BIOCHEMISTRY BOOKS ALC&MOD MST/ET PKG
BIOCHEMISTRY BOOKS ALC&MOD MST/ET PKG
1st Edition
ISBN: 9780134172507
Author: APPLING
Publisher: Pearson Education
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Chapter 3, Problem 3P

The decomposition of crystalline N2O5 N 2 O 5 (s) 2NO 2 (g) + 1 2 O 2 (g) is an example of a reaction that is thermodynamically favored, even though it absorbs heat. At 25o C we have the following values for the standard state enthalpy and free energy changes of the reaction:

Δ H = + 109kJ/m01
Δ Go = -30.5kJ/m01

a. Calculate Δ So at 25o C.

b. Why is the entropy change so favorable for this reaction?

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7. Which one is the major organic product obtained from the following reaction? CHO COOH CH₂OH CHO COOH H- -OH H₂ H- OH H- -OH H- -OH Ni HO -H HO -H HO- -H HO- H HO- H H- -OH H- -OH H- -OH H -OH H- -OH H- -OH H- -OH H- -OH H- -OH H -OH CH₂OH CH₂OH CH₂OH CH₂OH COOH A B C D
4. The compound on the right is- B) a ketopentose C) an aldohexose A) an aldopentose D) a ketohexose E) a ketoheptose OH OH CH2OH OH
12. When glutamic acid is heated to 180°C., it loses a molecule of water to form a lactam. The bond that creates the lactam is an amide bond that forms between the amino nitrogen and the carbon of the side chain -COOH group. What is the most reasonable structure for this lactam? (NOTE: The structure of glutamic acid is shown in Question 1.) COOH COOH ا کچھ جو کچھ C D COOH B COOH E COOH
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