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ORGANIC CHEMISTRY-STD.WILEY PLUS CARD
3rd Edition
ISBN: 9781119340515
Author: Klein
Publisher: WILEY
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Question
Chapter 3, Problem 55IP
Interpretation Introduction
Interpretation:
More acidic nature of salicylic acid than its constitutional isomers is needed to be explained.
Concept introduction:
Constitutional isomers:
- Constitutional isomers are isomers which have the same molecular formula and different bond connectivity between the atoms in the molecule.
Acidic strength of the molecule depends on the stability of the Conjugate anion.
- If the conjugate anion is more resonance stabilized, the acid considered as strong acid and the anion is weak base.
- If more sterically hindered the group, acidic nature is less. That means bulkiness decreases the acidic strength of the molecule.
To give: the explanation for the acidity of salicylic acid than para-hydroxybenzoic acid.
Expert Solution & Answer
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Chapter 3 Solutions
ORGANIC CHEMISTRY-STD.WILEY PLUS CARD
Ch. 3.2 - Prob. 1LTSCh. 3.2 - All of the following acid-base reactions are...Ch. 3.2 - Prob. 2PTSCh. 3.2 - Prob. 3ATSCh. 3.3 - Prob. 2LTSCh. 3.3 - Prob. 4PTSCh. 3.3 - Prob. 5ATSCh. 3.3 - Prob. 6ATSCh. 3.3 - Prob. 3LTSCh. 3.3 - Prob. 7PTS
Ch. 3.3 - Prob. 8ATSCh. 3.3 - Prob. 9ATSCh. 3.3 - Prob. 4LTSCh. 3.3 - Prob. 10PTSCh. 3.3 - Prob. 11ATSCh. 3.3 - Prob. 12CCCh. 3.4 - Prob. 5LTSCh. 3.4 - Prob. 13PTSCh. 3.4 - Prob. 14ATSCh. 3.4 - Prob. 6LTSCh. 3.4 - Prob. 15PTSCh. 3.4 - Prob. 16ATSCh. 3.4 - Prob. 17ATSCh. 3.4 - Prob. 7LTSCh. 3.4 - Prob. 18PTSCh. 3.4 - Prob. 19PTSCh. 3.4 - Prob. 20ATSCh. 3.4 - Prob. 8LTSCh. 3.4 - Prob. 21PTSCh. 3.4 - Prob. 22ATSCh. 3.4 - Prob. 9LTSCh. 3.4 - Prob. 23PTSCh. 3.4 - Prob. 24PTSCh. 3.4 - Prob. 25ATSCh. 3.4 - Prob. 26ATSCh. 3.5 - Prob. 10LTSCh. 3.5 - Prob. 27PTSCh. 3.5 - The development of chemical sensors that can...Ch. 3.5 - Determine whether H2O would be a suitable reagent...Ch. 3.5 - Prob. 29PTSCh. 3.5 - Prob. 30ATSCh. 3.7 - Prob. 31CCCh. 3.9 - Prob. 12LTSCh. 3.9 - Prob. 32PTSCh. 3.9 - Prob. 33ATSCh. 3 - Prob. 34PPCh. 3 - Prob. 35PPCh. 3 - Prob. 36PPCh. 3 - Prob. 37PPCh. 3 - Prob. 38PPCh. 3 - Prob. 39PPCh. 3 - Prob. 40PPCh. 3 - Prob. 41PPCh. 3 - Prob. 42PPCh. 3 - Prob. 43PPCh. 3 - Prob. 44PPCh. 3 - Prob. 45PPCh. 3 - Prob. 46PPCh. 3 - Prob. 47PPCh. 3 - Prob. 48PPCh. 3 - Prob. 49IPCh. 3 - Prob. 50IPCh. 3 - Prob. 51IPCh. 3 - Prob. 52IPCh. 3 - Prob. 53IPCh. 3 - Prob. 54IPCh. 3 - Prob. 55IPCh. 3 - Prob. 56IPCh. 3 - Prob. 57IPCh. 3 - Prob. 58IPCh. 3 - Prob. 59IPCh. 3 - Prob. 60IPCh. 3 - Prob. 61IPCh. 3 - Prob. 62IPCh. 3 - Prob. 63IPCh. 3 - Prob. 64IPCh. 3 - The bengamides are a series of natural products...Ch. 3 - Prob. 66IPCh. 3 - Prob. 67IPCh. 3 - Prob. 68IPCh. 3 - Prob. 69IPCh. 3 - Prob. 70CPCh. 3 - Prob. 71CPCh. 3 - Prob. 72CPCh. 3 - Prob. 73CP
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