(a) Interpretation: Two distinct configurations of the molecule are to be determined. Concept introduction: The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

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Answer 1

Question

Chapter 3, Problem 3.24P

Interpretation Introduction

(a)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Interpretation Introduction

(b)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Interpretation Introduction

(c)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Interpretation Introduction

(d)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

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How many signals do you expect in the H NMR spectrum for this molecule? Br Br Write the answer below. Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H atoms that would contribute to the same signal as the H already highlighted red. Note for advanced students: In this question, any multiplet is counted as one signal. Number of signals in the 'H NMR spectrum. For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional Hs to color in top molecule For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional Hs to color in bottom molecule

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Answer 2

Question

Chapter 3, Problem 3.24P

Interpretation Introduction

(a)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Interpretation Introduction

(b)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Interpretation Introduction

(c)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Interpretation Introduction

(d)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

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Answer 3

Question

Chapter 3, Problem 3.24P

Interpretation Introduction

(a)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Interpretation Introduction

(b)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Interpretation Introduction

(c)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Interpretation Introduction

(d)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

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Answer 4

Question

Chapter 3, Problem 3.24P

Interpretation Introduction

(a)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Interpretation Introduction

(b)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Interpretation Introduction

(c)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Interpretation Introduction

(d)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

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Answer 5

Chapter 3, Problem 3.24P

Interpretation Introduction

(a)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Interpretation Introduction

(b)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Interpretation Introduction

(c)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Interpretation Introduction

(d)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Answer 6

Chapter 3, Problem 3.24P

Interpretation Introduction

(a)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Answer 7

Chapter 3, Problem 3.24P

Interpretation Introduction

(a)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Answer 12

Interpretation Introduction

(d)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Answer 13

Interpretation Introduction

(d)

Interpretation:

Two distinct configurations of the molecule are to be determined.

Concept introduction:

The double bonded carbon will have two distinct configurations if one atom of the double bond possesses two different atoms or groups attached to it. A double bonded carbon will not have two distinct configurations if one atom of the double bond possesses two similar atoms or groups attached to it.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 3 - Prob. 3.1P Ch. 3 - Prob. 3.2P Ch. 3 - Prob. 3.3P Ch. 3 - Prob. 3.4P Ch. 3 - Prob. 3.5P Ch. 3 - Prob. 3.6P Ch. 3 - Prob. 3.7P Ch. 3 - Prob. 3.8P Ch. 3 - Prob. 3.9P Ch. 3 - Prob. 3.10P

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Chapter 3 Solutions