Introduction to Chemistry, Special Edition
6th Edition
ISBN: 9781337035934
Author: Cracolice/Peters
Publisher: Cengage Learning
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Textbook Question
Chapter 3, Problem 3E
Write the following numbers in ordinary decimal form:
(a) 5.12 x 106, (b) 8.04 x 10-7, (c) 1.92 x 1021.
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Redraw the flowchart
redraw the flowchart with boxes and molecules written in them
Part I.
a) Elucidate
the structure of compound A using the following information.
• mass spectrum: m+ = 102, m/2=57
312=29
• IR spectrum:
1002.5
% TRANSMITTANCE
Ngg
50
40
30
20
90
80
70
60
MICRONS
5
8
9 10
12
13
14 15 16
19
1740 cm
M
10
0
4000
3600
3200
2800
2400
2000
1800
1600
13
• CNMR
'H
-NMR
Peak
8
ppm (H)
Integration
multiplicity
a
1.5 (3H)
triplet
b
1.3
1.5 (3H)
triplet
C
2.3
1 (2H)
quartet
d
4.1
1 (2H)
quartet
& ppm (c)
10
15
28
60
177 (C=0)
b) Elucidate the structure of compound B using the following information
13C/DEPT NMR 150.9 MHz
IIL
1400
WAVENUMBERS (CM-1)
DEPT-90
DEPT-135
85 80 75
70
65
60
55
50
45 40
35
30 25 20
ppm
1200
1000
800
600
400
Chapter 3 Solutions
Introduction to Chemistry, Special Edition
Ch. 3 - Equivalency, conversion factor, solving...Ch. 3 - Metric system, SI units, derived unit, base unitCh. 3 - Prob. 3CLECh. 3 - Prob. 4CLECh. 3 - Prob. 5CLECh. 3 - Write the following numbers in scientific...Ch. 3 - Prob. 2ECh. 3 - Write the following numbers in ordinary decimal...Ch. 3 - Write the ordinary form of the following numbers:...Ch. 3 - Prob. 5E
Ch. 3 - Prob. 6ECh. 3 - Prob. 7ECh. 3 - Prob. 8ECh. 3 - Prob. 9ECh. 3 - Prob. 10ECh. 3 - Complete the following operations:...Ch. 3 - Prob. 12ECh. 3 - What is the mathematical criterion for two...Ch. 3 - Sixty seconds and minute are equivalent...Ch. 3 - Write the equivalency for each conversion...Ch. 3 - Write the equivalency for each conversion...Ch. 3 - Write the equivalency and both conversion factors...Ch. 3 - Write the equivalency and both conversion factors...Ch. 3 - Prob. 19ECh. 3 - Prob. 20ECh. 3 - How long will it take to travel the 406 miles...Ch. 3 - A student who is driving home for the holidays...Ch. 3 - How many minutes does it take a car traveling 88...Ch. 3 - How many days are in 89 weeks?Ch. 3 - What will be the cost in dollars for nails for a...Ch. 3 - A student working for Stop and Shop is packing...Ch. 3 - An American tourist in Mexico was startled to see...Ch. 3 - How many nickels should you receive in exchange...Ch. 3 - How many weeks are in a decade?Ch. 3 - How many seconds are in the month of January?Ch. 3 - List at least two measurements that would be...Ch. 3 - List at least two measurements that would be made...Ch. 3 - A woman stands on a scale in an elevator in a tall...Ch. 3 - A person can pick up a large rock that is...Ch. 3 - What is the metric unit of length?Ch. 3 - What is the metric unit of mass?Ch. 3 - Kilo buck is a slang expression for a sum of...Ch. 3 - What is the difference between the terms kilo unit...Ch. 3 - One milliliter is equal to how many liters?Ch. 3 - How many centimeters are in a meter?Ch. 3 - Which unit, megagrams or grams, would be more...Ch. 3 - What is the name of the unit whose symbol is nm?...Ch. 3 - a 5.74 cg to g, b 1.41 kg to g, c 4.54 x 108 cg to...Ch. 3 - a 15.3 kg to g and mg, b 80.5 g to kg and mg, c...Ch. 3 - a 21.7 m to cm, b 517 m to km, c 0.666 km to cmCh. 3 - a 90.4 mm to m and cm, b 11.9 m to mm and cm, c...Ch. 3 - a 494 cm3 to mL, b 1.91 L to mL, c 874 cm3 to LCh. 3 - a 90.8 mL to L and cm3, b 16.9 L to mL and cm3, c...Ch. 3 - a 7.11 hg to g, b 5.27 x 107 m to pm, c 3.63 x 106...Ch. 3 - a 0.194 Gg to g, b 5.66 nm to m, c 0.00481 Mm to...Ch. 3 - State the volume of liquid in each graduated...Ch. 3 - How long is the object measured with the rulers...Ch. 3 - The same volume of liquid is in each measuring...Ch. 3 - Why is the length of the line in the illustration...Ch. 3 - Prob. 55ECh. 3 - Prob. 56ECh. 3 - Prob. 57ECh. 3 - a 52.20 mL helium, b 17.963 g nitrogen, c 78.45 mg...Ch. 3 - A moving-van crew picks up the following items: a...Ch. 3 - A solution is prepared by dissolving 2.86 grams of...Ch. 3 - Prob. 61ECh. 3 - An empty beaker has a mass of 94.33 grams. After...Ch. 3 - The mole is the SI unit for the amount of a...Ch. 3 - Exactly 1 liter of a solution contains 31.4 grams...Ch. 3 - An empty beaker with a mass of 42.3 g is filled...Ch. 3 - Use the definition density ; mass 4 volume to...Ch. 3 - 0.0715 gal = _____ c m 3 2.27 x 10 4 mL = _____ g...Ch. 3 - 19.3 L = _____ gal 0 .461 qt = _____ LCh. 3 - A popular breakfast cereal comes in a box...Ch. 3 - A copy of your chemistry textbook is found to have...Ch. 3 - The payload of a small pickup truck is 1450 pounds...Ch. 3 - The Hope diamond is the worlds largest blue...Ch. 3 - There is 115 mg of calcium in a 100-g serving of...Ch. 3 - The largest recorded difference of weight between...Ch. 3 - An Austrian boxer reads 69.1 kg when he steps on a...Ch. 3 - A woman gives birth to a 7.5-lb baby. How would a...Ch. 3 - The height of Angel Falls in Venezuela is 979 m....Ch. 3 - A penny is found to have a length of 1.97...Ch. 3 - The Willis Tower in Chicago is 1451 feet tall. How...Ch. 3 - What is the length of the Mississippi River in...Ch. 3 - The summit of Mount Everest is 29, 029 ft above...Ch. 3 - One of the smallest brilliant-cut diamonds ever...Ch. 3 - An office building is heated by oil-fired burners...Ch. 3 - A gas can is found to have a volume of 9.10...Ch. 3 - Celsius Fahrenheit Kelvin 69 -29 111 36 358 -141Ch. 3 - Celsius Fahrenheit Kelvin 40 590 -13 229 440 -314Ch. 3 - Normal body temperature is 98.6 F. What is this...Ch. 3 - In the winter, a heated home in the Northeast...Ch. 3 - Energy conservationists suggest that air...Ch. 3 - The milting point of an unknown solid is...Ch. 3 - The worlds highest shade temperature was recorded...Ch. 3 - The boiling point of a liquid is calculated to be...Ch. 3 - Prob. 93ECh. 3 - Prob. 94ECh. 3 - Prob. 95ECh. 3 - Prob. 96ECh. 3 - Prob. 97ECh. 3 - Prob. 98ECh. 3 - Prob. 99ECh. 3 - Prob. 100ECh. 3 - Prob. 101ECh. 3 - Rank the substances in the photograph from least...Ch. 3 - Calculate the density of benzene, a liquid used in...Ch. 3 - A general chemistry student found a chunk of metal...Ch. 3 - Densities of gases are usually measured in grams...Ch. 3 - Prob. 106ECh. 3 - Ether, a well-known anesthetic, has a density of...Ch. 3 - Prob. 108ECh. 3 - Determine the mass of 2.0 L rubbing alcohol, which...Ch. 3 - Calculate the volume occupied by 15.4 grams of...Ch. 3 - The mass of the liquid in the graduated cylinder...Ch. 3 - Prob. 112ECh. 3 - Distinguish precisely and in scientific terms the...Ch. 3 - Determine whether each statement that follows is...Ch. 3 - How tall are you in a meters; b decimeters; c...Ch. 3 - What do you weigh in a milligrams; b grams; c...Ch. 3 - Standard printer and copier paper is the United...Ch. 3 - The density of aluminium is 2.7 g/cm3. An ecology...Ch. 3 - What is the average density of a single marble...Ch. 3 - A woman has just given birth to a bouncing 6 lb, 7...Ch. 3 - A students drivers license lists her height as 5...Ch. 3 - How many grams of milk are in a 12.0 fluid-ounce...Ch. 3 - The fuel tank in an automobile has a capacity of...Ch. 3 - A welcome rainfall caused the temperature to drop...Ch. 3 - At high noon on the lunar equator the temperature...Ch. 3 - A recipe calls for a quarter cup of butter....Ch. 3 - Prob. 127ECh. 3 - In Active Example 3-29 you calculated that you...Ch. 3 - Write each of the following in scientific...Ch. 3 - Write each of the following numbers in ordinary...Ch. 3 - Prob. 3PECh. 3 - Prob. 4PECh. 3 - How many seconds are in 12 minutes?Ch. 3 - Prob. 6PECh. 3 - Prob. 7PECh. 3 - Prob. 8PECh. 3 - Prob. 9PECh. 3 - Prob. 10PECh. 3 - Prob. 11PECh. 3 - Prob. 12PECh. 3 - What is the volume of liquid in the buret in the...Ch. 3 - Prob. 14PECh. 3 - Round off each of the following quantities to two...Ch. 3 - Prob. 16PECh. 3 - At a certain temperature, 0.878 g of a pure liquid...Ch. 3 - Prob. 18PECh. 3 - Prob. 19PECh. 3 - Prob. 20PECh. 3 - Prob. 21PECh. 3 - Prob. 22PECh. 3 - Prob. 23PECh. 3 - Prob. 24PECh. 3 - The mass of a 50.00-milliliter sample of methanol...Ch. 3 - Prob. 26PECh. 3 - Determine the mass in kilograms of a lead brick...Ch. 3 - Prob. 28PECh. 3 - Prob. 29PE
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- • Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forwardNonearrow_forward
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