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Concept explainers
(a)
Interpretation:
The given compounds represent the same or a different compound has to be identified.
Concept Introduction:
Isomers: Compounds that have same molecular formula but different structural formula.
Constitutional isomers: Compounds that have same molecular formula but different connectivity (arrangement of atoms are different).
Nomenclature of organic compounds:
The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,
- The longer number of Carbon chain of a compound is identified this is called parent of the compound.
- In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.
- The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.
- The names of all substituents are arranged by alphabets to starts with lowest numbering.
- The complex substituent is built by a substituent on a substituent; so called complex substituent.
- In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.
(b)
Interpretation:
The given compounds represent the same or a different compound has to be identified.
Concept Introduction:
Isomers: Compounds that have same molecular formula but different structural formula.
Constitutional isomers: Compounds that have same molecular formula but different connectivity (arrangement of atoms are different).
Nomenclature of organic compounds:
The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,
- The longer number of Carbon chain of a compound is identified this is called parent of the compound.
- In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.
- The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.
- The names of all substituents are arranged by alphabets to starts with lowest numbering.
- The complex substituent is built by a substituent on a substituent; so called complex substituent.
- In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.
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Chapter 3 Solutions
Essential Organic Chemistry Study Guide & Solution Manual, Books a la Carte Edition
- Nonearrow_forwardNonearrow_forwardWhat spectral features allow you to differentiate the product from the starting material? Use four separate paragraphs for each set of comparisons. You should have one paragraph each devoted to MS, HNMR, CNMR and IR. 2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too. 3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of functional group changes.arrow_forward
- Nonearrow_forwardNonearrow_forwardIn the solid state, oxalic acid occurs as a dihydrate with the formula H2C2O4 C+2H2O. Use this formula to calculate the formula weight of oxalic acid. Use the calculated formula weight and the number of moles (0.00504mol) of oxalic acid in each titrated unknown sample recorded in Table 6.4 to calculate the number of grams of pure oxalic acid dihydrate contained in each titrated unknown sample.arrow_forward
- 1. Consider a pair of elements with 2p and 4p valence orbitals (e.g., N and Se). Draw their (2p and 4p AO's) radial probability plots, and sketch their angular profiles. Then, consider these orbitals from the two atoms forming a homonuclear л-bond. Which element would have a stronger bond, and why? (4 points)arrow_forwardWrite the reaction and show the mechanism of the reaction. Include the mechanism for formation of the NO2+ 2. Explain, using resonance structures, why the meta isomer is formed. Draw possible resonance structures for ortho, meta and para.arrow_forwardNonearrow_forward
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