ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
6th Edition
ISBN: 9781319306977
Author: LOUDON
Publisher: INTER MAC
Question
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Chapter 3, Problem 3.58AP
Interpretation Introduction

(a)

Interpretation:

The reason as to why the concentration of aqueous solution, 103M of either HI or HCl in water gives the same pH reading of 3 is to be stated.

Concept introduction:

Strong acids dissociate in water completely. They give hydrogen ions. These hydrogen ions combine with water to form hydronium ions. Strong acids conduct electricity due to the presence of free ions.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the solution of the stronger base doesn’t have a higher pH is to be stated.

Concept introduction:

Strong base dissociates in water completely. They give more hydroxide ions than hydrogen ions. The relation between pOH and pH is given by an expression.

pOH+pH=14

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1. Answer the questions about the following reaction: (a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this reaction. Be sure to include any relevant stereochemistry in the product structure. + SK F Br + (b) In which solvent would this reaction proceed the fastest (Circle one) Methanol Acetone (c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest other products that are formed? Draw them in the box provided.
3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in the reactant before being able to draw the arrows corresponding to product formation. A. B. Rearrangement ΘΗ
2. Draw the arrows required to make the following reactions occur. Please ensure your arrows point from exactly where you want to exactly where you want. If it is unclear from where arrows start or where they end, only partial credit will be given. Note: You may need to draw in lone pairs before drawing the arrows. A. B. H-Br 人 C Θ CI H Cl Θ + Br O
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