Pushing Electrons
Pushing Electrons
4th Edition
ISBN: 9781133951889
Author: Weeks, Daniel P.
Publisher: Cengage Learning
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Chapter 3, Problem 12EQ
Interpretation Introduction

Interpretation:

The leaving group in the given molecule is to be determined in order identify the positively charged and neutral fragments produced during mechanism.

Concept Introduction:

Heterolytic cleavage of sigma bond occurs under a variety of conditions. The mechanism of bond cleavage is as shown below,

Pushing Electrons, Chapter 3, Problem 12EQ

The arrow in the above mechanism indicates that the sigma electrons form A-B bond are leaving A and becoming the exclusive property of B. Since the fragment A is formally losing one electron, it must become positively charged and B must become negatively charged since it gains an electron.

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Many free radicals combine to form molecules that do not contain any unpaired electrons. The driving force for the radical- radical combination reaction is the formation of a new electron-pair bond. Consider the formation of hydrogen peroxide. 2 OH(g) → H₂O₂(g) Write Lewis formulas for the reactant and product species in the chemical equation. Include nonbonding electrons. OH(g) Select Draw Rings More / ||| ||| Erase Q2 Q H₂O₂(g) Select Draw Rings More 3 S H Erase Q2 Q Question Source: McQuarrie, Rock, And Gallogly 4e - General Chemistry Publisher: University Science B
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