FOUNDATIONS OF COLLEGE CHEM +KNEWTONALTA
FOUNDATIONS OF COLLEGE CHEM +KNEWTONALTA
15th Edition
ISBN: 9781119797807
Author: Hein
Publisher: WILEY
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Chapter 3, Problem 3PE

(a)

Interpretation Introduction

Interpretation:

The elements present in potassium iodide (KI) have to be given.

(b)

Interpretation Introduction

Interpretation:

The elements present in sodium carbonate (Na2CO3) have to be given.

(c)

Interpretation Introduction

Interpretation:

The elements present in aluminium oxide (Al2O3) have to be given.

(d)

Interpretation Introduction

Interpretation:

The elements present in calcium bromide (CaBr2) have to be given.

(e)

Interpretation Introduction

Interpretation:

The elements present in acetic acid (HC2H3O2) have to be given.

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(a) Verify that the lattice energies of the alkali metal iodides are inversely proportional to the distances between the ions in MI (M = alkali metal) by plotting the lattice energies given below against the internuclear distances dMI. Is the correlation good? Would a better fit be obtained by plotting the lattice energies as a function of (1 — d*/d)/d, as theoretically suggested, with d* = 34.5 pm? You must use a standard graphing program to plot the graph. It generates an equation for the line and calculates a correlation coefficient. (b) From the graph obtained in (a), estimate the lattice energy of silver iodide. (c) Compare the results of (b) with the experimental value of 886 kJ/mol. If they do not agree, explain the deviation.
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