CHEM 212:STUDENT SOLUTION MANUAL
8th Edition
ISBN: 9781260304473
Author: SILBERBERG
Publisher: MCGRAW-HILL CUSTOM PUBLISHING
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Chapter 2.8, Problem 2.17BFP
(a)
Interpretation Introduction
Interpretation:
The name, formula, and formula mass of the compound in the image are to be determined.
Concept introduction:
The formula of a compound is a representation which suggests the total number of atoms of each element the compound is made of.
The formula mass of a compound is defined as the sum of the atomic masses of atoms of all the elements present in it.
The general formula to calculate the formula mass of a compound is,
(b)
Interpretation Introduction
Interpretation:
The name, formula and molecular mass of the compound in the image are to be determined.
Concept introduction:
The molecular formula of a compound is a representation which suggests the total number of atoms of each element the compound is made of.
The molecular mass of a compound is defined as the sum of the atomic masses of atoms of all the elements present in it.
The general formula to calculate the molecular mass of a compound is,
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Students have asked these similar questions
On the next page is an LC separation of the parabens found in baby wash. Parabens are
suspected in a link to breast cancer therefore an accurate way to quantitate them is desired.
a. In the chromatogram, estimate k' for ethyl paraben. Clearly indicate what values you used for
all the terms in your calculation.
b. Is this a "good" value for a capacity factor? Explain.
c. What is the resolution between n-Propyl paraben and n-Butyl paraben? Again, indicate clearly
what values you used in your calculation.
MAU
| Methyl paraben
40
20
0
-2
Ethyl paraben n-Propyl paraben
n-Butyl paraben
App ID 22925
6
8
min
d. In Figure 4, each stationary phase shows some negative correlation between plate count
and retention factor. In other words, as k' increases, N decreases. Explain this relationship
between k' and N.
Plate Count (N)
4000
3500
2500
2000
1500
1000
Figure 4. Column efficiency (N) vs retention factor (k') for 22
nonionizable solutes on FMS (red), PGC (black), and COZ (green). 3000
Eluent compositions (acetonitrile/water, A/W) were adjusted to obtain
k' less than 15, which was achieved for most solutes as follows: FMS
(30/70 A/W), PGC (60/40), COZ (80/20). Slightly different
compositions were used for the most highly retained solutes. All
columns were 50 mm × 4.6 mm id and packed with 5 um particles,
except for COZ, which was packed with 3 um particles. All other
chromatographic conditions were constant: column length 5 cm,
column j.§. 4.6 mm, flow rate 2 mL/min, column temperature 40 °C,
and injection volume 0.5 μL
Log(k'x/K'ethylbenzene)
FMS
1.5
1.0
0.5
0.0
ཐྭ ཋ ཤྩ བྷྲ ;
500
0
5
10…
f. Predict how the van Deemter curve in Figure 7
would change if the temperature were raised
from 40 °C to 55 °C.
Figure 7. van Desmter curves in reduced coordinates for four
nitroalkane homologues (nitropropane, black; nitrobutane, red;
nitropentane, blue; and nitrohexane, green) separated on the FMS
phase. Chromatographic conditions: column dimensions 50 mm × 4.6
mm id, eluent 30/70 ACN/water, flow rates 0.2-5.0 mL/min, injection
volume 0.5 and column temperature 40 °C. No corrections to the
plate heights have been made to account for extracolumn dispersion.
Reduced Plate Height (h)
°
20
40
60
Reduced Velocity (v)
8. (2) A water sample is analyzed for traces of benzene using headspace analysis. The sample and
standard are spiked with a fixed amount of toluene as an internal standard. The following data are
obtained:
Ppb benzene
Peak area benzene
Peak area toluene
10.0
252
376
Sample
533
368
What is the concentration of benzene in the sample?
Chapter 2 Solutions
CHEM 212:STUDENT SOLUTION MANUAL
Ch. 2.1 - Does each of the following scenes best represent...Ch. 2.1 - Describe the following representation of a...Ch. 2.2 - The mineral “fool’s gold” does not contain any...Ch. 2.2 - Silver bromide is the light-sensitive compound...Ch. 2.3 - Prob. 2.3AFPCh. 2.3 - Prob. 2.3BFPCh. 2.5 - Titanium, the ninth most abundant element, is used...Ch. 2.5 - Prob. 2.4BFPCh. 2.5 - Prob. 2.5AFPCh. 2.5 - Boron (B; Z = 5) has two naturally occurring...
Ch. 2.5 - Prob. B2.1PCh. 2.5 - Prob. B2.2PCh. 2.6 - Prob. 2.6AFPCh. 2.6 - Prob. 2.6BFPCh. 2.7 - Prob. 2.7AFPCh. 2.7 - Prob. 2.7BFPCh. 2.8 - Prob. 2.8AFPCh. 2.8 - Prob. 2.8BFPCh. 2.8 - Prob. 2.9AFPCh. 2.8 - Prob. 2.9BFPCh. 2.8 - Prob. 2.10AFPCh. 2.8 - Prob. 2.10BFPCh. 2.8 - Prob. 2.11AFPCh. 2.8 - Prob. 2.11BFPCh. 2.8 - Prob. 2.12AFPCh. 2.8 - Prob. 2.12BFPCh. 2.8 - Prob. 2.13AFPCh. 2.8 - Prob. 2.13BFPCh. 2.8 - Prob. 2.14AFPCh. 2.8 - Prob. 2.14BFPCh. 2.8 - Prob. 2.15AFPCh. 2.8 - Prob. 2.15BFPCh. 2.8 - Prob. 2.16AFPCh. 2.8 - Prob. 2.16BFPCh. 2.8 - Determine the name, formula, and molecular (or...Ch. 2.8 - Prob. 2.17BFPCh. 2.9 - Prob. B2.3PCh. 2 - Prob. 2.1PCh. 2 - List two differences between a compound and a...Ch. 2 - Which of the following are pure substances?...Ch. 2 - Classify each substance in Problem 2.3 as an...Ch. 2 - Explain the following statement: The smallest...Ch. 2 - Prob. 2.6PCh. 2 - Can the relative amounts of the components of a...Ch. 2 - Prob. 2.8PCh. 2 - Prob. 2.9PCh. 2 - Prob. 2.10PCh. 2 - Prob. 2.11PCh. 2 - Prob. 2.12PCh. 2 - In our modern view of matter and energy, is the...Ch. 2 - Prob. 2.14PCh. 2 - Which of the following scenes illustrate(s) the...Ch. 2 - Prob. 2.16PCh. 2 - Prob. 2.17PCh. 2 - Prob. 2.18PCh. 2 - Prob. 2.19PCh. 2 - Fluorite, a mineral of calcium, is a compound of...Ch. 2 - Prob. 2.21PCh. 2 - Prob. 2.22PCh. 2 - Prob. 2.23PCh. 2 - Prob. 2.24PCh. 2 - Prob. 2.25PCh. 2 - Prob. 2.26PCh. 2 - Prob. 2.27PCh. 2 - Dolomite is a carbonate of magnesium and calcium....Ch. 2 - Prob. 2.29PCh. 2 - Which of Dalton’s postulates about atoms are...Ch. 2 - Use Dalton’s theory to explain why potassium...Ch. 2 - Prob. 2.32PCh. 2 - The following charges on individual oil droplets...Ch. 2 - Prob. 2.34PCh. 2 - When Rutherford’s coworkers bombarded gold foil...Ch. 2 - Prob. 2.36PCh. 2 - Prob. 2.37PCh. 2 - Prob. 2.38PCh. 2 - Prob. 2.39PCh. 2 - Prob. 2.40PCh. 2 - Prob. 2.41PCh. 2 - Prob. 2.42PCh. 2 - Write the notation for each atomic depiction:
Ch. 2 - Write the notation for each atomic depiction:
Ch. 2 - Draw atomic depictions similar to those in Problem...Ch. 2 - Prob. 2.46PCh. 2 - Prob. 2.47PCh. 2 - Prob. 2.48PCh. 2 - Chlorine has two naturally occurring isotopes,...Ch. 2 - Prob. 2.50PCh. 2 - Prob. 2.51PCh. 2 - Prob. 2.52PCh. 2 - Prob. 2.53PCh. 2 - Prob. 2.54PCh. 2 - Prob. 2.55PCh. 2 - Prob. 2.56PCh. 2 - Prob. 2.57PCh. 2 - Prob. 2.58PCh. 2 - Prob. 2.59PCh. 2 - Prob. 2.60PCh. 2 - Prob. 2.61PCh. 2 - Prob. 2.62PCh. 2 - Prob. 2.63PCh. 2 - Prob. 2.64PCh. 2 - Prob. 2.65PCh. 2 - Prob. 2.66PCh. 2 - Prob. 2.67PCh. 2 - Prob. 2.68PCh. 2 - Prob. 2.69PCh. 2 - Prob. 2.70PCh. 2 - What monatomic ions would you expect radium (Z =...Ch. 2 - Prob. 2.72PCh. 2 - Prob. 2.73PCh. 2 - Prob. 2.74PCh. 2 - Prob. 2.75PCh. 2 - The radii of the sodium and potassium ions are 102...Ch. 2 - Prob. 2.77PCh. 2 - What information about the relative numbers of...Ch. 2 - Prob. 2.79PCh. 2 - Prob. 2.80PCh. 2 - Prob. 2.81PCh. 2 - Prob. 2.82PCh. 2 - Prob. 2.83PCh. 2 - Prob. 2.84PCh. 2 - Prob. 2.85PCh. 2 - Prob. 2.86PCh. 2 - Prob. 2.87PCh. 2 - Prob. 2.88PCh. 2 - Give the systematic names for the formulas or the...Ch. 2 - Prob. 2.90PCh. 2 - Prob. 2.91PCh. 2 - Prob. 2.92PCh. 2 - Prob. 2.93PCh. 2 - Prob. 2.94PCh. 2 - Prob. 2.95PCh. 2 - Prob. 2.96PCh. 2 - Prob. 2.97PCh. 2 - Prob. 2.98PCh. 2 - Prob. 2.99PCh. 2 - Prob. 2.100PCh. 2 - Prob. 2.101PCh. 2 - Prob. 2.102PCh. 2 - Prob. 2.103PCh. 2 - Prob. 2.104PCh. 2 - Prob. 2.105PCh. 2 - Prob. 2.106PCh. 2 - Prob. 2.107PCh. 2 - Prob. 2.108PCh. 2 - Prob. 2.109PCh. 2 - Prob. 2.110PCh. 2 - Prob. 2.111PCh. 2 - Prob. 2.112PCh. 2 - What is the difference between a homogeneous and a...Ch. 2 - Prob. 2.114PCh. 2 - Prob. 2.115PCh. 2 - Prob. 2.116PCh. 2 - Which separation method is operating in each of...Ch. 2 - Prob. 2.118PCh. 2 - Prob. 2.119PCh. 2 - Prob. 2.120PCh. 2 - Prob. 2.121PCh. 2 - Prob. 2.122PCh. 2 - Ammonium dihydrogen phosphate, formed from the...Ch. 2 - Prob. 2.124PCh. 2 - Prob. 2.125PCh. 2 - Prob. 2.126PCh. 2 - Prob. 2.127PCh. 2 - Prob. 2.128PCh. 2 - The following scenes represent a mixture of two...Ch. 2 - Prob. 2.130PCh. 2 - Prob. 2.131PCh. 2 - Prob. 2.132PCh. 2 - Prob. 2.133PCh. 2 - Prob. 2.134PCh. 2 - Prob. 2.135PCh. 2 - Prob. 2.136PCh. 2 - Prob. 2.137PCh. 2 - Prob. 2.138PCh. 2 - Prob. 2.139PCh. 2 - Prob. 2.140PCh. 2 - Prob. 2.141PCh. 2 - Prob. 2.142PCh. 2 - Prob. 2.143PCh. 2 - Prob. 2.144P
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