Acetylsalicylic acid is a monoprotic add...Ch. 4 - Prob. 154APCh. 4 - Prob. 155APCh. 4 - Prob. 156APCh. 4 - 4.157 The concentration of ions in the water...Ch. 4 - Prob. 158APCh. 4 - The police often use a device called a...Ch. 4 - Absorbance values for five standard solutions of a...Ch. 4 - Prob. 1SEPPCh. 4 - Prob. 2SEPPCh. 4 - Prob. 3SEPPCh. 4 - Prob. 4SEPP
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- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
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