EBK BASIC CHEMISTRY
5th Edition
ISBN: 8220101472335
Author: Timberlake
Publisher: PEARSON
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Chapter 3, Problem 3.78AQAP
Interpretation Introduction
To determine: The energy value for the rice in terms of
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 3 Solutions
EBK BASIC CHEMISTRY
Ch. 3.1 - Classify each of the following as a pure substance...Ch. 3.1 - Classify each of the following as a pure substance...Ch. 3.1 - Classify each of the following pure substances as...Ch. 3.1 - Classify each of the following pure substances as...Ch. 3.1 - 3.5 Classify each of the following mixtures as...Ch. 3.1 - Classify each of the following mixtures as...Ch. 3.2 - Indicate whether each of the following describes a...Ch. 3.2 - Indicate whether each of the following describes a...Ch. 3.2 - Prob. 3.9QAPCh. 3.2 - Describe each of the following as a physical or...
Ch. 3.2 - Prob. 3.11QAPCh. 3.2 - What type of change, physical or chemical, takes...Ch. 3.2 - Prob. 3.13QAPCh. 3.2 - Describe each property of the element zirconium as...Ch. 3.3 - Prob. 3.15QAPCh. 3.3 - Prob. 3.16QAPCh. 3.3 - Prob. 3.17QAPCh. 3.3 - Prob. 3.18QAPCh. 3.3 - Prob. 3.19QAPCh. 3.3 - Prob. 3.20QAPCh. 3.4 - Discuss the changes in the potential and kinetic...Ch. 3.4 - Prob. 3.22QAPCh. 3.4 - Prob. 3.23QAPCh. 3.4 - Prob. 3.24QAPCh. 3.4 - Prob. 3.25QAPCh. 3.4 - Prob. 3.26QAPCh. 3.4 - Prob. 3.27QAPCh. 3.4 - Prob. 3.28QAPCh. 3.5 - If the same amount of heat is supplied to samples...Ch. 3.5 - Prob. 3.30QAPCh. 3.5 - Prob. 3.31QAPCh. 3.5 - Prob. 3.32QAPCh. 3.5 - Prob. 3.33QAPCh. 3.5 - Use the heat equation to calculate the energy, in...Ch. 3.5 - Calculate the mass, in grams, for each of the...Ch. 3.5 - Prob. 3.36QAPCh. 3.5 - Prob. 3.37QAPCh. 3.5 - Prob. 3.38QAPCh. 3.6 - Calculate the kilocalories for each of the...Ch. 3.6 - Prob. 3.40QAPCh. 3.6 - Using the energy values for foods (see Table 3.7),...Ch. 3.6 - Prob. 3.42QAPCh. 3.6 - Prob. 3.43QAPCh. 3.6 - Prob. 3.44QAPCh. 3.6 - Prob. 3.45QAPCh. 3.6 - Prob. 3.46QAPCh. 3 - Prob. 3.47FUCh. 3 - Prob. 3.48FUCh. 3 - Prob. 3.49UTCCh. 3 - Prob. 3.50UTCCh. 3 - Prob. 3.51UTCCh. 3 - Prob. 3.52UTCCh. 3 - Prob. 3.53UTCCh. 3 - Prob. 3.54UTCCh. 3 - Prob. 3.55UTCCh. 3 - Prob. 3.56UTCCh. 3 - Prob. 3.57UTCCh. 3 - Prob. 3.58UTCCh. 3 - Prob. 3.59UTCCh. 3 - Prob. 3.60UTCCh. 3 - Prob. 3.61AQAPCh. 3 - Prob. 3.62AQAPCh. 3 - Prob. 3.63AQAPCh. 3 - Prob. 3.64AQAPCh. 3 - Prob. 3.65AQAPCh. 3 - Prob. 3.66AQAPCh. 3 - Prob. 3.67AQAPCh. 3 - Prob. 3.68AQAPCh. 3 - Prob. 3.69AQAPCh. 3 - Prob. 3.70AQAPCh. 3 - Prob. 3.71AQAPCh. 3 - Prob. 3.72AQAPCh. 3 - Prob. 3.73AQAPCh. 3 - Prob. 3.74AQAPCh. 3 - 3.83 On a hot day, the bleach sand gets hot but...Ch. 3 - Prob. 3.76AQAPCh. 3 - Prob. 3.77AQAPCh. 3 - Prob. 3.78AQAPCh. 3 - Prob. 3.79AQAPCh. 3 - Prob. 3.80AQAPCh. 3 - Prob. 3.81AQAPCh. 3 - Use the heat equation to calculate the energy, in...Ch. 3 - Prob. 3.83AQAPCh. 3 - Prob. 3.84AQAPCh. 3 - Prob. 3.85AQAPCh. 3 - Prob. 3.86AQAPCh. 3 - If you want to lose 1 lb of “body fat,” which is...Ch. 3 - Prob. 3.88AQAPCh. 3 - Prob. 3.89AQAPCh. 3 - Prob. 3.90AQAPCh. 3 - Prob. 3.91CQCh. 3 - Prob. 3.92CQCh. 3 - Prob. 3.93CQCh. 3 - Prob. 3.94CQCh. 3 - Prob. 3.95CQCh. 3 - Prob. 3.96CQCh. 3 - Prob. 3.97CQCh. 3 - Prob. 3.98CQCh. 3 - Prob. 1CICh. 3 - Prob. 2CICh. 3 - Prob. 3CICh. 3 - Prob. 4CICh. 3 - Prob. 5CICh. 3 - Prob. 6CI
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