Chemical Principles
8th Edition
ISBN: 9781337247269
Author: Steven S. Zumdahl; Donald J. DeCoste
Publisher: Cengage Learning US
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 3, Problem 27E
Interpretation Introduction
Interpretation: The mass of one of the two isotopes of Rhenium that is
Concept introduction: Average atomic masses corresponding to the isotopes can be used to mathematically evaluate their percent abundances. This is done as all element’s isotopes do not occur in equivalent ratios. The overall summation of respective abundances of isotopes should be
Expert Solution & Answer

Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 3 Solutions
Chemical Principles
Ch. 3 - Prob. 1DQCh. 3 - Consider the equation A+2BAB2 . Imagine that10...Ch. 3 - Prob. 3DQCh. 3 - Prob. 4DQCh. 3 - Prob. 5DQCh. 3 - For the preceding question, which of the following...Ch. 3 - Prob. 7DQCh. 3 - A kerosene lamp has a mass of 1.5 kg. You put 0.5...Ch. 3 - Prob. 9DQCh. 3 - You may have noticed that water sometimes drips...
Ch. 3 - Prob. 11DQCh. 3 - Prob. 12DQCh. 3 - Prob. 13DQCh. 3 - Atoms of three different elements are represented...Ch. 3 - Prob. 15DQCh. 3 - Prob. 16DQCh. 3 - Prob. 17DQCh. 3 - Prob. 18DQCh. 3 - Chlorine exists mainly as two isotopes,...Ch. 3 - According to the law of conservation of mass, mass...Ch. 3 - Prob. 21DQCh. 3 - Prob. 22DQCh. 3 - Prob. 23ECh. 3 - Prob. 24ECh. 3 - Prob. 25ECh. 3 - Prob. 26ECh. 3 - Prob. 27ECh. 3 - An element consists of 1.40% of an isotope with...Ch. 3 - Prob. 29ECh. 3 - Naturally occurring tellurium (Te) has the...Ch. 3 - Gallium arsenide (GaAs) has gained widespread use...Ch. 3 - Prob. 32ECh. 3 - Prob. 33ECh. 3 - Prob. 34ECh. 3 - Prob. 35ECh. 3 - How many atoms of nitrogen are present in 5.00 g...Ch. 3 - Consider the following gas samples: 4.0 g of...Ch. 3 - Prob. 38ECh. 3 - Prob. 39ECh. 3 - Prob. 40ECh. 3 - Prob. 41ECh. 3 - Prob. 42ECh. 3 - In 1987 the first substance to act as a...Ch. 3 - Prob. 44ECh. 3 - Prob. 45ECh. 3 - Vitamin B12 , cyanocobalamin, is essential for...Ch. 3 - Prob. 47ECh. 3 - Prob. 48ECh. 3 - Prob. 49ECh. 3 - Give the empirical formula of each of these...Ch. 3 - Determine the molecular formulas to which the...Ch. 3 - A sample of urea contains 1.121 g N, 0.161 g...Ch. 3 - Prob. 53ECh. 3 - The compound adrenaline contains 56.79% C, 6.56%H,...Ch. 3 - The most common form of nylon (nylon-6) is...Ch. 3 - Prob. 56ECh. 3 - Prob. 57ECh. 3 - Prob. 58ECh. 3 - Prob. 59ECh. 3 - Prob. 60ECh. 3 - Prob. 61ECh. 3 - Prob. 62ECh. 3 - Prob. 63ECh. 3 - Prob. 64ECh. 3 - Prob. 65ECh. 3 - Iron oxide ores, commonly a mixture of FeOand...Ch. 3 - Prob. 67ECh. 3 - Prob. 68ECh. 3 - Prob. 69ECh. 3 - Prob. 70ECh. 3 - Prob. 71ECh. 3 - Prob. 72ECh. 3 - Elixirs such as Alka-Seltzer use the reaction of...Ch. 3 - Prob. 74ECh. 3 - Prob. 75ECh. 3 - Prob. 76ECh. 3 - Prob. 77ECh. 3 - Bacterial digestion is an economical method of...Ch. 3 - Prob. 79ECh. 3 - Prob. 80ECh. 3 - Prob. 81ECh. 3 - Prob. 82ECh. 3 - Hydrogen peroxide is used as a cleaning agent in...Ch. 3 - Silver sulfadiazine burn-treating cream creates a...Ch. 3 - Bornite (Cu3FeS3) is a copper ore used in the...Ch. 3 - DDT, an insecticide harmful to fish, birds, and...Ch. 3 - Prob. 87ECh. 3 - Prob. 88ECh. 3 - Prob. 89ECh. 3 - Prob. 90ECh. 3 - Prob. 91AECh. 3 - Prob. 92AECh. 3 - A sample of a hydrocarbon (a compound consisting...Ch. 3 - Prob. 94AECh. 3 - Prob. 95AECh. 3 - The empirical formula of styrene is CH; the molar...Ch. 3 - A 0.755-g sample of hydrated copper(II) sulfate...Ch. 3 - Prob. 98AECh. 3 - Prob. 99AECh. 3 - Prob. 100AECh. 3 - Prob. 101AECh. 3 - Prob. 102AECh. 3 - Prob. 103AECh. 3 - Prob. 104AECh. 3 - Prob. 105AECh. 3 - Prob. 106AECh. 3 - Prob. 107AECh. 3 - Prob. 108AECh. 3 - Prob. 109AECh. 3 - Prob. 110AECh. 3 - Prob. 111AECh. 3 - Prob. 112AECh. 3 - Prob. 113AECh. 3 - Prob. 114AECh. 3 - Prob. 115AECh. 3 - Prob. 116AECh. 3 - Prob. 117AECh. 3 - Prob. 118AECh. 3 - Prob. 119AECh. 3 - Which of the following statements about chemical...Ch. 3 - Prob. 121AECh. 3 - Prob. 122AECh. 3 - Prob. 123CPCh. 3 - When the supply of oxygen is limited, iron metal...Ch. 3 - Element X forms both a dichloride (XCl2) and a...Ch. 3 - Zinc and magnesium metal each react with...Ch. 3 - An unknown binary compound containing hydrogen...Ch. 3 - A 2.25-g sample of scandium metal is reacted with...Ch. 3 - When M2S3(s) is heated in air, it is converted to...Ch. 3 - Consider a gaseous binary compound with a molar...Ch. 3 - Prob. 131CPCh. 3 - You take 1.00 g of an aspirin tablet (a compound...Ch. 3 - Lanthanum was reacted with hydrogen in a given...Ch. 3 - Prob. 134CPCh. 3 - Consider a mixture of potassium chloride and...Ch. 3 - Prob. 136CPCh. 3 - Prob. 137CPCh. 3 - A gas contains a mixture of NH3(g)andN2H4(g) ,...Ch. 3 - Prob. 139MPCh. 3 - Prob. 140MP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- elow are experimentally determined van Deemter plots of column efficiency, H, vs. flow rate. H is a quantitative measurement of band broadening. The left plot is for a liquid chromatography application and the night is for gas chromatography. Compare and contrast these two plots in terms of the three band broadening mechanisms presented in this activity. How are they similar? How do they differ? Justify your answers.? 0.4 H (mm) 0.2 0.1- 0.3- 0 0.5 H (mm) 8.0 7.0 6.0 5.0 4.0- 3.0 T +++ 1.0 1.5 0 2.0 4.0 Flow Rate, u (cm/s) 6.0 8.0 Flow Rate, u (cm/s)arrow_forwardPredict the products of this organic reaction: + H ZH NaBH3CN H+ n. ? Click and drag to start drawing a structure. Xarrow_forwardWhat is the missing reactant R in this organic reaction? + R H3O+ + • Draw the structure of R in the drawing area below. • Be sure to use wedge and dash bonds if it's necessary to draw one particular enantiomer. Click and drag to start drawing a structure.arrow_forward
- What would be the best choices for the missing reagents 1 and 3 in this synthesis? 1 1. PPh3 2. n-BuLi 2 • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Click and drag to start drawing a structure.arrow_forwardThe product on the right-hand side of this reaction can be prepared from two organic reactants, under the conditions shown above and below the arrow. Draw 1 and 2 below, in any arrangement you like. 1+2 NaBH₂CN H+ N Click and drag to start drawing a structure. X $arrow_forwardExplain what is the maximum absorbance of in which caffeine absorbs?arrow_forward
- Explain reasons as to why the amount of caffeine extracted from both a singular extraction (5ml Mountain Dew) and a multiple extraction (2 x 5.0ml Mountain Dew) were severely high when compared to coca-cola?arrow_forwardProtecting Groups and Carbonyls 6) The synthesis generates allethrolone that exhibits high insect toxicity but low mammalian toxicity. They are used in pet shampoo, human lice shampoo, and industrial sprays for insects and mosquitos. Propose detailed mechanistic steps to generate the allethrolone label the different types of reagents (Grignard, acid/base protonation, acid/base deprotonation, reduction, oxidation, witting, aldol condensation, Robinson annulation, etc.) III + VI HS HS H+ CH,CH,Li III I II IV CI + P(Ph)3 V ༼ Hint: no strong base added VI S VII IX HO VIII -MgBr HgCl2,HgO HO. isomerization aqeuous solution H,SO, ༽༽༤༽༽ X MeOH Hint: enhances selectivity for reaction at the S X ☑arrow_forwardDraw the complete mechanism for the acid-catalyzed hydration of this alkene. esc 田 Explanation Check 1 888 Q A slock Add/Remove step Q F4 F5 F6 A བྲA F7 $ % 5 @ 4 2 3 & 6 87 Click and drag to start drawing a structure. © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Ce W E R T Y U S D LL G H IK DD 요 F8 F9 F10 F1 * ( 8 9 0 O P J K L Z X C V B N M H He commandarrow_forward
- Explanation Check F1 H₂O H₂ Pd 1) MCPBA 2) H3O+ 1) Hg(OAc)2, H₂O 2) NaBH4 OH CI OH OH OH hydration halohydrin formation addition halogenation hydrogenation inhalation hydrogenation hydration ☐ halohydrin formation addition halogenation formation chelation hydrogenation halohydrin formation substitution hydration halogenation addition Ohalohydrin formation subtraction halogenation addition hydrogenation hydration F2 80 F3 σ F4 F5 F6 1 ! 2 # 3 $ 4 % 05 Q W & Å © 2025 McGraw Hill LLC. All Rights Reserved. F7 F8 ( 6 7 8 9 LU E R T Y U A F9arrow_forwardShow the mechanism steps to obtain the lowerenergy intermediate: *see imagearrow_forwardSoap is made by the previous reaction *see image. The main difference between one soap and another soap isthe length (number of carbons) of the carboxylic acid. However, if a soap irritates your skin, they mostlikely used too much lye.Detergents have the same chemical structure as soaps except for the functional group. Detergentshave sulfate (R-SO4H) and phosphate (R-PO4H2) functional groups. Draw the above carboxylic acidcarbon chain but as the two variants of detergents. *see imagearrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage LearningGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
- Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning

Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning

General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning

Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning

Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning


Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Step by Step Stoichiometry Practice Problems | How to Pass ChemistryMole Conversions Made Easy: How to Convert Between Grams and Moles; Author: Ketzbook;https://www.youtube.com/watch?v=b2raanVWU6c;License: Standard YouTube License, CC-BY