Problem 3.1E: Decide whether the following processes will be spontaneous, and why. The why can be general, not... Problem 3.2E: Try to find one additional example of a spontaneous process that is in fact endothermic that is, it... Problem 3.3E: Consider the following quantities for a Carnot-type cycle: Step 1: q=+850J,w=850J. Step 2:... Problem 3.4E: Consider the following quantities for a four-step cycle: Step 1: q=+445J,w=445J. Step 2: q=0,w=99J.... Problem 3.5E: What is the temperature of the low-temperature reservoir of a process that has an efficiency of... Problem 3.6E: What is the temperature of the high - temperature reservoir of a process that has an efficiency of... Problem 3.7E Problem 3.8E: Explain why the high-temperature reservoir of a heat engine must, indeed, be higher in temperature... Problem 3.9E: Superheated steam is steam with a temperature greater than 100C. Explain the advantages of using... Problem 3.10E Problem 3.11E: The Carnot cycle is defined as having a certain specific first step, the isothermal expansion of a... Problem 3.12E: In thermodynamics, the pathway in a pressure-volume diagram for an adiabatic change is called an... Problem 3.13E: A refrigerator is the reverse of an engine: Work is performed to remove heat from a system, making... Problem 3.14E: Efficiency is given by equations 3.5, 3.6, and 3.10. Although we deal mostly with ideal gases in the... Problem 3.15E: What is the entropy change for an ideal Carnot cycle? Explain your answer. Problem 3.16E: What is the entropy change for the melting of 3.87moles of bismuth at its melting point of 271.3C?... Problem 3.17E: What is the entropy change for the solidification of 1.00oz.(28.3g) of liquid gold at 1064C? The... Problem 3.18E: Explain why the statement No process is 100 efficient is not the best statement of the second law of... Problem 3.19E: What is the change in entropy of 1.00mole of water as it is heated reversibly from 0C to 100C?... Problem 3.20E Problem 3.21E: One mole of He warms up irreversibly at constant volume from 45C to 55C. Is the change in entropy... Problem 3.22E: Consider a monatomic ideal gas in a piston chamber, where the initial volume is 2.00L and the... Problem 3.23E: A 0.500-mol sample of an ideal gas has an initial temperature of 298K. It is compressed from an... Problem 3.24E: SO2 in a piston chamber kept in a constant-temperature bath at 25.0C expands from 25.0mL to 75.0mL... Problem 3.25E: A normal breath has a volume of about 1L. The pressure exerted by the lungs to draw air in is about... Problem 3.26E: An automobile tire contains 15.6L of air at 46.0psi absolute and 22.0C. What is the entropy change... Problem 3.27E: An automobile tire contains 15.6L of air at 46.0psi absolute and 22.0C. After driving around a... Problem 3.28E: A sample of ideal gas from a compressed gas cylinder goes from 230atm to 1atm, with a concurrent... Problem 3.29E Problem 3.30E: In Example 3.5, a heat capacity of 20.78J/molK was used, which is 5/2R. Is this value of heat... Problem 3.31E Problem 3.32E: 4.00L of Ar and 2.50L of He, each at 298K and 1.50atm, were mixed isothermally and isobarically. The... Problem 3.33E: Dentists might use a mixture of 40N2O and 60O2 as an initial anesthetic of nitrous oxide although... Problem 3.34E: A 5.33-g piece of Cu metal is heated to 99.7C in boiling water, then dropped into a calorimeter... Problem 3.35E: A sample of 1.00mol of silver at 150C is placed in contact with 1.00mol of silver at 0C. Calculate a... Problem 3.36E Problem 3.37E: What is the change in entropy when 2.22mol of water is heated from 25.0C to 100C? Assume that the... Problem 3.38E: Estimate the entropy change of an 800-lb engine (1lb=0.455kg) that goes from normal environmental... Problem 3.39E: Calculate the molar entropy change of the gas that accompanies the bursting of a balloon if the... Problem 3.40E: A normal breath is about 1L in volume. Assume you take a breath at sea level, where the pressure is... Problem 3.41E: The first law of thermodynamics is sometimes stated You cant win and the second law is stated... Problem 3.42E: Troutons rule states that the entropy of boiling at the normal point is 85J/molK. a Does the data... Problem 3.43E Problem 3.44E: Argue from Boltzmanns definition for entropy that S can never have a negative value. Hint: See... Problem 3.45E Problem 3.46E: Which system has the higher entropy? a A clean kitchen or a dirty kitchen? b A blackboard with... Problem 3.47E: Which system has the higher entropy? a 1g of solid Au at 1064K or 1g of liquid Au at 1064K? b 1 mole... Problem 3.48E: The absolute entropy of He at 298.15K is 126.04J/molK. What is its absolute entropy at 1000.00K?... Problem 3.49E: The absolute entropy of Kr at 298.15K is 163.97J/molK. What is its absolute entropy at 200.00K if... Problem 3.50E: The element helium is thought to remain a liquid at absolute zero. Solid helium can be made only by... Problem 3.51E: Order the following substances in order of increasing entropy: NaCl(solid), C(graphite), C(diamond),... Problem 3.52E: The molar entropy change for a process is 1.00J/molK. By what percentage has the number of possible... Problem 3.53E: What is the entropy change of a process if doubles in the course of the process? You will need to... Problem 3.54E: One mole of ideal gas expands isothermally and reversibly by 1.00L. In one case, the expansion... Problem 3.55E: Why isnt the entropy of elements in their standard pressure at normal that is, room temperatures... Problem 3.56E: Determine the entropy of formation, fS, of the following compounds. Assume 25C. a H2O(l) b H2O(g) c... Problem 3.57E: The thermite reaction has solid aluminum powder reacting with iron (III) oxide to make aluminum... Problem 3.58E Problem 3.59E: Determine the differences in the rxnS under standard conditions for the two following reactions:... Problem 3.60E: Calcium carbonate has two crystalline forms, called aragonite formed by mollusks for their shells... Problem 3.61E: The chemical formula for gasoline can be approximated as C8H18. The chemical reaction for the... Problem 3.62E Problem 3.63E Problem 3.64E: Plants take in CO2(g) and H2O(l) and make glucose, C6H12O6(s), and O2(g). Determine the standard... Problem 3.65E Problem 3.66E Problem 3.67E: Plots of Cp/T versus T are used to determine the entropy of a material, as the entropy value would... format_list_bulleted