Inorganic Chemistry
Inorganic Chemistry
5th Edition
ISBN: 9781292134147
Author: Housecroft, Catherine E.
Publisher: Pearson,
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Chapter 3, Problem 34P
Interpretation Introduction

Interpretation:

Meaning of the terms (a) chiral, (b) enantiomer and (c) helical chain is to be explained.

Concept Introduction:

If two species have the same molecular formula and same atom connectivity, but differ in the spatial arrangement of different atoms or groups about a central atom or a double bond, then the compounds are stereoisomers.

Chiral molecules can rotate plane of plane-polarized light and this property is known as optical activity and the two mirror images are known as optical isomers.

Optical isomers are also known as enantiomers.

Chiral molecules with one or more stereo-centre can be enantiomers.

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Using the general properties of equilibrium constants At a certain temperature, the equilibrium constant K for the following reaction is 0.84: H2(g) + 2(g) 2 HI(g) = Use this information to complete the following table. Suppose a 34. L reaction vessel is filled with 0.79 mol of HI. What can you say about the composition of the mixture in the vessel at equilibrium? There will be very little H2 and 12. ☐ x10 There will be very little HI. Neither of the above is true. What is the equilibrium constant for the following reaction? Be sure your answer has the correct number of significant digits. 2 HI(g) H₂(9)+12(9) K = What is the equilibrium constant for the following reaction? Be sure your answer has the correct number of significant digits. 2 H2(g)+212(9) 4 HI(g) K = ☐ ☑
Predicting the qualitative acid-base properties of salts Consider the following data on some weak acids and weak bases: base acid Κα Kb name formula name formula hydrocyanic acid - 10 HCN 4.9 × 10 pyridine C₂H₂N 1.7 × 10 9 acetic acid HCH3CO2 1.8 × 10 5 hydroxylamine HONH2 1.1 × 10¯ 8 Use this data to rank the following solutions in order of increasing pH. In other words, select a '1' next to the solution that will have the lowest pH, a '2' next to the solution that will have the next lowest pH, and so on. 0.1 M KCN solution pH choose one ✓ 0.1 M C5H5NHCI choose one ✓ 0.1 M NaCH3CO2 choose one ✓ 0.1 M HONH3Br ✓ choose one 1 (lowest) 2 3 4 (highest)
For this question please solve the first question. Please explain your thought process, the steps you took, and how you would tackle a similar problem. Thank you for your help!

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