a) The H-Cl bond length is 136pm. What would be the dipole moment of H-Cl be if the molecule were 100% ionic, H + Cl - ? Interpretation: Assuming H-Cl to be 100% ionic its dipole moment is to be calculated. Its bond length is given as 136pm. Concept introduction: Dipole moment is defined as, µ=Qxr Where, Q=Magnitude of the charge developed at either end of the dipole. R=The distance between the charges It is expressed in Debyes (D). 1 D=3.336x10 -30 C.m To determine: The dipole moment of H-Cl assuming it to be 100% ionic. Its bond length is given as 136pm.

Question

For this question, if the product is racemic, input both enantiomers in the same Marvin editor. A) Input the number that corresponds to the reagent which when added to (E)-but-2-ene will result in a racemic product. Input 1 for Cl, in the cold and dark Input 2 for Oy followed by H₂O, Zn Input 3 for D₂ with metal catalyst Input 4 for H₂ with metal catalyst B) Draw the skeletal structure of the major organic product made from the reagent in part A Marvin JS Help Edit drawing C) Draw the skeletal structure of the major organic product formed when (2)-but-2-ene is treated with peroxyacetic acid. Marvin 35 Help

Answer 1

Question

Chapter 2.SE, Problem 31AP

Interpretation Introduction

a) The H-Cl bond length is 136pm. What would be the dipole moment of H-Cl be if the molecule were 100% ionic, H⁺Cl^-?

Interpretation:

Assuming H-Cl to be 100% ionic its dipole moment is to be calculated. Its bond length is given as 136pm.

Concept introduction:

Dipole moment is defined as, µ=Qxr

Where, Q=Magnitude of the charge developed at either end of the dipole.

R=The distance between the charges

It is expressed in Debyes (D). 1 D=3.336x10^-30C.m

To determine:

The dipole moment of H-Cl assuming it to be 100% ionic. Its bond length is given as 136pm.

Interpretation Introduction

b) The actual dipole moment of H-Cl is 1.08 D. What is the percent ionic character of the H-Cl bond.

Interpretation:

Actual dipole moment of H-Cl is given as 1.08 D. Its percent ionic character is to be calculated.

Concept introduction:

Assuming H-Cl to be 100% ionic and knowing the bond length, the dipole moment of H-Cl can be calculated. From the calculated value and the actual value of dipole moments the percent of ionic character of H-Cl can be determined.

To determine:

The percent ionic character of the H-Cl bond, if its actual dipole moment is 1.08 D.

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