Introductory Chemistry (6th Edition)
6th Edition
ISBN: 9780134554525
Author: Tro
Publisher: PEARSON
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Chapter 3, Problem 27E
Interpretation Introduction
Interpretation: The term “heat capacity” should be explained.
Concept Introduction: When substances are heated, they undergo a change in temperature. However, the change in temperature the substance undergo depends upon the amount of heat absorbed by the substance which varies from substance to substance. It is the specific heat capacity of the substance on which a change in temperature of a substance depends.
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Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
Chapter 3 Solutions
Introductory Chemistry (6th Edition)
Ch. 3 - Which substance is a pure compound? a. Gold b....Ch. 3 - Which property of trinitrotoluene (TNT) is most...Ch. 3 - Which change is a chemical change? a. The...Ch. 3 - Q4. Which process is endothermic?
a. The burning...Ch. 3 - Q5. A 35-g sample of potassium completely reacts...Ch. 3 - Prob. 6SAQCh. 3 - Convert the boiling point of water (100.00C) to K....Ch. 3 - Q8. A European doctor reports that you have fever...Ch. 3 - Q9. How much heat must be absorbed by 125 g of...Ch. 3 - Q10. Substance A has a heat capacity that is much...
Ch. 3 - Define matter and list some examples.Ch. 3 - Prob. 2ECh. 3 - What are the three states of matter?Ch. 3 - Prob. 4ECh. 3 - Prob. 5ECh. 3 - Prob. 6ECh. 3 - Prob. 7ECh. 3 - Prob. 8ECh. 3 - 9. What is a mixture?
Ch. 3 - 10. What is the difference between a homogeneous...Ch. 3 - What is a pure substance?Ch. 3 - What is an element? A compound?Ch. 3 - What is the difference between a mixture and a...Ch. 3 - Prob. 14ECh. 3 - 15. What is the difference between a physical...Ch. 3 - Prob. 16ECh. 3 - Prob. 17ECh. 3 - Prob. 18ECh. 3 - Prob. 19ECh. 3 - What is chemical energy? List some examples of...Ch. 3 - Prob. 21ECh. 3 - 22. What is an exothermic reaction? Which has...Ch. 3 - 23. What is an endothermic reaction? Which has...Ch. 3 - Prob. 24ECh. 3 - Prob. 25ECh. 3 - 26. How do the three temperature scales differ?
Ch. 3 - Prob. 27ECh. 3 - Prob. 28ECh. 3 - The following equation can be used to convert...Ch. 3 - Prob. 30ECh. 3 - Classify each pure substance as an element or a...Ch. 3 - 32. Classify each pure substance as an element or...Ch. 3 - 33. Classify each mixture as homogeneous or...Ch. 3 - 34. Classify each mixture as homogeneous or...Ch. 3 - 35. Classify each substance as a pure substance or...Ch. 3 - 36. Classify each substance as a pure substance or...Ch. 3 - Classify each property as physical or chemical. a....Ch. 3 - Classify each property as physical or chemical. a....Ch. 3 - Which of the following properties of ethylene(a...Ch. 3 - Which of the following properties of ozone (a...Ch. 3 - 41. Classify each change as physical or...Ch. 3 - 42. Classify each change as physical or...Ch. 3 - A block of aluminum is (a) ground into aluminum...Ch. 3 - 44. Several pieces of graphite from a mechanical...Ch. 3 - 45. An automobile gasoline tank holds 42 kg of...Ch. 3 - In the explosion of a hydrogen-filled balloon,...Ch. 3 - 47. Are these data sets on chemical changes...Ch. 3 - 48. Are these data sets on chemical changes...Ch. 3 - Prob. 49ECh. 3 - 50. A 56-g sample of iron reacts with 24 g of...Ch. 3 - Prob. 51ECh. 3 - Prob. 52ECh. 3 - Prob. 53ECh. 3 - Prob. 54ECh. 3 - Prob. 55ECh. 3 - Prob. 56ECh. 3 - Prob. 57ECh. 3 - Prob. 58ECh. 3 - Prob. 59ECh. 3 - Prob. 60ECh. 3 - 61 A common type of handwarmer contains Iron...Ch. 3 - 62. In a chemical cold pack, two substances are...Ch. 3 - 63. Classify each process as exothermic or...Ch. 3 - Classify each process as exothermic or...Ch. 3 - Perform each temperature conversion. a.212 F to...Ch. 3 - Prob. 66ECh. 3 - The coldest temperature ever measured in the...Ch. 3 - 68. The warmest temperature ever measured in the...Ch. 3 - 69. Vodka does not freeze in the freezer because...Ch. 3 - Liquid helium boils at 4.2 K. Convert this...Ch. 3 - 71. The temperature in the South Pole during the...Ch. 3 - Prob. 72ECh. 3 - Prob. 73ECh. 3 - Prob. 74ECh. 3 - 75. Calculate the amount of heat required to raise...Ch. 3 - 76. Calculate the amount of heat required to raise...Ch. 3 - Calculate the amount of heat required to heat a...Ch. 3 - 78. Calculate the amount of heat required to heat...Ch. 3 - If 89 J of heat are added to a pure gold coin with...Ch. 3 - If 57 J heat are added to an aluminum can with a...Ch. 3 - An iron nail with a mass of 12 g absorbs 15 J of...Ch. 3 - Prob. 82ECh. 3 - Prob. 83ECh. 3 - 84. A lead fishing weight with a mass of 57 g...Ch. 3 - An unknown metal with a mass of 28 g absorbs 58 J...Ch. 3 - When 2.8 J of heat are added to 5.6 g of an...Ch. 3 - When 56 J of heat are added to 11 g of a liquid,...Ch. 3 - Prob. 88ECh. 3 - Prob. 89ECh. 3 - Prob. 90ECh. 3 - How much energy (In J) lost when a sample of iron...Ch. 3 - Prob. 92ECh. 3 - Prob. 93ECh. 3 - Prob. 94ECh. 3 - A pure gold ring with a volume of 1.57 cm3 is...Ch. 3 - Prob. 96ECh. 3 - Prob. 97ECh. 3 - Prob. 98ECh. 3 - 99. What is the temperature change (ΔT) in Celsius...Ch. 3 - Prob. 100ECh. 3 - Prob. 101ECh. 3 - Prob. 102ECh. 3 - A backpacker wants to carry enough fuel to heat...Ch. 3 - 104. A cook wants to heat 1.35 kg of water from...Ch. 3 - Evaporating sweat cools the body because...Ch. 3 - Prob. 106ECh. 3 - A 15.7-g aluminum block is warmed to 53.2C and...Ch. 3 - A 25.0-mL sample of ethanol (density = 0.789g/mL)...Ch. 3 - The wattage of an appliance indicates its average...Ch. 3 - Prob. 110ECh. 3 - What temperature is the same whether it is...Ch. 3 - What temperature on the Celsius scale is equal to...Ch. 3 - 113. Classify each as pure substance or a...Ch. 3 - Classify each as a pure substance or a mixture. If...Ch. 3 - This molecular drawing shows images of acetone...Ch. 3 - This molecular drawing shows of methane molecules...Ch. 3 - Prob. 117ECh. 3 - Global warming refers to the rise in average...Ch. 3 - 119. Examine the data for the maximum and minimum...Ch. 3 - Using white and black circles to represent...Ch. 3 - Prob. 121QGWCh. 3 - 122. A friend asks you to invest in a new...Ch. 3 - Prob. 123QGW
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