ORGANIC CHEMISTRY W/OWL
9th Edition
ISBN: 9781305717527
Author: McMurry
Publisher: CENGAGE C
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Chapter 29.SE, Problem 26MP
Interpretation Introduction
Interpretation:
A mechanism for the conversion of fumaroylacetoacetate to fumarate plus acetoacetate.
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CH3CH2CH=CH2 + H₂O −
H+
Г
C-RSA CHROMATOPAC CH=1
DATA 1: @CHRM1.C00
ATTEN=10 SPEED= 10.0
0.0 b.092
0.797
1.088
1.813
C-RSA CHROMATOPAC CH=1 Report No. =13
** CALCULATION REPORT **
DATA=1: @CHRM1.000 11/03/05 08:09:52
CH PKNO
TIME
1
2
0.797
3
1.088
4
1.813
AREA
1508566
4625442
2180060
HEIGHT
207739
701206 V
287554 V
MK IDNO
CONC
NAME
18.1447
55.6339
26.2213
TOTAL
8314067 1196500
100
C-R8A CHROMATOPAC CH=1
DATA 1: @CHRM1.C00
ATTEN=10 SPEED= 10.0
0. 0
087
337.
0.841
1.150
C-R8A CHROMATOPAC CH=1 Report No. =14
DATA=1: @CHRM1.000 11/03/05 08:12:40
** CALCULATION REPORT **
CH PKNO
TIME
AREA
1
3 0.841
1099933
41.15
4039778
HEIGHT MK IDNO
170372
649997¯¯¯
CONC
NAME
21.4007
78.5993
TOTAL
5139711 820369
100
3
C-R8A CHROMATOPAC
CH=1
DATA 1: @CHRM1.C00
ATTEN=10 SPEED= 10.0
0.100
0:652
5.856
3
1.165
C-RSA CHROMATOPAC CH-1 Report No. =15
DATA=1: @CHRM1.000 11/03/05 08:15:26
** CALCULATION REPORT **
CH PKNO TIME
AREA
HEIGHT MK IDNO CONC
NAME
1 3 3 0.856
4
1.165
TOTAL
1253386
4838738
175481
708024 V
20.5739
79.4261
6092124…
Indicate the product that is obtained if the benzotriazole reacts with the use of a medium basic product.
Chapter 29 Solutions
ORGANIC CHEMISTRY W/OWL
Ch. 29.1 - Prob. 1PCh. 29.3 - Write the equations for the remaining passages of...Ch. 29.3 - Prob. 3PCh. 29.4 - Write a mechanism for the dehydration reaction of...Ch. 29.4 - Evidence for the role of acetate in fatty-acid...Ch. 29.4 - Does the reduction of acetoacetyl ACP in step 6...Ch. 29.5 - Prob. 7PCh. 29.5 - Look at the entire glycolysis pathway, and make a...Ch. 29.6 - Prob. 9PCh. 29.7 - Prob. 10P
Ch. 29.7 - Write mechanisms for step 2 of the citric acid...Ch. 29.7 - Prob. 12PCh. 29.8 - Prob. 13PCh. 29.9 - Write all the steps in the transamination reaction...Ch. 29.9 - What -keto acid is formed on transamination of...Ch. 29.9 - Prob. 16PCh. 29.SE - Prob. 17VCCh. 29.SE - Identify the following intermediate in the citric...Ch. 29.SE - The following compound is an intermediate in the...Ch. 29.SE - Prob. 20VCCh. 29.SE - In the pentose phosphate pathway for degrading...Ch. 29.SE - Prob. 22MPCh. 29.SE - One of the steps in the pentose phosphate pathway...Ch. 29.SE - One of the steps in the pentose phosphate pathway...Ch. 29.SE - Prob. 25MPCh. 29.SE - Prob. 26MPCh. 29.SE - Prob. 27MPCh. 29.SE - Prob. 28MPCh. 29.SE - Prob. 29MPCh. 29.SE - Prob. 30MPCh. 29.SE - Prob. 31MPCh. 29.SE - Prob. 32APCh. 29.SE - Prob. 33APCh. 29.SE - Prob. 34APCh. 29.SE - Prob. 35APCh. 29.SE - Prob. 36APCh. 29.SE - Prob. 37APCh. 29.SE - Prob. 38APCh. 29.SE - Prob. 39APCh. 29.SE - Prob. 40APCh. 29.SE - Prob. 41APCh. 29.SE - Prob. 42APCh. 29.SE - Prob. 43APCh. 29.SE - Prob. 44APCh. 29.SE - Prob. 45APCh. 29.SE - Prob. 46APCh. 29.SE - Prob. 47APCh. 29.SE - Prob. 48APCh. 29.SE - Prob. 49APCh. 29.SE - Prob. 50APCh. 29.SE - In glycerol metabolism, the oxidation of...Ch. 29.SE - Prob. 52APCh. 29.SE - Prob. 53APCh. 29.SE - Prob. 54APCh. 29.SE - In step 7 of fatty-acid biosynthesis (Figure...Ch. 29.SE - Prob. 56AP
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- Indicate the product that is obtained if the benzotriazol reacts with dimethyl sulfate.arrow_forwardIndicate how to obtain 2-metilbencimidazol from 1,2-diaminobenzene.arrow_forwardbreak down both reactions shown and explain it correctly using the bromonium ion mechanism, instead of the (disproven) carbocation-based mechanism.arrow_forward
- Indicate how from 1,2-diaminobenzene to obtain 1-metilbenzotriazol.arrow_forward-C = C - C - + Br₂ + I" -> -C-C-c -C = C -C- + Br² + I₂ -C=C Br I + Brū + Iz -7- C - C-C- I Br Mechanism; - C = c - c - + Br - Br > - C-c-c- Br -C-C-C- + 1 - - -Ċ-Ċ'-c' - Br Br Iarrow_forwardWrite the mechanism of the esterification reaction (please show the mechanism included line pairs and arrows)arrow_forward
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