EBK CHEMICAL PRINCIPLES IN THE LABORATO
EBK CHEMICAL PRINCIPLES IN THE LABORATO
11th Edition
ISBN: 9781305446366
Author: SLOWINSKI
Publisher: YUZU
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Chapter 28, Problem 3ASA

A 100-mL sample of hard water is titrated with the EDTA solution in Problem 2. The same amount of Mg2+ is added as previously, and the volume of EDTA required is 31.84 mL.

a. What volume of EDTA is used in titrating the Ca2+ in the hard water? _____________mL

b. How many moles of EDTA are there in that volume? _____________ moles

c. How many moles of Ca2+ are there in the 100 mL of water? _____________ moles

d. If the Ca2+ comes from CaCO3, how many moles of CaCO3 are there in one liter of the water? How many grams of CaCO3 are present per liter of the water? _____________ mol / L _____________ g / L

e. If 1 ppm CaCO3 = 1 mg per liter, what is the water hardness in ppm CaCO3? _____________ ppm CaCO3

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(11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B Bond A Bond C a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest Bond Strongest Bond b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. c. (5pts) Use principles discussed in lecture, supported by relevant structures, to succinctly explain the why your part b (i) radical is more stable than your part b(ii) radical. Written explanation can be no more than one-two succinct sentence(s)!

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EBK CHEMICAL PRINCIPLES IN THE LABORATO

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