The electron affinity of fluorine and ionization energy of sodium is to be compared. The sign of Δ E in the process of electron “pull” from the sodium atom to the fluorine atom is to be evaluated. The reason of stability of NaF compound is to be explained. The sign of Δ E in the overall formation of NaF is to be evaluated. Concept introduction: The change in energy of a reaction is defined as the sum of change in the internal energy of a system and the product of its absolute temperature and entropy. Electron affinity is defined as the energy released from a neutral atom in gaseous phase when it gains an electron to form negatively charged ion. Ionization energy is defined as the energy required to remove an electron from the neutral atom. To determine: The analogy between the electron affinity of fluorine and ionization energy of sodium; if the Δ E is positive or negative in the process of electron “pull” from the sodium atom to the fluorine atom; the reason that the NaF compound is stable; if the Δ E is positive or negative in the overall formation of NaF .
The electron affinity of fluorine and ionization energy of sodium is to be compared. The sign of Δ E in the process of electron “pull” from the sodium atom to the fluorine atom is to be evaluated. The reason of stability of NaF compound is to be explained. The sign of Δ E in the overall formation of NaF is to be evaluated. Concept introduction: The change in energy of a reaction is defined as the sum of change in the internal energy of a system and the product of its absolute temperature and entropy. Electron affinity is defined as the energy released from a neutral atom in gaseous phase when it gains an electron to form negatively charged ion. Ionization energy is defined as the energy required to remove an electron from the neutral atom. To determine: The analogy between the electron affinity of fluorine and ionization energy of sodium; if the Δ E is positive or negative in the process of electron “pull” from the sodium atom to the fluorine atom; the reason that the NaF compound is stable; if the Δ E is positive or negative in the overall formation of NaF .
Solution Summary: The author compares the electron affinity of fluorine and ionization energy of sodium. The sign of Delta E in the process of electron "pull" from the sodium atom to the flu
Definition Definition Change in energy of a neutral gaseous atom when an electron is added to the atom to form a negative ion.
Chapter 3, Problem 64E
Interpretation Introduction
Interpretation: The electron affinity of fluorine and ionization energy of sodium is to be compared. The sign of
ΔE in the process of electron “pull” from the sodium atom to the fluorine atom is to be evaluated. The reason of stability of
NaF compound is to be explained. The sign of
ΔE in the overall formation of
NaF is to be evaluated.
Concept introduction: The change in energy of a reaction is defined as the sum of change in the internal energy of a system and the product of its absolute temperature and entropy.
Electron affinity is defined as the energy released from a neutral atom in gaseous phase when it gains an electron to form negatively charged ion.
Ionization energy is defined as the energy required to remove an electron from the neutral atom.
To determine: The analogy between the electron affinity of fluorine and ionization energy of sodium; if the
ΔE is positive or negative in the process of electron “pull” from the sodium atom to the fluorine atom; the reason that the
NaF compound is stable; if the
ΔE is positive or negative in the overall formation of
NaF.
Acetic acid is added to DI water at an initial concentration of 10 -6 M (Ka=1.8x10-5)
A. Using the "ICE" Method, what would the pH be at equilibrium? State assumptions and show your
work.
B. Using the simultaneous equations method, what would the pH be at equilibrium? Show your work
1. Show that the change in entropy for a fixed amount of ideal gas held at a constant
temperature undergoing a volume change is given by the simple equation
AS = NkB In
Hint: Start with the equation
M
dS =
du + (Œ) dv - Ž (#) an,
dU
du+av-dN;
j=1
Why doesn't the equation for the entropy of an ideal gas depend on the strength of the
intermolecular forces for the gas?
2. Make an ice cube at 1 bar pressure by freezing an amount of liquid water that is 2
cm x 2 cm x 2 cm in volume. The density of liquid water at 0 °C is 1.000 g cm³ and the
density of ice at 0 °C is 0.915 g cm³. Note that this difference in density is the reason
your water pipes burst if they freeze and why you shouldn't forget to take your bottle of
pop out of the freezer if you put it in there to try and cool it down faster.
A. What is the work of expansion upon freezing?
B. Is work done on the system or by the system?
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