Bundle: Chemistry: An Atoms First Approach, Loose-leaf Version, 2nd + OWLv2 with Student Solutions Manual, 4 terms (24 months) Printed Access Card
2nd Edition
ISBN: 9781337086431
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
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Chapter 3, Problem 148CP
Interpretation Introduction
Interpretation: The first ionization energies of the given halogen atoms and the electronegativity of the fluorine tom has been given. The electronegativity values for the given halogens, with respect to the given formula, are to be calculated. These values need to be further compared with the stated electronegativity values for the given compounds.
Concept introduction: Electronegativity can be defined as the measure of the tendency of an electron to attract the shared pair of electrons towards itself. It is directly proportional to the difference between the ionization energy and the
To determine: The electronegativity values of the given halogens; a comparison of these values with the values in the text.
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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
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Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
80
70
-26
60
50
40
46
30
20
115
10
1.0 0.9 0.8
0
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V
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Chapter 3 Solutions
Bundle: Chemistry: An Atoms First Approach, Loose-leaf Version, 2nd + OWLv2 with Student Solutions Manual, 4 terms (24 months) Printed Access Card
Ch. 3 - Distinguish between the terms electronegativity...Ch. 3 - Prob. 2RQCh. 3 - When an element forms an anion, what happens to...Ch. 3 - Define the term lattice energy. Why,...Ch. 3 - Explain how bond energies can be used to estimate...Ch. 3 - Prob. 6RQCh. 3 - Prob. 7RQCh. 3 - Explain the terms resonance and delocalized...Ch. 3 - Define formal charge and explain how to calculate...Ch. 3 - The compounds AlCl3, CrCl3, and ICl3 have similar...
Ch. 3 - How would you name HBrO4, KIO3, NaBrO2, and HIO?...Ch. 3 - Explain the electronegativity trends across a row...Ch. 3 - The ionic compound AB is formed. The charges on...Ch. 3 - Prob. 3ALQCh. 3 - The bond energy for a CH bond is about 413 kJ/mol...Ch. 3 - Prob. 5ALQCh. 3 - Which has the greater bond lengths: NO2 or NO3?...Ch. 3 - Prob. 7ALQCh. 3 - The second electron affinity values for both...Ch. 3 - What is meant by a chemical bond? Why do atoms...Ch. 3 - Why are some bonds ionic and some covalent?Ch. 3 - Prob. 11ALQCh. 3 - Prob. 12ALQCh. 3 - Prob. 13ALQCh. 3 - Why do we call Ba(NO3)2 barium nitrate, but we...Ch. 3 - Prob. 15ALQCh. 3 - Prob. 16ALQCh. 3 - Compare and contrast the bonding found in the...Ch. 3 - Describe the type of bonding that exists in the...Ch. 3 - Some of the important properties of ionic...Ch. 3 - Prob. 21QCh. 3 - Distinguish between the following terms. a....Ch. 3 - What is the electronegativity trend? Where does...Ch. 3 - Prob. 24QCh. 3 - In general the higher the charge on the ions in an...Ch. 3 - Combustion reactions of fossil fuels provide most...Ch. 3 - Which of the following statements is/are true?...Ch. 3 - Three resonance structures can be drawn for CO2...Ch. 3 - Prob. 29QCh. 3 - Prob. 30QCh. 3 - Without using Fig. 3-4, predict the order of...Ch. 3 - Without using Fig. 3-4, predict the order of...Ch. 3 - Without using Fig. 3-4, predict which bond in each...Ch. 3 - Without using Fig. 3-4, predict which bond in each...Ch. 3 - Prob. 35ECh. 3 - Prob. 36ECh. 3 - Which of the following incorrectly shows the bond...Ch. 3 - Indicate the bond polarity (show the partial...Ch. 3 - Predict the type of bond (ionic, covalent, or...Ch. 3 - List all the possible bonds that can occur between...Ch. 3 - Hydrogen has an electronegativity value between...Ch. 3 - Rank the following bonds in order of increasing...Ch. 3 - Would you expect each of the following atoms to...Ch. 3 - Prob. 44ECh. 3 - Prob. 45ECh. 3 - Prob. 46ECh. 3 - Predict the empirical formulas of the ionic...Ch. 3 - Prob. 48ECh. 3 - Write electron configurations for a. the cations...Ch. 3 - Write electron configurations for a. the cations...Ch. 3 - Which of the following ions have noble gas...Ch. 3 - What noble gas has the same electron configuration...Ch. 3 - Give the formula of a negative ion that would have...Ch. 3 - Prob. 54ECh. 3 - Give three ions that are isoelectronic with neon....Ch. 3 - Consider the ions Sc3+, Cl, K+, Ca2+, and S2....Ch. 3 - Prob. 57ECh. 3 - Prob. 58ECh. 3 - Which compound in each of the following pairs of...Ch. 3 - Which compound in each of the following pairs of...Ch. 3 - Use the following data for potassium chloride to...Ch. 3 - Prob. 62ECh. 3 - Consider the following energy changes: E(kJ/mol)...Ch. 3 - Prob. 64ECh. 3 - Consider the following:...Ch. 3 - Prob. 66ECh. 3 - Rationalize the following lattice energy values:...Ch. 3 - The lattice energies of FeCl3, FeCl2, and Fe2O3...Ch. 3 - Prob. 69ECh. 3 - Prob. 70ECh. 3 - Prob. 71ECh. 3 - Acetic acid is responsible for the sour taste of...Ch. 3 - Prob. 73ECh. 3 - The major industrial source of hydrogen gas is by...Ch. 3 - Prob. 75ECh. 3 - Prob. 76ECh. 3 - Prob. 77ECh. 3 - Prob. 78ECh. 3 - Write Lewis structures that obey the octet rule...Ch. 3 - Write Lewis structures that obey the octet rule...Ch. 3 - Write Lewis structures that obey the octet rule...Ch. 3 - Write Lewis structures that obey the octet rule...Ch. 3 - Prob. 83ECh. 3 - Lewis structures can be used to understand why...Ch. 3 - The most common exceptions to the octet rule are...Ch. 3 - Prob. 86ECh. 3 - Write Lewis structures for the following. Show all...Ch. 3 - Prob. 88ECh. 3 - Benzene (C6H6) consists of a six-membered ring of...Ch. 3 - Borazine (B3N3H6) has often been called inorganic...Ch. 3 - An important observation supporting the concept of...Ch. 3 - Consider the following bond lengths: CO143pmC9O123...Ch. 3 - A toxic cloud covered Bhopal, India, in December...Ch. 3 - Peroxyacetyl nitrate, or PAN, is present in...Ch. 3 - Order the following species with respect to...Ch. 3 - Place the species below in order of the shortest...Ch. 3 - Prob. 97ECh. 3 - Prob. 98ECh. 3 - Write Lewis structures that obey the octet rule...Ch. 3 - Write Lewis structures for the species in Exercise...Ch. 3 - A common trait of simple organic compounds is to...Ch. 3 - Prob. 102ECh. 3 - Oxidation of the cyanide ion produces the stable...Ch. 3 - Prob. 104ECh. 3 - Name the compounds in parts ad and write the...Ch. 3 - Prob. 106ECh. 3 - Prob. 107ECh. 3 - Prob. 108ECh. 3 - Prob. 109ECh. 3 - Prob. 110ECh. 3 - Prob. 111ECh. 3 - Prob. 112ECh. 3 - Prob. 113ECh. 3 - Prob. 114ECh. 3 - Prob. 115ECh. 3 - Prob. 116ECh. 3 - Prob. 117ECh. 3 - Write the formula for each of the following...Ch. 3 - Prob. 119ECh. 3 - Write the formula for each of the following...Ch. 3 - Prob. 121ECh. 3 - Prob. 122ECh. 3 - Arrange the following in order of increasing...Ch. 3 - For each of the following, write an equation that...Ch. 3 - Prob. 125AECh. 3 - Write Lewis structures for CO32, HCO3, and H2CO3....Ch. 3 - Which member of the following pairs would you...Ch. 3 - What do each of the following sets of...Ch. 3 - Although both Br3 and I3 ions are known, the F3...Ch. 3 - Prob. 130AECh. 3 - Prob. 131AECh. 3 - Identify each of the following elements: a. a...Ch. 3 - Prob. 133AECh. 3 - Prob. 134AECh. 3 - When molten sulfur reacts with chlorine gas, a...Ch. 3 - The study of carbon-containing compounds and their...Ch. 3 - Prob. 137CWPCh. 3 - Prob. 138CWPCh. 3 - Complete the following table to predict whether...Ch. 3 - Prob. 140CWPCh. 3 - Prob. 141CWPCh. 3 - List the bonds PCl, PF, OF, and SiF from least...Ch. 3 - Arrange the atoms and/or ions in the following...Ch. 3 - Prob. 144CWPCh. 3 - Prob. 145CWPCh. 3 - Which of the following compounds or ions exhibit...Ch. 3 - Prob. 147CPCh. 3 - Prob. 148CPCh. 3 - Given the following information: Energy of...Ch. 3 - Think of forming an ionic compound as three steps...Ch. 3 - Use data in this chapter (and Chapter 2) to...Ch. 3 - Three processes that have been used for the...Ch. 3 - Prob. 153CPCh. 3 - Prob. 154CPCh. 3 - Draw a Lewis structure for the N,...Ch. 3 - Cholesterol (C27H46O) has the following structure:...Ch. 3 - Consider the following computer-generated model of...Ch. 3 - For each of the following ions, indicate the total...Ch. 3 - Prob. 159IPCh. 3 - A polyatomic ion is composed of C, N, and an...
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