(a) Interpretation: Whether two unique configurations about double bond are possible in the given compound is to be explained. Concept introduction: For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

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Answer 1

Question

Chapter 3, Problem 3.46P

Interpretation Introduction

(a)

Interpretation:

Whether two unique configurations about double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(b)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(c)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(d)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

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2. 200 LOD For an unknown compound with a molecular ion of 101 m/z: a. Use the molecular ion to propose at least two molecular formulas. (show your work) b. What is the DU for each of your possible formulas? (show your work) C. Solve the structure and assign each of the following spectra. 8 6 4 2 (ppm) 150 100 50 ō (ppm) 4000 3000 2000 1500 1000 500 HAVENUMBERI-11

Answer 2

Question

Chapter 3, Problem 3.46P

Interpretation Introduction

(a)

Interpretation:

Whether two unique configurations about double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(b)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(c)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(d)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

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Answer 3

Question

Chapter 3, Problem 3.46P

Interpretation Introduction

(a)

Interpretation:

Whether two unique configurations about double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(b)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(c)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(d)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

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Answer 4

Question

Chapter 3, Problem 3.46P

Interpretation Introduction

(a)

Interpretation:

Whether two unique configurations about double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(b)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(c)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(d)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

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Answer 5

Chapter 3, Problem 3.46P

Interpretation Introduction

(a)

Interpretation:

Whether two unique configurations about double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(b)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(c)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(d)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Answer 6

Chapter 3, Problem 3.46P

Interpretation Introduction

(a)

Interpretation:

Whether two unique configurations about double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Answer 7

Chapter 3, Problem 3.46P

Interpretation Introduction

(a)

Interpretation:

Whether two unique configurations about double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Answer 12

Interpretation Introduction

(d)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Answer 13

Interpretation Introduction

(d)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 3 - Prob. 3.1P Ch. 3 - Prob. 3.2P Ch. 3 - Prob. 3.3P Ch. 3 - Prob. 3.4P Ch. 3 - Prob. 3.5P Ch. 3 - Prob. 3.6P Ch. 3 - Prob. 3.7P Ch. 3 - Prob. 3.8P Ch. 3 - Prob. 3.9P Ch. 3 - Prob. 3.10P

Solution Summary: The author explains that two unique configurations about the double bond are not possible in the given structure.

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Chapter 3 Solutions