Chemical Principles
8th Edition
ISBN: 9781337247269
Author: Steven S. Zumdahl; Donald J. DeCoste
Publisher: Cengage Learning US
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Chapter 3, Problem 114AE
Interpretation Introduction
Interpretation: The number of peaks and mass of each peak in the mass spectrum of
Concept introduction: The molar mass of any compound can be calculated by taking sum of
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20. The Brusselator. This hypothetical system was first proposed by a group work-
ing in Brussels [see Prigogine and Lefever (1968)] in connection with spatially
nonuniform chemical patterns. Because certain steps involve trimolecular reac
tions, it is not a model of any real chemical system but rather a prototype that
has been studied extensively. The reaction steps are
A-X.
B+X-Y+D.
2X+ Y-3X,
X-E.
305
It is assumed that concentrations of A, B, D, and E are kept artificially con
stant so that only X and Y vary with time.
(a) Show that if all rate constants are chosen appropriately, the equations de
scribing a Brusselator are:
dt
A-(B+ 1)x + x²y,
dy
=Bx-x²y.
di
Problem 3. Provide a mechanism for the following transformation:
H₂SO A
Me.
Me
Me
Me
Me
You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products:
xi
1. ☑
2. H₂O
хе
i
Draw the missing reagent X you think will make this synthesis work in the drawing area below.
If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank.
Click and drag to start drawing a
structure.
There is no reagent that will make this synthesis work without complications.
: ☐
S
☐
Chapter 3 Solutions
Chemical Principles
Ch. 3 - Prob. 1DQCh. 3 - Consider the equation A+2BAB2 . Imagine that10...Ch. 3 - Prob. 3DQCh. 3 - Prob. 4DQCh. 3 - Prob. 5DQCh. 3 - For the preceding question, which of the following...Ch. 3 - Prob. 7DQCh. 3 - A kerosene lamp has a mass of 1.5 kg. You put 0.5...Ch. 3 - Prob. 9DQCh. 3 - You may have noticed that water sometimes drips...
Ch. 3 - Prob. 11DQCh. 3 - Prob. 12DQCh. 3 - Prob. 13DQCh. 3 - Atoms of three different elements are represented...Ch. 3 - Prob. 15DQCh. 3 - Prob. 16DQCh. 3 - Prob. 17DQCh. 3 - Prob. 18DQCh. 3 - Chlorine exists mainly as two isotopes,...Ch. 3 - According to the law of conservation of mass, mass...Ch. 3 - Prob. 21DQCh. 3 - Prob. 22DQCh. 3 - Prob. 23ECh. 3 - Prob. 24ECh. 3 - Prob. 25ECh. 3 - Prob. 26ECh. 3 - Prob. 27ECh. 3 - An element consists of 1.40% of an isotope with...Ch. 3 - Prob. 29ECh. 3 - Naturally occurring tellurium (Te) has the...Ch. 3 - Gallium arsenide (GaAs) has gained widespread use...Ch. 3 - Prob. 32ECh. 3 - Prob. 33ECh. 3 - Prob. 34ECh. 3 - Prob. 35ECh. 3 - How many atoms of nitrogen are present in 5.00 g...Ch. 3 - Consider the following gas samples: 4.0 g of...Ch. 3 - Prob. 38ECh. 3 - Prob. 39ECh. 3 - Prob. 40ECh. 3 - Prob. 41ECh. 3 - Prob. 42ECh. 3 - In 1987 the first substance to act as a...Ch. 3 - Prob. 44ECh. 3 - Prob. 45ECh. 3 - Vitamin B12 , cyanocobalamin, is essential for...Ch. 3 - Prob. 47ECh. 3 - Prob. 48ECh. 3 - Prob. 49ECh. 3 - Give the empirical formula of each of these...Ch. 3 - Determine the molecular formulas to which the...Ch. 3 - A sample of urea contains 1.121 g N, 0.161 g...Ch. 3 - Prob. 53ECh. 3 - The compound adrenaline contains 56.79% C, 6.56%H,...Ch. 3 - The most common form of nylon (nylon-6) is...Ch. 3 - Prob. 56ECh. 3 - Prob. 57ECh. 3 - Prob. 58ECh. 3 - Prob. 59ECh. 3 - Prob. 60ECh. 3 - Prob. 61ECh. 3 - Prob. 62ECh. 3 - Prob. 63ECh. 3 - Prob. 64ECh. 3 - Prob. 65ECh. 3 - Iron oxide ores, commonly a mixture of FeOand...Ch. 3 - Prob. 67ECh. 3 - Prob. 68ECh. 3 - Prob. 69ECh. 3 - Prob. 70ECh. 3 - Prob. 71ECh. 3 - Prob. 72ECh. 3 - Elixirs such as Alka-Seltzer use the reaction of...Ch. 3 - Prob. 74ECh. 3 - Prob. 75ECh. 3 - Prob. 76ECh. 3 - Prob. 77ECh. 3 - Bacterial digestion is an economical method of...Ch. 3 - Prob. 79ECh. 3 - Prob. 80ECh. 3 - Prob. 81ECh. 3 - Prob. 82ECh. 3 - Hydrogen peroxide is used as a cleaning agent in...Ch. 3 - Silver sulfadiazine burn-treating cream creates a...Ch. 3 - Bornite (Cu3FeS3) is a copper ore used in the...Ch. 3 - DDT, an insecticide harmful to fish, birds, and...Ch. 3 - Prob. 87ECh. 3 - Prob. 88ECh. 3 - Prob. 89ECh. 3 - Prob. 90ECh. 3 - Prob. 91AECh. 3 - Prob. 92AECh. 3 - A sample of a hydrocarbon (a compound consisting...Ch. 3 - Prob. 94AECh. 3 - Prob. 95AECh. 3 - The empirical formula of styrene is CH; the molar...Ch. 3 - A 0.755-g sample of hydrated copper(II) sulfate...Ch. 3 - Prob. 98AECh. 3 - Prob. 99AECh. 3 - Prob. 100AECh. 3 - Prob. 101AECh. 3 - Prob. 102AECh. 3 - Prob. 103AECh. 3 - Prob. 104AECh. 3 - Prob. 105AECh. 3 - Prob. 106AECh. 3 - Prob. 107AECh. 3 - Prob. 108AECh. 3 - Prob. 109AECh. 3 - Prob. 110AECh. 3 - Prob. 111AECh. 3 - Prob. 112AECh. 3 - Prob. 113AECh. 3 - Prob. 114AECh. 3 - Prob. 115AECh. 3 - Prob. 116AECh. 3 - Prob. 117AECh. 3 - Prob. 118AECh. 3 - Prob. 119AECh. 3 - Which of the following statements about chemical...Ch. 3 - Prob. 121AECh. 3 - Prob. 122AECh. 3 - Prob. 123CPCh. 3 - When the supply of oxygen is limited, iron metal...Ch. 3 - Element X forms both a dichloride (XCl2) and a...Ch. 3 - Zinc and magnesium metal each react with...Ch. 3 - An unknown binary compound containing hydrogen...Ch. 3 - A 2.25-g sample of scandium metal is reacted with...Ch. 3 - When M2S3(s) is heated in air, it is converted to...Ch. 3 - Consider a gaseous binary compound with a molar...Ch. 3 - Prob. 131CPCh. 3 - You take 1.00 g of an aspirin tablet (a compound...Ch. 3 - Lanthanum was reacted with hydrogen in a given...Ch. 3 - Prob. 134CPCh. 3 - Consider a mixture of potassium chloride and...Ch. 3 - Prob. 136CPCh. 3 - Prob. 137CPCh. 3 - A gas contains a mixture of NH3(g)andN2H4(g) ,...Ch. 3 - Prob. 139MPCh. 3 - Prob. 140MP
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- Predict the major products of this organic reaction: H OH 1. LiAlH4 2. H₂O ? Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. G C टेarrow_forwardFor each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 CI MgCl ? Will the first product that forms in this reaction create a new CC bond? Yes No MgBr ? Will the first product that forms in this reaction create a new CC bond? Yes No G टेarrow_forwardFor each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. དྲ。 ✗MgBr ? O CI Will the first product that forms in this reaction create a new C-C bond? Yes No • ? Will the first product that forms in this reaction create a new CC bond? Yes No × : ☐ Xarrow_forward
- Predict the major products of this organic reaction: OH NaBH4 H ? CH3OH Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. ☐ : Sarrow_forwardPredict the major products of this organic reaction: 1. LIAIHA 2. H₂O ? Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. X : ☐arrow_forwardFor each reaction below, decide if the first stable organic product that forms in solution will create a new C - C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 tu ? ? OH Will the first product that forms in this reaction create a new CC bond? Yes No Will the first product that forms in this reaction create a new CC bond? Yes No C $ ©arrow_forward
- As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C-C bond as its major product: 1. MgCl ? 2. H₂O* If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. This reaction will not make a product with a new CC bond. G marrow_forwardIncluding activity coefficients, find [Hg22+] in saturated Hg2Br2 in 0.00100 M NH4 Ksp Hg2Br2 = 5.6×10-23.arrow_forwardgive example for the following(by equation) a. Converting a water insoluble compound to a soluble one. b. Diazotization reaction form diazonium salt c. coupling reaction of a diazonium salt d. indacator properties of MO e. Diazotization ( diazonium salt of bromobenzene)arrow_forward
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