Pushing Electrons
4th Edition
ISBN: 9781133951889
Author: Weeks, Daniel P.
Publisher: Cengage Learning
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Chapter 3, Problem 23EQ
Interpretation Introduction
Interpretation:
The bond making and breaking in the given species is to be represented.
Concept Introduction:
Molecules also show a simultaneous bond making and breaking. This can be illustrated nicely in the familiar SN2 reaction. A negatively charged nucleophile approaches a carbon atom having a leaving group in a direction anti to the leaving group. The pushable electrons are possessed by the nucleophile and the receptor is the carbon atom. The products are a compound having a C-Nu bond and the anion of the leaving group. Thus, Nu has been substituted for L.
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Draw structural formulas for organic products A and B in the window below.
Li
Cul
-Br
pentane
Draw only products having the organic portion of the original alkyl halide.
• Draw carbon-lithium bonds using the single bond tool. If a structure has a copper-lithium bond, do not draw the lithium.
• Separate products from different steps using the → sign from the drop-down menu.
Draw structural formulas for organic products A and B in the window below.
-CH₂CI
Li
pentane
Cul
B
• Draw only products having the organic portion of the original alkyl halide.
• Draw carbon-lithium bonds using the single bond tool. If a structure has a
copper-lithium bond, do not draw the lithium.
Separate products from different steps using the → sign from the drop-
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Consider the given alkyl halide reaction below. Which of the following statements is TRUE about the
chemical reaction equation? The solvent used in the reaction is acetic acid.
Br.
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Chapter 3 Solutions
Pushing Electrons
Ch. 3 - Prob. 1EQCh. 3 - Prob. 2EQCh. 3 - Prob. 3EQCh. 3 - Prob. 4EQCh. 3 - Prob. 5EQCh. 3 - Prob. 6EQCh. 3 - Here are some exercises in sigma bond breaking....Ch. 3 - Prob. 8EQCh. 3 - Prob. 9EQCh. 3 - Prob. 10EQ
Ch. 3 - Prob. 11EQCh. 3 - Prob. 12EQCh. 3 - Prob. 13EQCh. 3 - Prob. 14EQCh. 3 - Prob. 15EQCh. 3 - Prob. 16EQCh. 3 - Prob. 17EQCh. 3 - Prob. 18EQCh. 3 - Prob. 19EQCh. 3 - Prob. 20EQCh. 3 - Prob. 21EQCh. 3 - Prob. 22EQCh. 3 - Prob. 23EQCh. 3 - Prob. 24EQCh. 3 - Prob. 25EQCh. 3 - Prob. 26EQCh. 3 - Prob. 27EQCh. 3 - Prob. 28EQCh. 3 - Prob. 29EQCh. 3 - Prob. 30EQCh. 3 - The reaction just described is reversible....Ch. 3 - Prob. 32EQCh. 3 - Prob. 59EQ
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