The steric number of CBr 4 should be calculated. The molecular geometry for the same should be predicted. Concept Introduction: The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom. Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

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Answer 1

Question

Chapter 3, Problem 59P

(a)

Interpretation Introduction

Interpretation:

The steric number of CBr4 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

(b)

Interpretation Introduction

Interpretation:

The steric number of SO3 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

(c)

Interpretation Introduction

Interpretation:

The steric number of SeF6 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pair around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

(d)

Interpretation Introduction

Interpretation:

The steric number of SOCl2 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

(e)

Interpretation Introduction

Interpretation:

The steric number of ICl3 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

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4. (3 pts) From the information below, determine the lattice enthalpy for MgBr2. Show all work. AH/(kJ mol-¹) Sublimation of Mg(s) +148 lonization of Mg(g) +2187 to Mg2+(g) Vaporization of Br₂(1) +31 Dissociation of Br,(g) +193 Electron gain by Br(g) -331 Formation of MgBr₂(s) -524

1. (4 pts-2 pts each part) Consider the crystal structures of NaCl, ZnS, and CsCl (not necessarily shown in this order). a. For one of the three compounds, justify that the unit cell is consistent with stoichiometry of the compound. b. In each of the crystal structures, the cations reside in certain holes in the anions' packing structures. For each compound, what type of holes are occupied by the cations and explain why those particular types of holes are preferred.

(2 pts) What do you expect to happen in a Na2O crystal if a Cl− ion replaces one of the O2−ions in the lattice?

Answer 2

Question

Chapter 3, Problem 59P

(a)

Interpretation Introduction

Interpretation:

The steric number of CBr4 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

(b)

Interpretation Introduction

Interpretation:

The steric number of SO3 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

(c)

Interpretation Introduction

Interpretation:

The steric number of SeF6 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pair around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

(d)

Interpretation Introduction

Interpretation:

The steric number of SOCl2 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

(e)

Interpretation Introduction

Interpretation:

The steric number of ICl3 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

Expert Solution & Answer

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Answer 3

Question

Chapter 3, Problem 59P

(a)

Interpretation Introduction

Interpretation:

The steric number of CBr4 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

(b)

Interpretation Introduction

Interpretation:

The steric number of SO3 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

(c)

Interpretation Introduction

Interpretation:

The steric number of SeF6 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pair around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

(d)

Interpretation Introduction

Interpretation:

The steric number of SOCl2 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

(e)

Interpretation Introduction

Interpretation:

The steric number of ICl3 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

Expert Solution & Answer

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Answer 4

Question

Chapter 3, Problem 59P

(a)

Interpretation Introduction

Interpretation:

The steric number of CBr4 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

(b)

Interpretation Introduction

Interpretation:

The steric number of SO3 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

(c)

Interpretation Introduction

Interpretation:

The steric number of SeF6 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pair around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

(d)

Interpretation Introduction

Interpretation:

The steric number of SOCl2 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

(e)

Interpretation Introduction

Interpretation:

The steric number of ICl3 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

Expert Solution & Answer

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Answer 5

Chapter 3, Problem 59P

(a)

Interpretation Introduction

Interpretation:

The steric number of CBr4 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

(b)

Interpretation Introduction

Interpretation:

The steric number of SO3 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

(c)

Interpretation Introduction

Interpretation:

The steric number of SeF6 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pair around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

(d)

Interpretation Introduction

Interpretation:

The steric number of SOCl2 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

(e)

Interpretation Introduction

Interpretation:

The steric number of ICl3 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

Answer 6

Chapter 3, Problem 59P

(a)

Interpretation Introduction

Interpretation:

The steric number of CBr4 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

Answer 7

Chapter 3, Problem 59P

(a)

Interpretation Introduction

Interpretation:

The steric number of CBr4 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The steric number of SO3 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The steric number of SO3 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The steric number of SeF6 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pair around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The steric number of SeF6 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pair around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The steric number of SOCl2 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The steric number of SOCl2 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The steric number of ICl3 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The steric number of ICl3 should be calculated. The molecular geometry for the same should be predicted.

Concept Introduction:

The molecular structure is a 3-dimensional representation of bond pairs around the central atom. It is also known as molecular geometry. Electron geometry is a 3-dimensional representation of bond pairs and lone pairs around the central atom.

Shape corresponds to electron geometry and geometry corresponds to molecular geometry or structure.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 3 - Before the element scandium was discovered in...Ch. 3 - Prob. 2P Ch. 3 - Prob. 3P Ch. 3 - Prob. 4P Ch. 3 - Prob. 5P Ch. 3 - A gold nucleus is located at the origin of...Ch. 3 - Prob. 7P Ch. 3 - A gold nucleus is located at the origin of...Ch. 3 - Prob. 9P Ch. 3 - Prob. 10P

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