Basic Chemistry
6th Edition
ISBN: 9780134878119
Author: Timberlake, Karen C. , William
Publisher: Pearson,
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Question
Chapter 3, Problem 73APP
Interpretation Introduction
To determine: If the stated change is physical or chemical.
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Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone
required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one
molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01
number of moles= 0.400/277.15 = 0.00144 moles
2 x 0.00 144=0.00288 moves
arams of acetophenone = 0.00144 X 120.16 = 0.1739
0.1739x2=0.3469
grams of benzaldehyde = 0.00144X106.12=0.1539
0.1539x2 = 0.3069
Starting materials:
0.3469 Ox acetophenone,
0.3069 of benzaldehyde
3
1.
Answer the questions about the following reaction:
(a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this
reaction. Be sure to include any relevant stereochemistry in the product structure.
+
SK
F
Br
+
(b) In which solvent would this reaction proceed the fastest (Circle one)
Methanol
Acetone
(c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the
one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you
observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest
other products that are formed? Draw them in the box provided.
3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants
or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure
and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in
the reactant before being able to draw the arrows corresponding to product formation.
A.
B.
Rearrangement
ΘΗ
Chapter 3 Solutions
Basic Chemistry
Ch. 3.1 - Classify each of the following pure substances as...Ch. 3.1 - Classify each of the following pure substances as...Ch. 3.1 - Classify each of the following as a pure substance...Ch. 3.1 - Classify each of the following as a pure substance...Ch. 3.1 - A dietitian includes one of the following mixtures...Ch. 3.1 - A dietitian includes one of the following mixtures...Ch. 3.2 - Indicate whether each of the following describes a...Ch. 3.2 - Indicate whether each of the following describes a...Ch. 3.2 - Describe each of the following as a physical or...Ch. 3.2 - Describe each of the following as a physical or...
Ch. 3.2 - Prob. 11PPCh. 3.2 - Prob. 12PPCh. 3.2 - Prob. 13PPCh. 3.2 - Describe each of the following properties for the...Ch. 3.3 - Prob. 15PPCh. 3.3 - Prob. 16PPCh. 3.3 - Prob. 17PPCh. 3.3 - Calculate the unknown temperature in each of the...Ch. 3.3 - Prob. 19PPCh. 3.3 - Prob. 20PPCh. 3.4 - Prob. 21PPCh. 3.4 - Prob. 22PPCh. 3.4 - Prob. 23PPCh. 3.4 - Prob. 24PPCh. 3.4 - Prob. 25PPCh. 3.4 - Prob. 26PPCh. 3.4 - Prob. 27PPCh. 3.4 - Prob. 28PPCh. 3.5 - If the same amount of heat is supplied to samples...Ch. 3.5 - Substances A and B are the same mass and at the...Ch. 3.5 - Calculate the specific heat (J/g °C) for each of...Ch. 3.5 - Calculate the specific heat (J/g °C) for each of...Ch. 3.5 - Use the heat equation to calculate the energy, in...Ch. 3.5 - Use the heat equation to calculate the energy, in...Ch. 3.5 - Calculate the mass, in grams, for each of the...Ch. 3.5 - Prob. 36PPCh. 3.5 - Prob. 37PPCh. 3.5 - Prob. 38PPCh. 3.5 - Prob. 39PPCh. 3.5 - a. A 22.8-g piece of metal at 92.6 °C is dropped...Ch. 3.6 - Prob. 41PPCh. 3.6 - Prob. 42PPCh. 3.6 - Prob. 43PPCh. 3.6 - Prob. 44PPCh. 3.6 - Prob. 45PPCh. 3.6 - Prob. 46PPCh. 3.6 - Prob. 47PPCh. 3.6 - Prob. 48PPCh. 3.6 - When a 1.50-g sample of walnuts is burned in a...Ch. 3.6 - Prob. 50PPCh. 3.6 - Prob. 51PPCh. 3.6 - Prob. 52PPCh. 3 - Prob. 53UTCCh. 3 - Prob. 54UTCCh. 3 - Prob. 55UTCCh. 3 - Classify each of the following as a homogeneous or...Ch. 3 - Prob. 57UTCCh. 3 - Prob. 58UTCCh. 3 - Prob. 59UTCCh. 3 - Prob. 60UTCCh. 3 - Prob. 61UTCCh. 3 - Prob. 62UTCCh. 3 - Prob. 63UTCCh. 3 - Prob. 64UTCCh. 3 - Prob. 65APPCh. 3 - Classify each of the following as an element, a...Ch. 3 - Classify each of the following mixtures as...Ch. 3 - Prob. 68APPCh. 3 - Prob. 69APPCh. 3 - Prob. 70APPCh. 3 - Prob. 71APPCh. 3 - Prob. 72APPCh. 3 - Prob. 73APPCh. 3 - Prob. 74APPCh. 3 - Prob. 75APPCh. 3 - Calculate each of the following temperatures in...Ch. 3 - Prob. 77APPCh. 3 - Prob. 78APPCh. 3 - Prob. 79APPCh. 3 - Prob. 80APPCh. 3 - A 0.50-g sample of vegetable oil is placed in a...Ch. 3 - A 1.3-g sample of rice is placed in a calorimeter....Ch. 3 - A hot-water bottle for a patient contains 725 g of...Ch. 3 - Prob. 84APPCh. 3 - Prob. 85APPCh. 3 - Prob. 86APPCh. 3 - The following problems are related to the topics...Ch. 3 - The following problems are related to the topics...Ch. 3 - The following problems are related to the topics...Ch. 3 - The following problems are related to the topics...Ch. 3 - Prob. 91CPCh. 3 - Prob. 92CPCh. 3 - Gold, one of the most sought-after metals in the...Ch. 3 - Prob. 2CICh. 3 - Prob. 3CICh. 3 - Prob. 4CICh. 3 - In one box of nails weighing 0.250 lb, there are...Ch. 3 - A hot tub is filled with 450 gal of water. (2.5,...
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