The expression of ( ∂ S / ∂ V ) T for the given equations of state has to be derived. The change in entropy of for perfect gas and van der Waals gas has to be compared for isothermal expansion and the conclusion of the comparison has to be rationalized. Concept introduction: The randomness present in the system is called its entropy. It is an extensive property. At equilibrium, the entropy of the system is zero. It is denoted by S . The entropy that is measured under the standard conditions of temperature is known as standard entropy. The standard entropy change is denoted by Δ S .

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Answer 1

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Chapter 3, Problem 3E.4P

Interpretation Introduction

Interpretation: The expression of (∂S/∂V)T for the given equations of state has to be derived. The change in entropy of for perfect gas and van der Waals gas has to be compared for isothermal expansion and the conclusion of the comparison has to be rationalized.

Concept introduction: The randomness present in the system is called its entropy. It is an extensive property. At equilibrium, the entropy of the system is zero. It is denoted by S. The entropy that is measured under the standard conditions of temperature is known as standard entropy. The standard entropy change is denoted by ΔS.

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Answer 2

Question

Chapter 3, Problem 3E.4P

Interpretation Introduction

Interpretation: The expression of (∂S/∂V)T for the given equations of state has to be derived. The change in entropy of for perfect gas and van der Waals gas has to be compared for isothermal expansion and the conclusion of the comparison has to be rationalized.

Concept introduction: The randomness present in the system is called its entropy. It is an extensive property. At equilibrium, the entropy of the system is zero. It is denoted by S. The entropy that is measured under the standard conditions of temperature is known as standard entropy. The standard entropy change is denoted by ΔS.

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Answer 3

Question

Chapter 3, Problem 3E.4P

Interpretation Introduction

Interpretation: The expression of (∂S/∂V)T for the given equations of state has to be derived. The change in entropy of for perfect gas and van der Waals gas has to be compared for isothermal expansion and the conclusion of the comparison has to be rationalized.

Concept introduction: The randomness present in the system is called its entropy. It is an extensive property. At equilibrium, the entropy of the system is zero. It is denoted by S. The entropy that is measured under the standard conditions of temperature is known as standard entropy. The standard entropy change is denoted by ΔS.

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Answer 4

Question

Chapter 3, Problem 3E.4P

Interpretation Introduction

Interpretation: The expression of (∂S/∂V)T for the given equations of state has to be derived. The change in entropy of for perfect gas and van der Waals gas has to be compared for isothermal expansion and the conclusion of the comparison has to be rationalized.

Concept introduction: The randomness present in the system is called its entropy. It is an extensive property. At equilibrium, the entropy of the system is zero. It is denoted by S. The entropy that is measured under the standard conditions of temperature is known as standard entropy. The standard entropy change is denoted by ΔS.

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Answer 5

Chapter 3, Problem 3E.4P

Interpretation Introduction

Interpretation: The expression of (∂S/∂V)T for the given equations of state has to be derived. The change in entropy of for perfect gas and van der Waals gas has to be compared for isothermal expansion and the conclusion of the comparison has to be rationalized.

Concept introduction: The randomness present in the system is called its entropy. It is an extensive property. At equilibrium, the entropy of the system is zero. It is denoted by S. The entropy that is measured under the standard conditions of temperature is known as standard entropy. The standard entropy change is denoted by ΔS.

Answer 6

Chapter 3, Problem 3E.4P

Interpretation Introduction

Interpretation: The expression of (∂S/∂V)T for the given equations of state has to be derived. The change in entropy of for perfect gas and van der Waals gas has to be compared for isothermal expansion and the conclusion of the comparison has to be rationalized.

Concept introduction: The randomness present in the system is called its entropy. It is an extensive property. At equilibrium, the entropy of the system is zero. It is denoted by S. The entropy that is measured under the standard conditions of temperature is known as standard entropy. The standard entropy change is denoted by ΔS.

Answer 7

Chapter 3, Problem 3E.4P

Interpretation Introduction

Interpretation: The expression of (∂S/∂V)T for the given equations of state has to be derived. The change in entropy of for perfect gas and van der Waals gas has to be compared for isothermal expansion and the conclusion of the comparison has to be rationalized.

Concept introduction: The randomness present in the system is called its entropy. It is an extensive property. At equilibrium, the entropy of the system is zero. It is denoted by S. The entropy that is measured under the standard conditions of temperature is known as standard entropy. The standard entropy change is denoted by ΔS.

Answer 8

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Answer 11

Ch. 3 - Prob. 3A.1ST Ch. 3 - Prob. 3B.1ST Ch. 3 - Prob. 3C.1ST Ch. 3 - Prob. 3D.1ST Ch. 3 - Prob. 3D.2ST Ch. 3 - Prob. 3E.1ST Ch. 3 - Prob. 3E.2ST Ch. 3 - Prob. 3E.3ST Ch. 3 - Prob. 3A.1DQ Ch. 3 - Prob. 3A.2DQ

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