The table representing the difference in energy for axial-equatorial groups is given. The pictures of axial conformations of isopropylcyclohexane and t e r t − butylcyclohexane and an explanation corresponding to increase in large energy of tert-butyl substituent over the isopropyl group is to be stated. Concept introduction: The cycloalkane with molecular formula C 6 H 12 is called cyclohexane. This six vertex ring does not show the shape of a complete hexagon. In the case of hexane, the bond angles between carbon atoms are 109.5 ° due to which it has some angle strain that is known as torsional strain. This strain is reduced by cyclohexane, after it adopts a 3 − D structure known as chair conformation. To determine: The pictures of axial conformations of isopropylcyclohexane and t e r t − butylcyclohexane and an explanation corresponding to increase in large energy of tert-butyl substituent over the isopropyl group.

Question

Draw the product of the reaction shown below. Ignore inorganic byproducts. H conc. HBr Drawing Q

Answer 1

Question

Chapter 3.14, Problem 3.24P

Interpretation Introduction

Interpretation: The table representing the difference in energy for axial-equatorial groups is given. The pictures of axial conformations of isopropylcyclohexane and tert−butylcyclohexane and an explanation corresponding to increase in large energy of tert-butyl substituent over the isopropyl group is to be stated.

Concept introduction: The cycloalkane with molecular formula C6H12 is called cyclohexane. This six vertex ring does not show the shape of a complete hexagon. In the case of hexane, the bond angles between carbon atoms are 109.5° due to which it has some angle strain that is known as torsional strain. This strain is reduced by cyclohexane, after it adopts a 3−D structure known as chair conformation.

To determine: The pictures of axial conformations of isopropylcyclohexane and tert−butylcyclohexane and an explanation corresponding to increase in large energy of tert-butyl substituent over the isopropyl group.

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