The structure of 2 -ketohexose is to be determined. Concept introduction: The aldehyde carbonyl group and ketone carbonyl group reduces to alcohol on reaction with NaBH 4 . The C = O group changes to C − OH on reduction.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 28, Problem 28.21P

Interpretation Introduction

Interpretation: The structure of 2-ketohexose is to be determined.

Concept introduction: The aldehyde carbonyl group and ketone carbonyl group reduces to alcohol on reaction with NaBH4. The C=O group changes to C−OH on reduction.

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You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products: xi 1. ☑ 2. H₂O хе i Draw the missing reagent X you think will make this synthesis work in the drawing area below. If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. There is no reagent that will make this synthesis work without complications. : ☐ S ☐

Predict the major products of this organic reaction: H OH 1. LiAlH4 2. H₂O ? Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. G C टे

For each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 CI MgCl ? Will the first product that forms in this reaction create a new CC bond? Yes No MgBr ? Will the first product that forms in this reaction create a new CC bond? Yes No G टे

Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 28, Problem 28.21P

Interpretation Introduction

Interpretation: The structure of 2-ketohexose is to be determined.

Concept introduction: The aldehyde carbonyl group and ketone carbonyl group reduces to alcohol on reaction with NaBH4. The C=O group changes to C−OH on reduction.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 28, Problem 28.21P

Interpretation Introduction

Interpretation: The structure of 2-ketohexose is to be determined.

Concept introduction: The aldehyde carbonyl group and ketone carbonyl group reduces to alcohol on reaction with NaBH4. The C=O group changes to C−OH on reduction.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 28, Problem 28.21P

Interpretation Introduction

Interpretation: The structure of 2-ketohexose is to be determined.

Concept introduction: The aldehyde carbonyl group and ketone carbonyl group reduces to alcohol on reaction with NaBH4. The C=O group changes to C−OH on reduction.

Expert Solution & Answer

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Answer 5

Chapter 28, Problem 28.21P

Interpretation Introduction

Interpretation: The structure of 2-ketohexose is to be determined.

Concept introduction: The aldehyde carbonyl group and ketone carbonyl group reduces to alcohol on reaction with NaBH4. The C=O group changes to C−OH on reduction.

Answer 6

Chapter 28, Problem 28.21P

Interpretation Introduction

Interpretation: The structure of 2-ketohexose is to be determined.

Concept introduction: The aldehyde carbonyl group and ketone carbonyl group reduces to alcohol on reaction with NaBH4. The C=O group changes to C−OH on reduction.

Answer 7

Chapter 28, Problem 28.21P

Interpretation Introduction

Interpretation: The structure of 2-ketohexose is to be determined.

Concept introduction: The aldehyde carbonyl group and ketone carbonyl group reduces to alcohol on reaction with NaBH4. The C=O group changes to C−OH on reduction.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 28 - Prob. 28.1P Ch. 28 - Prob. 28.2P Ch. 28 - Label each stereogenic center as R or S. a. b. c....Ch. 28 - Convert the ball-and-stick model to a Fischer...Ch. 28 - Prob. 28.5P Ch. 28 - Prob. 28.6P Ch. 28 - Prob. 28.7P Ch. 28 - Prob. 28.8P Ch. 28 - Prob. 28.9P Ch. 28 - Prob. 28.10P

The structure of 2 -ketohexose is to be determined. Concept introduction: The aldehyde carbonyl group and ketone carbonyl group reduces to alcohol on reaction with NaBH 4 . The C = O group changes to C − OH on reduction.

Solution Summary: The author explains that the structure of 2 -ketohexose is shown in Figure 2.

Concept explainers

Interpretation: The structure of 2-ketohexose is to be determined.

Concept introduction: The aldehyde carbonyl group and ketone carbonyl group reduces to alcohol on reaction with NaBH4. The C=O group changes to C−OH on reduction.

Want to see the full answer?

Chapter 28 Solutions

The structure of 2 -ketohexose is to be determined. Concept introduction: The aldehyde carbonyl group and ketone carbonyl group reduces to alcohol on reaction with NaBH 4 . The C = O group changes to C − OH on reduction.

Solution Summary: The author explains that the structure of 2 -ketohexose is shown in Figure 2.

Concept explainers

Interpretation: The structure of 2-ketohexose is to be determined. Concept introduction: The aldehyde carbonyl group and ketone carbonyl group reduces to alcohol on reaction with NaBH4. The C=O group changes to C−OH on reduction.

Want to see the full answer?

Chapter 28 Solutions

Interpretation: The structure of 2-ketohexose is to be determined.

Concept introduction: The aldehyde carbonyl group and ketone carbonyl group reduces to alcohol on reaction with NaBH4. The C=O group changes to C−OH on reduction.