Explanation Substitute the different values of T in d P d T for T = 303, 313, 323, 333 and 343 and use the obtained values to verify Clausius–Clapeyron Law by calculating T 2 P d P d T for various values of T and checking if the values are roughly constant. Use this to determine the value of k Given: Calculation: Using the given formula of the derivative of P, P ' ( 303 ) ≈ P ( 303 + 10 ) − P ( 303 − 10 ) 20 = P ( 313 ) − P ( 293 ) 20 = 0.0808 − 0.0278 20 = 0.00265 atm/K P ' ( 313 ) ≈ P ( 313 + 10 ) − P ( 313 − 10 ) 20 = P ( 323 ) − P ( 303 ) 20 = 0.1311 − 0.0482 20 = 0.004145 atm/K P ' ( 323 ) ≈ P ( 323 + 10 ) − P ( 323 − 10 ) 20 = P ( 333 ) − P ( 313 ) 20 = 0.2067 − 0.0808 20 = 0.006295 atm/K P ' ( 333 ) ≈ P ( 333 + 10 ) − P ( 333 − 10 ) 20 = P ( 343 ) − P ( 323 ) 20 = 0

3rd Edition

ISBN: 9781464125263

Author: Jon Rogawski, Colin Adams

Publisher: W.H. Freeman & Co

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Question

Chapter 3.2, Problem 63E

To determine

The value of dPdT for T = 303, 313, 323, 333, 343 using the given data and verify if the results confirm the Clausius–Clapeyron Law, then determine the approximate value of k

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Chapter 3.2, Problem 62E

Chapter 3.2, Problem 64E

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Chapter 3 Solutions

Calculus - Standalone book

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The value of d P d T for T = 303, 313, 323, 333, 343 using the given data and verify if the results confirm the Clausius–Clapeyron Law, then determine the approximate value of k

Solution Summary: The author explains how to determine the approximate value of k using the given data and the Clausius–Clapeyron Law.

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The value of dPdT for T = 303, 313, 323, 333, 343 using the given data and verify if the results confirm the Clausius–Clapeyron Law, then determine the approximate value of k

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