Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
13th Edition
ISBN: 9780134421353
Author: Karen C. Timberlake
Publisher: PEARSON
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Chapter 3.4, Problem 3.21PP
Discuss the changes in the potential and kinetic energy of a roller-coaster ride as the roller-coaster car climbs to the top and goes down the other side.
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Part 1. Aqueous 0.010M AgNO 3 is slowly added to a 50-ml solution containing both carbonate [co32-] = 0.105 M
and sulfate [soy] = 0.164 M anions. Given the ksp of Ag2CO3 and Ag₂ soy below. Answer the ff:
Ag₂ CO3 = 2 Ag+ caq) + co} (aq)
ksp = 8.10 × 10-12
Ag₂SO4 = 2Ag+(aq) + soy² (aq) ksp = 1.20 × 10-5
a) which salt will precipitate first?
(b)
What % of the first anion precipitated will remain in the solution.
by the time the second anion starts to precipitate?
(c) What is the effect of low pH (more acidic) condition on the separate of the carbonate and
sulfate anions via silver precipitation? What is the effect of high pH (more basic)? Provide appropriate
explanation per answer
Part 4. Butanoic acid (ka= 1.52× 10-5) has a partition coefficient of 3.0 (favors benzene) when distributed bet.
water and benzene. What is the formal concentration of butanoic acid in each phase when
0.10M aqueous butanoic acid is extracted w❘ 25 mL of benzene
100 mL of
a) at pit 5.00
b) at pH 9.00
Calculate activation energy (Ea) from the following kinetic data: Temp (oC) Time (s) 23.0 180. 32.1 131 40.0 101 51.8 86.0 Group of answer choices 0.0269 kJ/mole 2610 kJ/mole 27.6 kJ/mole 0.215 kJ/mole 20.8 kJ/mole
Chapter 3 Solutions
Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
Ch. 3.1 - Prob. 3.1PPCh. 3.1 - Prob. 3.2PPCh. 3.1 - Classify each of the following as a pure substance...Ch. 3.1 - Classify each of the following as a pure substance...Ch. 3.1 - Prob. 3.5PPCh. 3.1 - Prob. 3.6PPCh. 3.2 - Indicate whether each of the following describes a...Ch. 3.2 - Indicate whether each of the following describes a...Ch. 3.2 - Describe each of the following as a physical or...Ch. 3.2 - Describe each of the following as a physical or...
Ch. 3.2 - Prob. 3.11PPCh. 3.2 - What type of change, physical or chemical, takes...Ch. 3.2 - Describe each property of the element fluorine as...Ch. 3.2 - Describe each property of the element zirconium as...Ch. 3.3 - Prob. 3.15PPCh. 3.3 - Prob. 3.16PPCh. 3.3 - Prob. 3.17PPCh. 3.3 - Calculate the unknown temperature in each of the...Ch. 3.3 - Prob. 3.19PPCh. 3.3 - a. Water is heated to 145 °F. What is the...Ch. 3.4 - Discuss the changes in the potential and kinetic...Ch. 3.4 - Prob. 3.22PPCh. 3.4 - Indicate whether each of the following statements...Ch. 3.4 - Prob. 3.24PPCh. 3.4 - Convert each of the following energy units: a....Ch. 3.4 - Prob. 3.26PPCh. 3.4 - The energy needed to keep a 75-wattlight bulb...Ch. 3.4 - Prob. 3.28PPCh. 3.5 - Calculate the kilocalories for each of the...Ch. 3.5 - Calculate the kilocalories for each of the...Ch. 3.5 - Using the energy values for foods (see TABLE3.7),...Ch. 3.5 - Using the energy values for foods (see TABLE3.7),...Ch. 3.5 - Prob. 3.33PPCh. 3.5 - Prob. 3.34PPCh. 3.5 - Prob. 3.35PPCh. 3.5 - Prob. 3.36PPCh. 3.6 - If the same amount of heat is supplied to samples...Ch. 3.6 - Substances A and B are the same mass and at the...Ch. 3.6 - Use the heat equation to calculate the energy for...Ch. 3.6 - Use the heat equation to calculate the energy for...Ch. 3.6 - Use the heat equation to calculate the energy, in...Ch. 3.6 - Use the heat equation to calculate the energy, in...Ch. 3.7 - Identify each of the following changes of state as...Ch. 3.7 - Identify each of the following changes of state as...Ch. 3.7 - Calculate the heat change at 0 °C for each of the...Ch. 3.7 - Prob. 3.46PPCh. 3.7 - Identify each of the following changes of state as...Ch. 3.7 - Identify each of the following changes of state as...Ch. 3.7 - Prob. 3.49PPCh. 3.7 - 3.50 Calculate the heat change at 100 °C for each...Ch. 3.7 - Prob. 3.51PPCh. 3.7 - Prob. 3.53PPCh. 3.7 - Prob. 3.54PPCh. 3.7 - Prob. 3.55PPCh. 3.7 - Prob. 3.56PPCh. 3.7 - Prob. 3.57PPCh. 3.7 - Prob. 3.58PPCh. 3 - Prob. 3.59UTCCh. 3 - Prob. 3.60UTCCh. 3 - Prob. 3.61UTCCh. 3 - Prob. 3.62UTCCh. 3 - Prob. 3.63UTCCh. 3 - Prob. 3.64UTCCh. 3 - Prob. 3.65UTCCh. 3 - Prob. 3.66UTCCh. 3 - Calculate the energy to heat two cubes (gold and...Ch. 3 - Calculate the energy to heat two cubes (silver and...Ch. 3 - Prob. 3.69UTCCh. 3 - Prob. 3.70UTCCh. 3 - Prob. 3.71APPCh. 3 - Prob. 3.72APPCh. 3 - Prob. 3.73APPCh. 3 - Prob. 3.74APPCh. 3 - Prob. 3.75APPCh. 3 - Prob. 3.76APPCh. 3 - Prob. 3.77APPCh. 3 - Prob. 3.78APPCh. 3 - Prob. 3.79APPCh. 3 - Prob. 3.80APPCh. 3 - Prob. 3.81APPCh. 3 - Calculate each of the following temperatures in...Ch. 3 - What is 15 °F in degrees Celsius and in kelvins?...Ch. 3 - Prob. 3.84APPCh. 3 - A 0.50-g sample of vegetable oil is placed in a...Ch. 3 - A 1.3-g sample of rice is placed in a calorimeter....Ch. 3 - On a hot day, the beach sand gets hot but the...Ch. 3 - On a hot sunny day, you get out of the swimming...Ch. 3 - Prob. 3.89APPCh. 3 - Prob. 3.90APPCh. 3 - The melting point of dibromomethane is 53 °C and...Ch. 3 - Prob. 3.92APPCh. 3 - Prob. 3.93APPCh. 3 - Prob. 3.94APPCh. 3 - Prob. 3.95APPCh. 3 - Prob. 3.96APPCh. 3 - Prob. 3.97CPCh. 3 - A 45-g piece of ice at 0.0 °C is added to a sample...Ch. 3 - Prob. 3.99CPCh. 3 - Prob. 3.100CPCh. 3 - Prob. 3.101CPCh. 3 - A 115-g sample of steam at 100 °C is emitted from...Ch. 3 - Prob. 3.103CPCh. 3 - 3.104 A 125-g piece of metal is heated to 288 °C...Ch. 3 - A metal is thought to be titanium or aluminum....Ch. 3 - 3.106 A metal is thought to be copper or gold....Ch. 3 - Gold, one of the most sought-after metals in the...Ch. 3 - The mileage for a motorcycle with a fuel-tank...Ch. 3 - Answer the following for water samples A and B...Ch. 3 - Prob. 4CICh. 3 - Prob. 5CICh. 3 - Prob. 6CI
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- Calculate activation energy (Ea) from the following kinetic data: Temp (oC) Time (s) 23.0 180. 32.1 131 40.0 101 51.8 86.0 choices: 0.0269 kJ/mole 2610 kJ/mole 27.6 kJ/mole 0.215 kJ/mole 20.8 kJ/molearrow_forwardCalculate activation energy (Ea) from the following kinetic data: Temp (oC) Time (s) 23.0 180. 32.1 131 40.0 101 51.8 86.0arrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forward
- Rank the compounds in each group below according to their reactivity toward electrophilic aromatic substitution (most reactive = 1; least reactive = 3). Place the number corresponding to the compounds' relative reactivity in the blank below the compound. a. CH₂F CH3 F b. At what position, and on what ring, is bromination of phenyl benzoate expected to occur? Explain your answer. :0: C-O phenyl benzoate 6.Consider the reaction below to answer the following questions. A B C NO₂ FeBr3 + Br₂ D a. The nucleophile in the reaction is: BODADES b. The Lewis acid catalyst in the reaction is: C. This reaction proceeds d. Draw the structure of product D. (faster or slower) than benzene.arrow_forwardPart 2. A solution of 6.00g of substance B in 100.0mL of aqueous solution is in equilibrium, at room temperature, wl a solution of B in diethyl ether (ethoxyethane) containing 25.0 g of B in 50.0 mL 9) what is the distribution coefficient of substance B b) what is the mass of B extracted by shaking 200 ml of an aqueous solution containing 10g of B with call at room temp): i) 100 mL of diethyl ether ii) 50ml of diethyl ether twice iii) 25ml of diethyl ether four timesarrow_forward- Rank the following groups of compounds from most acidic (1) to least acidic (4). Place the number corresponding to the compound's relative rank in the blank below the structure. a. NO₂ NO₂ CH2CH2CH2CH2OH CH3 CH3CH2CHOH CH3CH2CH2CH2OH NO₂ CH3CHCH2CH2OH b. OH OH CH₂OH CO₂H HC CN CN CNarrow_forward
- Give the major organic product(s) of the following reactions or sequences of reactions. Show all relevant stereochemistry a. H MgBr 1. ether 2. H₂O* 4 COH b. 1. LIAIH, ether 2. H₂O Choose the best reagent(s) for carrying out the following conversions from the list provided below. Place the letter of the best choice in the blank to the left of the conversion. Reagents may be used more than once. a. 1. CH3MgBr, ether 2. H3O+ NaOH b. 1. PBr3 2. C. 2. 1. (CH3)3SiCl, (CH3CH2)3N CH3MgBr, ether 3. H₂O*+ 2. H3O+ e. 1. p-TosCl, pyridine f. نها g. 2. NaOH CrO3, H₂SO4, H₂O 1. NaBH4, ethanol 2. H30* h. PCC, CH2Cl2 Ovoldo-6 a. b. OH OH H OH O any organicarrow_forwardDetermine the rate law for sodium thiosulfate from the following data: [Na2S2O3] Time (s) 0.0318 230. 0.0636 57.5arrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forward
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