PHYSICAL CHEMISTRY. VOL.1+2 (LL)(11TH)
11th Edition
ISBN: 9780198826910
Author: ATKINS
Publisher: Oxford University Press
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Chapter 3, Problem 3A.5P
(a)
Interpretation Introduction
Interpretation:
The reason for the fact that it is impossible to transfer heat from a cold source to the hot sink without some work done has to be stated.
Concept introduction:
The term entropy is used to represent the randomness in a system. When a system moves from an ordered arrangement to a less order arrangement, then the entropy of the system increases. The second law of
(b)
Interpretation Introduction
Interpretation:
The magnitude of work need to transfer heat of magnitude
Concept introduction:
The efficiency of a machine is defined as the ratio of fruitful output and total input. The efficiency of a machine is used to determine the effectiveness of the machine. When the efficiency of the machine is high, the machine is very efficient. The efficiency of a machine cannot be
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Transmitance
3. Which one of the following compounds corresponds to
this IR spectrum?
Point out the absorption band(s) that helped you
decide.
OH
H3C
OH
H₂C
CH3
H3C
CH3
H3C
INFRARED SPECTRUM
0.8-
0.6
0.4-
0.2
3000
2000
1000
Wavenumber (cm-1)
4. Consider this compound:
H3C
On the structure above, label the different types of H's
as A, B, C, etc.
In table form, list the labeled signals, and for each
one state the number of hydrogens, their shifts, and the
splitting you would observe for these hydrogens in the ¹H
NMR spectrum.
Label
# of hydrogens
splitting
Shift (2)
None
Chapter 3 Solutions
PHYSICAL CHEMISTRY. VOL.1+2 (LL)(11TH)
Ch. 3 - Prob. 3A.1STCh. 3 - Prob. 3B.1STCh. 3 - Prob. 3C.1STCh. 3 - Prob. 3D.1STCh. 3 - Prob. 3D.2STCh. 3 - Prob. 3E.1STCh. 3 - Prob. 3E.2STCh. 3 - Prob. 3E.3STCh. 3 - Prob. 3A.1DQCh. 3 - Prob. 3A.2DQ
Ch. 3 - Prob. 3A.1AECh. 3 - Prob. 3A.1BECh. 3 - Prob. 3A.2AECh. 3 - Prob. 3A.2BECh. 3 - Prob. 3A.3AECh. 3 - Prob. 3A.3BECh. 3 - Prob. 3A.4AECh. 3 - Prob. 3A.4BECh. 3 - Prob. 3A.5AECh. 3 - Prob. 3A.5BECh. 3 - Prob. 3A.6AECh. 3 - Prob. 3A.6BECh. 3 - Prob. 3A.1PCh. 3 - Prob. 3A.2PCh. 3 - Prob. 3A.3PCh. 3 - Prob. 3A.4PCh. 3 - Prob. 3A.5PCh. 3 - Prob. 3A.6PCh. 3 - Prob. 3A.7PCh. 3 - Prob. 3B.1DQCh. 3 - Prob. 3B.1AECh. 3 - Prob. 3B.1BECh. 3 - Prob. 3B.2AECh. 3 - Prob. 3B.2BECh. 3 - Prob. 3B.3AECh. 3 - Prob. 3B.3BECh. 3 - Prob. 3B.4AECh. 3 - Prob. 3B.4BECh. 3 - Prob. 3B.5AECh. 3 - Prob. 3B.5BECh. 3 - Prob. 3B.6AECh. 3 - Prob. 3B.6BECh. 3 - Prob. 3B.7AECh. 3 - Prob. 3B.7BECh. 3 - Prob. 3B.1PCh. 3 - Prob. 3B.2PCh. 3 - Prob. 3B.3PCh. 3 - Prob. 3B.4PCh. 3 - Prob. 3B.5PCh. 3 - Prob. 3B.6PCh. 3 - Prob. 3B.7PCh. 3 - Prob. 3B.8PCh. 3 - Prob. 3B.9PCh. 3 - Prob. 3B.10PCh. 3 - Prob. 3B.12PCh. 3 - Prob. 3C.1DQCh. 3 - Prob. 3C.1AECh. 3 - Prob. 3C.1BECh. 3 - Prob. 3C.2AECh. 3 - Prob. 3C.2BECh. 3 - Prob. 3C.3AECh. 3 - Prob. 3C.3BECh. 3 - Prob. 3C.1PCh. 3 - Prob. 3C.2PCh. 3 - Prob. 3C.4PCh. 3 - Prob. 3C.5PCh. 3 - Prob. 3C.6PCh. 3 - Prob. 3C.7PCh. 3 - Prob. 3C.8PCh. 3 - Prob. 3C.9PCh. 3 - Prob. 3C.10PCh. 3 - Prob. 3D.1DQCh. 3 - Prob. 3D.2DQCh. 3 - Prob. 3D.1AECh. 3 - Prob. 3D.1BECh. 3 - Prob. 3D.2AECh. 3 - Prob. 3D.2BECh. 3 - Prob. 3D.3AECh. 3 - Prob. 3D.3BECh. 3 - Prob. 3D.4AECh. 3 - Prob. 3D.4BECh. 3 - Prob. 3D.5AECh. 3 - Prob. 3D.5BECh. 3 - Prob. 3D.1PCh. 3 - Prob. 3D.2PCh. 3 - Prob. 3D.3PCh. 3 - Prob. 3D.4PCh. 3 - Prob. 3D.5PCh. 3 - Prob. 3D.6PCh. 3 - Prob. 3E.1DQCh. 3 - Prob. 3E.2DQCh. 3 - Prob. 3E.1AECh. 3 - Prob. 3E.1BECh. 3 - Prob. 3E.2AECh. 3 - Prob. 3E.2BECh. 3 - Prob. 3E.3AECh. 3 - Prob. 3E.3BECh. 3 - Prob. 3E.4AECh. 3 - Prob. 3E.4BECh. 3 - Prob. 3E.5AECh. 3 - Prob. 3E.5BECh. 3 - Prob. 3E.6AECh. 3 - Prob. 3E.6BECh. 3 - Prob. 3E.1PCh. 3 - Prob. 3E.2PCh. 3 - Prob. 3E.3PCh. 3 - Prob. 3E.4PCh. 3 - Prob. 3E.5PCh. 3 - Prob. 3E.6PCh. 3 - Prob. 3E.8PCh. 3 - Prob. 3.1IACh. 3 - Prob. 3.2IA
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