Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Chapter 3, Problem 3.146QE
Interpretation Introduction
Interpretation:
The formula of iron (III) sulfate has to be written. The mass percentage of each element in the compound has to be calculated.
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 3 Solutions
Chemistry: Principles and Practice
Ch. 3 - Prob. 3.1QECh. 3 - Prob. 3.2QECh. 3 - Using solid circles for H atoms and open circles...Ch. 3 - Prob. 3.4QECh. 3 - Prob. 3.5QECh. 3 - How many objects are in 1 mol? What is the common...Ch. 3 - Prob. 3.7QECh. 3 - Prob. 3.8QECh. 3 - Prob. 3.11QECh. 3 - Describe an experiment that would enable someone...
Ch. 3 - Only the empirical formula can be calculated from...Ch. 3 - Prob. 3.14QECh. 3 - Prob. 3.15QECh. 3 - Prob. 3.16QECh. 3 - Prob. 3.17QECh. 3 - Prob. 3.18QECh. 3 - Prob. 3.19QECh. 3 - A mixture of sulfur dioxide and oxygen gas reacts...Ch. 3 - Prob. 3.21QECh. 3 - Prob. 3.22QECh. 3 - Prob. 3.23QECh. 3 - Prob. 3.24QECh. 3 - Prob. 3.25QECh. 3 - Prob. 3.26QECh. 3 - Prob. 3.27QECh. 3 - Prob. 3.28QECh. 3 - Prob. 3.29QECh. 3 - Prob. 3.30QECh. 3 - Prob. 3.31QECh. 3 - Prob. 3.32QECh. 3 - Prob. 3.33QECh. 3 - Prob. 3.34QECh. 3 - Prob. 3.35QECh. 3 - Prob. 3.36QECh. 3 - Acetone, (CH3)2CO, is an important industrial...Ch. 3 - Prob. 3.38QECh. 3 - Prob. 3.39QECh. 3 - Prob. 3.40QECh. 3 - Prob. 3.41QECh. 3 - Prob. 3.42QECh. 3 - Prob. 3.43QECh. 3 - Prob. 3.44QECh. 3 - Prob. 3.45QECh. 3 - Prob. 3.46QECh. 3 - Prob. 3.47QECh. 3 - Prob. 3.48QECh. 3 -
One of the ways to remove nitrogen monoxide gas,...Ch. 3 - Prob. 3.50QECh. 3 - Prob. 3.51QECh. 3 - Prob. 3.52QECh. 3 - Prob. 3.53QECh. 3 - Prob. 3.54QECh. 3 - Prob. 3.55QECh. 3 - Prob. 3.56QECh. 3 - Prob. 3.57QECh. 3 - Prob. 3.58QECh. 3 - Prob. 3.59QECh. 3 - Prob. 3.60QECh. 3 - Prob. 3.61QECh. 3 - Prob. 3.62QECh. 3 - Prob. 3.63QECh. 3 - Prob. 3.64QECh. 3 - Prob. 3.65QECh. 3 - Prob. 3.66QECh. 3 - Prob. 3.67QECh. 3 - Prob. 3.68QECh. 3 - (a) Calculate the mass, in grams, of 3.50 mol NO2....Ch. 3 - Prob. 3.70QECh. 3 - Prob. 3.71QECh. 3 - Prob. 3.72QECh. 3 - Prob. 3.73QECh. 3 - Nickel tetracarbonyl, Ni(CO)4, is a volatile...Ch. 3 - Prob. 3.75QECh. 3 - Prob. 3.76QECh. 3 - Prob. 3.77QECh. 3 - Prob. 3.78QECh. 3 - Prob. 3.79QECh. 3 - Prob. 3.80QECh. 3 - Prob. 3.81QECh. 3 - Prob. 3.82QECh. 3 - Prob. 3.83QECh. 3 - Prob. 3.84QECh. 3 - A chemist prepared a compound that she thought had...Ch. 3 - Prob. 3.86QECh. 3 - Prob. 3.87QECh. 3 - Prob. 3.88QECh. 3 - Prob. 3.89QECh. 3 - Prob. 3.90QECh. 3 - Prob. 3.91QECh. 3 - Prob. 3.92QECh. 3 - Prob. 3.93QECh. 3 - Prob. 3.94QECh. 3 - Prob. 3.95QECh. 3 - Prob. 3.96QECh. 3 - Prob. 3.97QECh. 3 - Prob. 3.98QECh. 3 - Prob. 3.99QECh. 3 - Prob. 3.100QECh. 3 - Prob. 3.101QECh. 3 - Prob. 3.102QECh. 3 - Prob. 3.103QECh. 3 - Prob. 3.104QECh. 3 - Prob. 3.105QECh. 3 - Prob. 3.106QECh. 3 - Prob. 3.107QECh. 3 - Prob. 3.108QECh. 3 - Prob. 3.109QECh. 3 - Prob. 3.110QECh. 3 - Prob. 3.111QECh. 3 - Prob. 3.112QECh. 3 - Prob. 3.113QECh. 3 - Prob. 3.114QECh. 3 - A compound contains 62.0% carbon, 10.4% hydrogen,...Ch. 3 - Mandelic acid is an organic acid composed of...Ch. 3 - Acetic acid gives vinegar its sour taste. Analysis...Ch. 3 - Prob. 3.118QECh. 3 - Prob. 3.119QECh. 3 - Prob. 3.120QECh. 3 - Prob. 3.121QECh. 3 - Prob. 3.122QECh. 3 - Aluminum metal reacts with sulfuric acid, H2SO4,...Ch. 3 - Prob. 3.124QECh. 3 - Lithium metal reacts with O2 to form lithium...Ch. 3 - Prob. 3.126QECh. 3 - A mixture of hydrogen and nitrogen gas reacts as...Ch. 3 - Prob. 3.128QECh. 3 - Prob. 3.129QECh. 3 - Prob. 3.130QECh. 3 - Prob. 3.131QECh. 3 - Prob. 3.132QECh. 3 - Prob. 3.133QECh. 3 - A reaction of 43.1 g CS2 with excess Cl2 yields...Ch. 3 - The reaction of 9.66 g O2 with 9.33 g NO produces...Ch. 3 - Prob. 3.136QECh. 3 - The combustion of 33.5 g C3H6 with 127 g O2 yields...Ch. 3 - Prob. 3.138QECh. 3 - Prob. 3.139QECh. 3 - When heated, potassium chlorate, KClO3, melts and...Ch. 3 - Prob. 3.141QECh. 3 - Prob. 3.142QECh. 3 - Prob. 3.143QECh. 3 - Prob. 3.144QECh. 3 - Prob. 3.145QECh. 3 - Prob. 3.146QECh. 3 - Prob. 3.147QECh. 3 - Prob. 3.149QECh. 3 - Prob. 3.150QECh. 3 - Prob. 3.151QECh. 3 - Prob. 3.152QECh. 3 - The compound dinitrogen monoxide, N2O, is a...Ch. 3 - Prob. 3.154QECh. 3 - Prob. 3.155QECh. 3 - Prob. 3.156QECh. 3 - Prob. 3.157QECh. 3 - Prob. 3.159QECh. 3 - Prob. 3.160QECh. 3 - The reaction of equal molar amounts of benzene,...Ch. 3 - Although copper does not usually react with acids,...
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