EBK GENERAL CHEMISTRY
11th Edition
ISBN: 9780133400588
Author: Bissonnette
Publisher: VST
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Chapter 3, Problem 23E
Determine the mass percent of each of the elements in the antimalarial drug quinine,
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Q2: Draw the molecules based on the provided nomenclatures below:
(2R,3S)-2-chloro-3-methylpentane:
(2S, 2R)-2-hydroxyl-3,6-dimethylheptane:
Q3: Describes the relationship (identical, constitutional isomers, enantiomers or diastereomers)
of each pair of compounds below.
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Q1: For each molecule, assign each stereocenter as R or S. Circle the meso compounds. Label
each compound as chiral or achiral.
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Chapter 3 Solutions
EBK GENERAL CHEMISTRY
Ch. 3 - Refer to the color scheme given Figure 3-3, and...Ch. 3 - Give the molecular formulas for the molecules...Ch. 3 - Give the structure formulas of the molecules shown...Ch. 3 - Give the structure formulas of the molecules shown...Ch. 3 - Calculate the total number of (a) atoms one...Ch. 3 - Determine the mass, in grams, of a. 7.34molNO2 b....Ch. 3 - The amino acid methionine, which is essential in...Ch. 3 - Determine the number of moles of Br2 in a sample...Ch. 3 - Without doing detailed calculations, explain which...Ch. 3 - Without doing detailed calculations, determine...
Ch. 3 - Determine the number of moles of a. N2O4 in a 115...Ch. 3 - Determine the mass, in grams, of a. 2.10102 molS2...Ch. 3 - The content of is 15.5g/100 mLblood. The molar...Ch. 3 - In white phosphorus, P atoms are joined into P,...Ch. 3 - Prob. 15ECh. 3 - Prob. 16ECh. 3 - For the mineral torbernite, Cu( UO2)2( PO4)2,8H2O...Ch. 3 - For the compound Ge[S( CH 2 )4CH2]4 determine a....Ch. 3 - Determine the mass percent H in the hydrocarbon...Ch. 3 - Determine the mass percent O in the mineral...Ch. 3 - Determine the mass percent H in the hydrocarbon...Ch. 3 - Prob. 22ECh. 3 - Determine the mass percent of each of the elements...Ch. 3 - Prob. 24ECh. 3 - Determine the percent, by mass,of the indicated...Ch. 3 - All of the following minerals are semiprecious or...Ch. 3 - Without doing calculations, arrange the following...Ch. 3 - Prob. 28ECh. 3 - Two oxides of sulfur have nearly identical...Ch. 3 - An oxide of chromium used in chrome plating has a...Ch. 3 - Diethylene glycol, used to de-ice aircraft, is a...Ch. 3 - Prob. 32ECh. 3 - Determine the empirical formula of (a) the...Ch. 3 - Prob. 34ECh. 3 - A compound of carbon and hydrogen consists of...Ch. 3 - Selenium, an element used in the manufacture of...Ch. 3 - Indigo, the dye for blue jeans, has a percent...Ch. 3 - Prob. 38ECh. 3 - Prob. 39ECh. 3 - The element X forms the compound XOCI2 containing...Ch. 3 - Prob. 41ECh. 3 - Two compounds of CI and X are found to have...Ch. 3 - A 0.1888 g sample of a hydrocarbon produces 0.6260...Ch. 3 - Para-cresol (p-cresol) is used as a disinfectant...Ch. 3 - Dimethylhydrazine is a carbon-hydrogen-nitrogen...Ch. 3 - Prob. 46ECh. 3 - Without doing detailed calculations, explain which...Ch. 3 - Prob. 48ECh. 3 - A 1.562 g sample of the alcohol CH2CHOHCH2CH2 is...Ch. 3 - Prob. 50ECh. 3 - Indicate the oxidation state of the underlined...Ch. 3 - Indicate the oxidation state of S in (a) SO42 (b)...Ch. 3 - Prob. 53ECh. 3 - Prob. 54ECh. 3 - Prob. 55ECh. 3 - Hydrogen and oxygen usually have oxidation states...Ch. 3 - Prob. 57ECh. 3 - Name these compounds: (a)Ba(...Ch. 3 - Prob. 59ECh. 3 - Prob. 60ECh. 3 - Prob. 61ECh. 3 - Prob. 62ECh. 3 - Write a formula for (a) the chloride of titanium...Ch. 3 - Write formula for (a) an oxide of nitrogen with N...Ch. 3 - Prob. 65ECh. 3 - Supply the formula for the acids: (a) hydrofluoric...Ch. 3 - Name the following compounds and specify which...Ch. 3 - Prob. 68ECh. 3 - Prob. 69ECh. 3 - Prob. 70ECh. 3 - Anhydrous CuSO4 can be used to dry liquids in...Ch. 3 - Anhydrous sodium sulfate, Na2SO4 absorbs water...Ch. 3 - A certain hydrate is found to have the composition...Ch. 3 - An 8.129 g sample of MgSO4H2O is heated until all...Ch. 3 - Prob. 75ECh. 3 - Prob. 76ECh. 3 - Prob. 77ECh. 3 - Prob. 78ECh. 3 - Prob. 79ECh. 3 - Prob. 80ECh. 3 - Prob. 81ECh. 3 - Prob. 82ECh. 3 - The mineral spodumene has the empirical formula...Ch. 3 - Prob. 84IAECh. 3 - Prob. 85IAECh. 3 - The important natural sources of boron compounds...Ch. 3 - Prob. 87IAECh. 3 - By analysis, a compound was found to contain 26.58...Ch. 3 - Prob. 89IAECh. 3 - What is the molecular formula of a hydrocarbon...Ch. 3 - A hydrocarbon mixture consists of 601% by mass of...Ch. 3 - A 0.732 g mature of methane, CH4 and ethane, C2H5...Ch. 3 - The density of a mixture of H2SO4 and water is...Ch. 3 - Prob. 94IAECh. 3 - Prob. 95IAECh. 3 - Prob. 96IAECh. 3 - Prob. 97IAECh. 3 - Prob. 98IAECh. 3 - The metal M forms the sulfate M2( SO4)2. A 0.738 g...Ch. 3 - Prob. 100IAECh. 3 - Prob. 101IAECh. 3 - Prob. 102IAECh. 3 - A 1.013 g sample of ZnSO4H2O is dissolved in water...Ch. 3 - The iodide ion in a 1.552 g sample of the compound...Ch. 3 - Prob. 105IAECh. 3 - The insecticide dieldrin contains carbon, oxygen,...Ch. 3 - Prob. 107IAECh. 3 - The atomic mass of Bi is to be determined by...Ch. 3 - A piece of gold (Au) foil measuring 0.25mm15mm is...Ch. 3 - Prob. 110IAECh. 3 - Prob. 111IAECh. 3 - All-purpose fertilizers contain the essential...Ch. 3 - A hydrate of copper(II) sulfate, when heated, goes...Ch. 3 - Prob. 114FPCh. 3 - Prob. 115SAECh. 3 - Prob. 116SAECh. 3 - Prob. 117SAECh. 3 - Prob. 118SAECh. 3 - Prob. 119SAECh. 3 - Three of the following formulas might be ether an...Ch. 3 - Prob. 121SAECh. 3 - Prob. 122SAECh. 3 - Iron is present red blood and acts to carry oxygen...Ch. 3 - Prob. 124SAECh. 3 - Prob. 125SAECh. 3 - Prob. 126SAECh. 3 - Prob. 127SAECh. 3 - Prob. 128SAECh. 3 - Prob. 129SAECh. 3 - Which compound has a molar mass of...Ch. 3 - Prob. 131SAECh. 3 - Prob. 132SAECh. 3 - A hydrate of Na2SO2 contains almost exactly 50%...Ch. 3 - Malachite is a common copper-containing mineral...Ch. 3 - Prob. 135SAECh. 3 - Ibuprofen is a compound used in painkiller. When a...Ch. 3 - Prob. 137SAE
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- These are synthesis questions. You need to show how the starting material can be converted into the product(s) shown. You may use any reactions we have learned. Show all the reagents you need. Show each molecule synthesized along the way and be sure to pay attention to the regiochemistry and stereochemistry preferences for each reaction. If a racemic molecule is made along the way, you need to draw both enantiomers and label the mixture as "racemic". All of the carbon atoms of the products must come from the starting material! ? H Harrow_forwardQ5: Draw every stereoisomer for 1-bromo-2-chloro-1,2-difluorocyclopentane. Clearly show stereochemistry by drawing the wedge-and-dashed bonds. Describe the relationship between each pair of the stereoisomers you have drawn.arrow_forwardClassify each pair of molecules according to whether or not they can participate in hydrogen bonding with one another. Participate in hydrogen bonding CH3COCH3 and CH3COCH2CH3 H2O and (CH3CH2)2CO CH3COCH3 and CH₂ CHO Answer Bank Do not participate in hydrogen bonding CH3CH2OH and HCHO CH3COCH2CH3 and CH3OHarrow_forward
- Nonearrow_forwardGiven the standard enthalpies of formation for the following substances, determine the reaction enthalpy for the following reaction. 4A (g) + 2B (g) → 2C (g) + 7D (g) AHrxn =?kJ Substance AH in kJ/mol A (g) - 20.42 B (g) + 32.18 C (g) - 72.51 D (g) - 17.87arrow_forwardDetermine ASran for Zn(s) + 2HCl(aq) = ZnCl2(aq) + H2(aq) given the following information: Standard Entropy Values of Various Substance Substance So (J/mol • K) 60.9 Zn(s) HCl(aq) 56.5 130.58 H2(g) Zn2+(aq) -106.5 55.10 CI (aq)arrow_forward
- 3) Catalytic hydrogenation of the compound below produced the expected product. However, a byproduct with molecular formula C10H12O is also formed in small quantities. What is the by product?arrow_forwardWhat is the ΔHorxn of the reaction? NaOH(aq) + HCl(aq) → H2O(l) + NaCl(aq) ΔHorxn 1= ________ kJ/molarrow_forward= +92kJ ΔΗ = +170kJ Use the following reactions: 2NH3(9) N2(g) + 3H2(g) → 11/N2(g) + 2H2O (1) → NO2(g) + 2H2(g) Determine the DH° of this reaction: NO2(g) + H2(g) → 2(g) → 2H2O(l) + NH3(9) ΔΗarrow_forward
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