CHEMISTRY:ATOMS FIRST (LL)>CUSTOM PKG.<
2nd Edition
ISBN: 9781259382307
Author: Burdge
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Textbook Question
Chapter 3, Problem 3.101QP
List the following atoms in order of increasing number of unpaired electrons: B, C, N, O, F.
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Students have asked these similar questions
Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
☐ x10
fall
Х
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of NH 3 will tend to rise, can that
be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
atm
00.
18
Ar
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?
Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
2.2 mol of NaOH is added to
1.0 L of a 1.4M HF
solution.
acids:
П
bases:
Х
other: ☐
ப
acids:
0.51 mol of KOH is added to
1.0 L of a solution that is
bases:
1.3M in both HF and NaF.
other: ☐
00.
18
Ar
Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
N2O4 (g) 2NO2 (g)
AG⁰ = 5.4 kJ
Now suppose a reaction vessel is filled with 1.68 atm of dinitrogen tetroxide (N204) at 148. °C. Answer the following questions about this system:
rise
Under these conditions, will the pressure of N2O4 tend to rise or fall?
x10
fall
Is it possible to reverse this tendency by adding NO2?
In other words, if you said the pressure of N2O4 will tend to rise, can that
be changed to a tendency to fall by adding NO2? Similarly, if you said the
pressure of N2O4 will tend to fall, can that be changed to a tendency to
rise by adding NO2?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO 2 needed to reverse it.
Round your answer to 2 significant digits.
yes
no
0.42 atm
☑
5
0/5
?
مله
Ar
Chapter 3 Solutions
CHEMISTRY:ATOMS FIRST (LL)>CUSTOM PKG.<
Ch. 3.1 - Calculate the kinetic energy of a helium atom...Ch. 3.1 - Calculate the energy in joules of a 5.25-g object...Ch. 3.1 - Prob. 1PPBCh. 3.1 - Prob. 1PPCCh. 3.1 - Prob. 3.2WECh. 3.1 - How much greater is the electrostatic potential...Ch. 3.1 - What must the separation between charges of +2 and...Ch. 3.1 - Prob. 2PPCCh. 3.1 - Prob. 3.1.1SRCh. 3.1 - Prob. 3.1.2SR
Ch. 3.1 - Prob. 3.1.3SRCh. 3.2 - One type of laser used in the treatment of...Ch. 3.2 - What is the wavelength (in meters) of an...Ch. 3.2 - What is the frequency (in reciprocal seconds) of...Ch. 3.2 - Which of the following sets of waves best...Ch. 3.2 - Prob. 3.2.1SRCh. 3.2 - Prob. 3.2.2SRCh. 3.2 - Prob. 3.2.3SRCh. 3.2 - Prob. 3.2.4SRCh. 3.3 - Calculate the energy (in joules) of (a) a photon...Ch. 3.3 - Calculate the energy (in joules) of (a) a photon...Ch. 3.3 - (a) Calculate the wavelength (in nanometers) of...Ch. 3.3 - Prob. 3.3.1SRCh. 3.3 - Prob. 3.3.2SRCh. 3.3 - Prob. 3.3.3SRCh. 3.3 - Prob. 3.3.4SRCh. 3.3 - Prob. 3.3.5SRCh. 3.4 - Calculate the wavelength (in nanometers) of the...Ch. 3.4 - What is the wavelength (in nanometers) of a photon...Ch. 3.4 - What is the value of ni for an electron that emits...Ch. 3.4 - For each pair of transitions, determine which one...Ch. 3.4 - Prob. 3.4.1SRCh. 3.4 - Prob. 3.4.2SRCh. 3.4 - Prob. 3.4.3SRCh. 3.4 - Prob. 3.4.4SRCh. 3.5 - Calculate the de Broglie wavelength of the...Ch. 3.5 - Calculate the de Broglie wavelength (in...Ch. 3.5 - Use Equation 3.11 to calculate the momentum, p...Ch. 3.5 - Consider the impact of early electron diffraction...Ch. 3.5 - Prob. 3.5.1SRCh. 3.5 - Prob. 3.5.2SRCh. 3.5 - Prob. 3.5.3SRCh. 3.6 - An electron in a hydrogen atom is known to have a...Ch. 3.6 - Prob. 7PPACh. 3.6 - (a) Calculate the minimum uncertainty in the...Ch. 3.6 - Using Equation 3.13, we can calculate the minimum...Ch. 3.6 - Prob. 3.6.1SRCh. 3.6 - Prob. 3.6.2SRCh. 3.7 - What are the possible values for the magnetic...Ch. 3.7 - Prob. 8PPACh. 3.7 - Prob. 8PPBCh. 3.7 - Prob. 8PPCCh. 3.7 - Prob. 3.7.1SRCh. 3.7 - Prob. 3.7.2SRCh. 3.7 - Prob. 3.7.3SRCh. 3.7 - Prob. 3.7.4SRCh. 3.8 - Prob. 3.9WECh. 3.8 - Prob. 9PPACh. 3.8 - Prob. 9PPBCh. 3.8 - Prob. 9PPCCh. 3.8 - Prob. 3.8.1SRCh. 3.8 - Prob. 3.8.2SRCh. 3.8 - Prob. 3.8.3SRCh. 3.8 - Prob. 3.8.4SRCh. 3.9 - Write the electron configuration and give the...Ch. 3.9 - Prob. 10PPACh. 3.9 - Write the electron configuration and give the...Ch. 3.9 - Prob. 10PPCCh. 3.9 - Prob. 3.9.1SRCh. 3.9 - Prob. 3.9.2SRCh. 3.9 - Prob. 3.9.3SRCh. 3.10 - Without referring to Figure 3.26, write the...Ch. 3.10 - Prob. 11PPACh. 3.10 - Prob. 11PPBCh. 3.10 - Consider again the alternate universe and its...Ch. 3.10 - Prob. 3.10.1SRCh. 3.10 - Prob. 3.10.2SRCh. 3.10 - Prob. 3.10.3SRCh. 3.10 - Prob. 3.10.4SRCh. 3 - Define these terms: potential energy, kinetic...Ch. 3 - What are the units for energy commonly employed in...Ch. 3 - A truck initially traveling at 60 km/h is brought...Ch. 3 - Describe the interconversions of forms of energy...Ch. 3 - Prob. 3.5QPCh. 3 - Prob. 3.6QPCh. 3 - Prob. 3.7QPCh. 3 - Prob. 3.8QPCh. 3 - Prob. 3.9QPCh. 3 - (a) How much greater is the electrostatic energy...Ch. 3 - Prob. 3.11QPCh. 3 - Prob. 3.12QPCh. 3 - List the types of electromagnetic radiation,...Ch. 3 - Prob. 3.14QPCh. 3 - Prob. 3.15QPCh. 3 - Prob. 3.16QPCh. 3 - The SI unit of time is the second, which is...Ch. 3 - Prob. 3.18QPCh. 3 - Prob. 3.19QPCh. 3 - Four waves represent light in four different...Ch. 3 - Prob. 3.21QPCh. 3 - Prob. 3.22QPCh. 3 - Prob. 3.23QPCh. 3 - What is a photon? What role did Einsteins...Ch. 3 - A photon has a wavelength of 705 nm. Calculate the...Ch. 3 - The blue color of the sky results from the...Ch. 3 - A photon has a frequency of 6.5 109 Hz. (a)...Ch. 3 - Prob. 3.28QPCh. 3 - Prob. 3.29QPCh. 3 - Prob. 3.30QPCh. 3 - Prob. 3.31QPCh. 3 - A particular form of electromagnetic radiation has...Ch. 3 - Photosynthesis makes use of visible light to bring...Ch. 3 - The retina of a human eye can detect light when...Ch. 3 - Prob. 3.35QPCh. 3 - The binding energy of magnesium metal is 5.86 ...Ch. 3 - What is the kinetic energy of the ejected electron...Ch. 3 - A red light was shined onto a metal sample and the...Ch. 3 - A photoelectric experiment was performed by...Ch. 3 - Which of the following best explains why we see...Ch. 3 - One way to see the emission spectrum of hydrogen...Ch. 3 - How many lines would we see in the emission...Ch. 3 - For a hydrogen atom in which the electron has been...Ch. 3 - Prob. 3.40QPCh. 3 - Prob. 3.41QPCh. 3 - Briefly describe Bohrs theory of the hydrogen atom...Ch. 3 - Explain the meaning of the negative sign in...Ch. 3 - Consider the following energy levels of a...Ch. 3 - Prob. 3.45QPCh. 3 - Calculate the wavelength (in nanometers) of a...Ch. 3 - Calculate the frequency (hertz) and wavelength...Ch. 3 - What wavelength of light is needed to excite the...Ch. 3 - An electron in the hydrogen atom makes a...Ch. 3 - Explain why elements produce their own...Ch. 3 - Some copper-containing substances emit green light...Ch. 3 - Prob. 3.52QPCh. 3 - Prob. 3.53QPCh. 3 - Prob. 3.54QPCh. 3 - Why is Equation 3.11 meaningful only for...Ch. 3 - Prob. 3.56QPCh. 3 - Thermal neutrons are neutrons that move at speeds...Ch. 3 - Protons can be accelerated to speeds near that of...Ch. 3 - Prob. 3.59QPCh. 3 - Prob. 3.60QPCh. 3 - Prob. 3.61QPCh. 3 - Prob. 3.62QPCh. 3 - What are the inadequacies of Bohrs theory?Ch. 3 - What is the Heisenberg uncertainty principle? What...Ch. 3 - Prob. 3.65QPCh. 3 - Prob. 3.66QPCh. 3 - Prob. 3.67QPCh. 3 - The speed of a thermal neutron (see Problem 3.57)...Ch. 3 - Alveoli are tiny sacs of air in the lungs. Their...Ch. 3 - In the beginning of the twentieth century, some...Ch. 3 - Suppose that photons of blue light (430 nm) are...Ch. 3 - Prob. 3.72QPCh. 3 - Prob. 3.73QPCh. 3 - Which of the four quantum numbers (n, , m, ms)...Ch. 3 - Prob. 3.75QPCh. 3 - Prob. 3.76QPCh. 3 - Prob. 3.77QPCh. 3 - Prob. 3.78QPCh. 3 - Describe the shapes of s, p, and d orbitals. How...Ch. 3 - Prob. 3.80QPCh. 3 - Describe the characteristics of an s orbital, p...Ch. 3 - Why is a boundary surface diagram useful in...Ch. 3 - Prob. 3.83QPCh. 3 - Give the values of the four quantum numbers of an...Ch. 3 - Describe how a 1s orbital and a 2s orbital are...Ch. 3 - Prob. 3.86QPCh. 3 - Prob. 3.87QPCh. 3 - Make a chart of all allowable orbitals in the...Ch. 3 - Prob. 3.89QPCh. 3 - Prob. 3.90QPCh. 3 - A 3s orbital is illustrated here. Using this as a...Ch. 3 - Prob. 3.92QPCh. 3 - Prob. 3.93QPCh. 3 - State the Aufbau principle, and explain the role...Ch. 3 - Indicate the total number of (a) p electrons in N...Ch. 3 - Calculate the total number of electrons that can...Ch. 3 - Determine the total number of electrons that can...Ch. 3 - Determine the maximum number of electrons that can...Ch. 3 - Prob. 3.99QPCh. 3 - The electron configuration of an atom in the...Ch. 3 - List the following atoms in order of increasing...Ch. 3 - Determine the number of unpaired electrons in each...Ch. 3 - Determine the number of impaired electrons in each...Ch. 3 - Determine the number of unpaired electrons in each...Ch. 3 - Prob. 3.105QPCh. 3 - Portions of orbital diagrams representing the...Ch. 3 - Prob. 3.107QPCh. 3 - Prob. 3.108QPCh. 3 - Prob. 3.109QPCh. 3 - Define the following terms and give an example of...Ch. 3 - Explain why the ground-state electron...Ch. 3 - Write the election configuration of a xenon core.Ch. 3 - Comment on the correctness of the following...Ch. 3 - Prob. 3.114QPCh. 3 - Prob. 3.115QPCh. 3 - Write the ground-state electron configurations for...Ch. 3 - Write the ground-state electron configurations for...Ch. 3 - What is the symbol of the element with the...Ch. 3 - Prob. 3.119QPCh. 3 - Prob. 3.120QPCh. 3 - Discuss the current view of the correctness of the...Ch. 3 - Distinguish carefully between the following terms:...Ch. 3 - What is the maximum number of electrons in an atom...Ch. 3 - Prob. 3.124QPCh. 3 - Prob. 3.125QPCh. 3 - A baseball pitchers fastball has been clocked at...Ch. 3 - A ruby laser produces radiation of wavelength 633...Ch. 3 - Four atomic energy levels of an atom are shown...Ch. 3 - Prob. 3.129QPCh. 3 - Spectral lines of the Lyman and Balmer series do...Ch. 3 - Only a fraction of the electric energy supplied to...Ch. 3 - The figure here illustrates a series of...Ch. 3 - When one of heliums electrons is removed, the...Ch. 3 - The retina of a human eye can detect light when...Ch. 3 - An electron in an excited state in a hydrogen atom...Ch. 3 - Prob. 3.136QPCh. 3 - The election configurations described in this...Ch. 3 - Draw the shapes (boundary surfaces) of the...Ch. 3 - Prob. 3.139QPCh. 3 - Consider the graph here. (a) Calculate the binding...Ch. 3 - Scientists have found interstellar hydrogen atoms...Ch. 3 - Ionization energy is the minimum energy required...Ch. 3 - Prob. 3.143QPCh. 3 - Prob. 3.144QPCh. 3 - The cone cells of the human eye are sensitive to...Ch. 3 - (a) An electron in the ground state of the...Ch. 3 - Prob. 3.147QPCh. 3 - Prob. 3.148QPCh. 3 - When an election makes a transition between energy...Ch. 3 - Blackbody radiation is the term used to describe...Ch. 3 - Suppose that photons of red light (675 nm) are...Ch. 3 - In an election microscope, electrons are...Ch. 3 - According to Einsteins special theory of...Ch. 3 - The mathematical equation for studying the...
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