Organic Chemistry
4th Edition
ISBN: 9780073402772
Author: Janice G. Smith
Publisher: MCG
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Chapter 31, Problem 31.41P
Cationic
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A 25.0 g sample of water was cooled from 23.9°C to 12.7°C, how much heat was released? (Assume thatthe specific heat of water is 4.18 J/g °C)
Zeolites: environmental applications.
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The structure of the bicarbonate (hydrogen carbonate) ion, HCO3-, HCO3
best described as a hybrid of several contributing resonance forms, two of which
are shown here.
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Bicarbonate is crucial for the control of body pH (for example, blood pH:
7.4). A more self-indulgent use is in baking soda, where it serves as a
source of CO2 CO₂ 2 gas, which gives bread and pastry their fluffy
constituency.
(i) Draw at least one additional resonance form.
=
(ii) Using curved "electron-pushing" arrows, show how these Lewis structures may
be interconverted by movement of electron pairs. (iii) Determine which form or
forms will be the major contributor(s) to the real structure of bicarbonate,
explaining your answer on the basis of the criteria in Section 1-5.
Chapter 31 Solutions
Organic Chemistry
Ch. 31 - Prob. 31.1PCh. 31 - Prob. 31.2PCh. 31 - Prob. 31.3PCh. 31 - Draw the mechanism for the radical polymerization...Ch. 31 - Prob. 31.5PCh. 31 - Prob. 31.6PCh. 31 - Prob. 31.7PCh. 31 - Prob. 31.8PCh. 31 - Prob. 31.9PCh. 31 - Prob. 31.10P
Ch. 31 - Prob. 31.11PCh. 31 - Problem 30.12
What polymer is formed by anionic...Ch. 31 - Prob. 31.13PCh. 31 - Prob. 31.14PCh. 31 - Problem 30.15
What polyamide is formed from each...Ch. 31 - Prob. 31.16PCh. 31 - Prob. 31.17PCh. 31 - Prob. 31.18PCh. 31 - Prob. 31.19PCh. 31 - Prob. 31.20PCh. 31 - Prob. 31.21PCh. 31 - Prob. 31.22PCh. 31 - Prob. 31.23PCh. 31 - Prob. 31.24PCh. 31 - Prob. 31.25PCh. 31 - Prob. 31.26PCh. 31 - 30.26 Draw the structure of the polymer formed by...Ch. 31 - Prob. 31.28PCh. 31 - Prob. 31.29PCh. 31 - Prob. 31.30PCh. 31 - Prob. 31.31PCh. 31 - Prob. 31.32PCh. 31 - Prob. 31.33PCh. 31 - Prob. 31.34PCh. 31 - Prob. 31.35PCh. 31 - Prob. 31.36PCh. 31 - Prob. 31.37PCh. 31 - Prob. 31.38PCh. 31 - Prob. 31.39PCh. 31 - 30.39 Draw a stepwise mechanism for the...Ch. 31 - 30.40 Cationic polymerization of 3-phenylpropene ...Ch. 31 - Prob. 31.42PCh. 31 - Prob. 31.43PCh. 31 - 30.43 Although styrene undergoes both cationic and...Ch. 31 - 30.44 Rank the following compounds in order of...Ch. 31 - Prob. 31.46PCh. 31 - Prob. 31.47PCh. 31 - 30.47 Draw a stepwise mechanism for the following...Ch. 31 - 30.48 Draw a stepwise mechanism for the reaction...Ch. 31 - Prob. 31.50PCh. 31 - Prob. 31.51PCh. 31 - Prob. 31.52PCh. 31 - 30.52 (a) Explain why poly (vinyl alcohol) cannot...Ch. 31 - Prob. 31.54PCh. 31 - 30.53 Devise a synthesis of terephthalic acid and...Ch. 31 - Prob. 31.56PCh. 31 - Prob. 31.57PCh. 31 - 30.56 Compound A is a novel poly (ester amide)...Ch. 31 - Researchers at Rutgers University have developed...Ch. 31 - 30.58 Melmac, a thermosetting polymer formed from...Ch. 31 - 30.59 Although chain branching in radical...Ch. 31 - Prob. 31.62P
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