ORGANIC CHEMISTRY-ACCESS
ORGANIC CHEMISTRY-ACCESS
6th Edition
ISBN: 9781260475586
Author: SMITH
Publisher: MCG
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Chapter 28.6, Problem 19P
Interpretation Introduction

(a)

Interpretation: The structure of prepolymer A formed from 1,4-dihydroxybenzene and excess epichlorohydrin is to be stated.

Concept introduction: Epoxides are strained three-membered rings. They undergo anionic polymerization to afford the ring opening, by following the SN2 pathway. The ring opening in an unsymmetrical epoxide takes place at the less substituted or the more accessible carbon atom.

Interpretation Introduction

(b)

Interpretation: The structure of cross-linked polymer B formed from the treatment of A with H2NCH2CH2CH2NH2 is to be stated.

Concept introduction: Epoxides are strained three-membered rings. They undergo anionic polymerization to afford the ring opening, by following the SN2 pathway. The ring opening in an unsymmetrical epoxide takes place at the less substituted or the more accessible carbon atom.

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