a) NaH then CH 3 I Interpretation: The product formed when estradiol reacts with NaH and then with CH 3 I is to be given. Concept introduction: When treated with NaH and CH 3 I, The hydrogen of -OH group in alcohols and phenols is replaced by methyl group. To give: The product formed when estradiol reacts with NaH and then with CH 3 I.

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 27.SE, Problem 46AP

Interpretation Introduction

a) NaH then CH₃I

Interpretation:

The product formed when estradiol reacts with NaH and then with CH₃I is to be given.

Concept introduction:

When treated with NaH and CH₃I, The hydrogen of -OH group in alcohols and phenols is replaced by methyl group.

To give:

The product formed when estradiol reacts with NaH and then with CH₃I.

Interpretation Introduction

b) CH₃COCl, pyridine

Interpretation:

The product formed when estradiol reacts with CH₃COCl in pyridine is to be given.

Concept introduction:

When treated with CH₃COCl in pyridine, the hydrogen of -OH group in alcohols and phenols is replaced by acetyl group.

To give:

The product formed when estradiol reacts with CH₃COCl in pyridine.

Interpretation Introduction

c) Br₂, FeBr₃

Interpretation:

The product formed when estradiol reacts with Br₂, FeBr₃ to be given.

Concept introduction:

Phenols undergo electrophilic substitution reaction (bromination) when treated with Br₂, FeBr₃ in the ortho and para positions.

To give:

The product formed when estradiol reacts with Br₂, FeBr₃.

Interpretation Introduction

d) Dess-Martin periodinane

Interpretation:

The product formed when estradiol reacts with Dess-Martin periodinate is to be given.

Concept introduction:

Secondary alcohols are oxidized to ketones by Dess-Martin periodinate. Tertiary alcohols are not oxidized by Dess-Martin periodinate.

To give:

The product formed when estradiol reacts with Dess-Martin periodinate.

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If possible, replace an H atom on the a carbon of the molecule in the drawing area with a methyl group substituent, and replace an H atom on the ẞ carbon with a hydroxyl group substituent. If one of the substituents can't be added for any reason, just don't add it. If neither substituent can be added, check the box under the drawing area. en HO OH

Curved arrows are used to illustrate the flow of electrons. Use the reaction conditions provided and follow the curved arrows to draw the intermediate and product of this hydrohalogenation reaction. Include all lone pairs and charges as appropriate. Br Select to Draw 51°F Sunny esc F1 HBr Select to Draw 1,2-hydride shift Br Select to Draw Q Search F2 F3 F4 1 2 # # 3 DII L F5 F6 F tA $ % Λ

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 27.SE, Problem 46AP

Interpretation Introduction

a) NaH then CH₃I

Interpretation:

The product formed when estradiol reacts with NaH and then with CH₃I is to be given.

Concept introduction:

When treated with NaH and CH₃I, The hydrogen of -OH group in alcohols and phenols is replaced by methyl group.

To give:

The product formed when estradiol reacts with NaH and then with CH₃I.

Interpretation Introduction

b) CH₃COCl, pyridine

Interpretation:

The product formed when estradiol reacts with CH₃COCl in pyridine is to be given.

Concept introduction:

When treated with CH₃COCl in pyridine, the hydrogen of -OH group in alcohols and phenols is replaced by acetyl group.

To give:

The product formed when estradiol reacts with CH₃COCl in pyridine.

Interpretation Introduction

c) Br₂, FeBr₃

Interpretation:

The product formed when estradiol reacts with Br₂, FeBr₃ to be given.

Concept introduction:

Phenols undergo electrophilic substitution reaction (bromination) when treated with Br₂, FeBr₃ in the ortho and para positions.

To give:

The product formed when estradiol reacts with Br₂, FeBr₃.

Interpretation Introduction

d) Dess-Martin periodinane

Interpretation:

The product formed when estradiol reacts with Dess-Martin periodinate is to be given.

Concept introduction:

Secondary alcohols are oxidized to ketones by Dess-Martin periodinate. Tertiary alcohols are not oxidized by Dess-Martin periodinate.

To give:

The product formed when estradiol reacts with Dess-Martin periodinate.

Expert Solution & Answer

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 27.SE, Problem 46AP

Interpretation Introduction

a) NaH then CH₃I

Interpretation:

The product formed when estradiol reacts with NaH and then with CH₃I is to be given.

Concept introduction:

When treated with NaH and CH₃I, The hydrogen of -OH group in alcohols and phenols is replaced by methyl group.

To give:

The product formed when estradiol reacts with NaH and then with CH₃I.

Interpretation Introduction

b) CH₃COCl, pyridine

Interpretation:

The product formed when estradiol reacts with CH₃COCl in pyridine is to be given.

Concept introduction:

When treated with CH₃COCl in pyridine, the hydrogen of -OH group in alcohols and phenols is replaced by acetyl group.

To give:

The product formed when estradiol reacts with CH₃COCl in pyridine.

Interpretation Introduction

c) Br₂, FeBr₃

Interpretation:

The product formed when estradiol reacts with Br₂, FeBr₃ to be given.

Concept introduction:

Phenols undergo electrophilic substitution reaction (bromination) when treated with Br₂, FeBr₃ in the ortho and para positions.

To give:

The product formed when estradiol reacts with Br₂, FeBr₃.

Interpretation Introduction

d) Dess-Martin periodinane

Interpretation:

The product formed when estradiol reacts with Dess-Martin periodinate is to be given.

Concept introduction:

Secondary alcohols are oxidized to ketones by Dess-Martin periodinate. Tertiary alcohols are not oxidized by Dess-Martin periodinate.

To give:

The product formed when estradiol reacts with Dess-Martin periodinate.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 27.SE, Problem 46AP

Interpretation Introduction

a) NaH then CH₃I

Interpretation:

The product formed when estradiol reacts with NaH and then with CH₃I is to be given.

Concept introduction:

When treated with NaH and CH₃I, The hydrogen of -OH group in alcohols and phenols is replaced by methyl group.

To give:

The product formed when estradiol reacts with NaH and then with CH₃I.

Interpretation Introduction

b) CH₃COCl, pyridine

Interpretation:

The product formed when estradiol reacts with CH₃COCl in pyridine is to be given.

Concept introduction:

When treated with CH₃COCl in pyridine, the hydrogen of -OH group in alcohols and phenols is replaced by acetyl group.

To give:

The product formed when estradiol reacts with CH₃COCl in pyridine.

Interpretation Introduction

c) Br₂, FeBr₃

Interpretation:

The product formed when estradiol reacts with Br₂, FeBr₃ to be given.

Concept introduction:

Phenols undergo electrophilic substitution reaction (bromination) when treated with Br₂, FeBr₃ in the ortho and para positions.

To give:

The product formed when estradiol reacts with Br₂, FeBr₃.

Interpretation Introduction

d) Dess-Martin periodinane

Interpretation:

The product formed when estradiol reacts with Dess-Martin periodinate is to be given.

Concept introduction:

Secondary alcohols are oxidized to ketones by Dess-Martin periodinate. Tertiary alcohols are not oxidized by Dess-Martin periodinate.

To give:

The product formed when estradiol reacts with Dess-Martin periodinate.

Expert Solution & Answer

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See solution

Answer 5

Chapter 27.SE, Problem 46AP

Interpretation Introduction

a) NaH then CH₃I

Interpretation:

The product formed when estradiol reacts with NaH and then with CH₃I is to be given.

Concept introduction:

When treated with NaH and CH₃I, The hydrogen of -OH group in alcohols and phenols is replaced by methyl group.

To give:

The product formed when estradiol reacts with NaH and then with CH₃I.

Interpretation Introduction

b) CH₃COCl, pyridine

Interpretation:

The product formed when estradiol reacts with CH₃COCl in pyridine is to be given.

Concept introduction:

When treated with CH₃COCl in pyridine, the hydrogen of -OH group in alcohols and phenols is replaced by acetyl group.

To give:

The product formed when estradiol reacts with CH₃COCl in pyridine.

Interpretation Introduction

c) Br₂, FeBr₃

Interpretation:

The product formed when estradiol reacts with Br₂, FeBr₃ to be given.

Concept introduction:

Phenols undergo electrophilic substitution reaction (bromination) when treated with Br₂, FeBr₃ in the ortho and para positions.

To give:

The product formed when estradiol reacts with Br₂, FeBr₃.

Interpretation Introduction

d) Dess-Martin periodinane

Interpretation:

The product formed when estradiol reacts with Dess-Martin periodinate is to be given.

Concept introduction:

Secondary alcohols are oxidized to ketones by Dess-Martin periodinate. Tertiary alcohols are not oxidized by Dess-Martin periodinate.

To give:

The product formed when estradiol reacts with Dess-Martin periodinate.

Answer 6

Chapter 27.SE, Problem 46AP

Interpretation Introduction

a) NaH then CH₃I

Interpretation:

The product formed when estradiol reacts with NaH and then with CH₃I is to be given.

Concept introduction:

When treated with NaH and CH₃I, The hydrogen of -OH group in alcohols and phenols is replaced by methyl group.

To give:

The product formed when estradiol reacts with NaH and then with CH₃I.

Answer 7

Chapter 27.SE, Problem 46AP

Interpretation Introduction

a) NaH then CH₃I

Interpretation:

The product formed when estradiol reacts with NaH and then with CH₃I is to be given.

Concept introduction:

When treated with NaH and CH₃I, The hydrogen of -OH group in alcohols and phenols is replaced by methyl group.

To give:

The product formed when estradiol reacts with NaH and then with CH₃I.

Answer 8

Interpretation Introduction

b) CH₃COCl, pyridine

Interpretation:

The product formed when estradiol reacts with CH₃COCl in pyridine is to be given.

Concept introduction:

When treated with CH₃COCl in pyridine, the hydrogen of -OH group in alcohols and phenols is replaced by acetyl group.

To give:

The product formed when estradiol reacts with CH₃COCl in pyridine.

Answer 9

Interpretation Introduction

b) CH₃COCl, pyridine

Interpretation:

The product formed when estradiol reacts with CH₃COCl in pyridine is to be given.

Concept introduction:

When treated with CH₃COCl in pyridine, the hydrogen of -OH group in alcohols and phenols is replaced by acetyl group.

To give:

The product formed when estradiol reacts with CH₃COCl in pyridine.

Answer 10

Interpretation Introduction

c) Br₂, FeBr₃

Interpretation:

The product formed when estradiol reacts with Br₂, FeBr₃ to be given.

Concept introduction:

Phenols undergo electrophilic substitution reaction (bromination) when treated with Br₂, FeBr₃ in the ortho and para positions.

To give:

The product formed when estradiol reacts with Br₂, FeBr₃.

Answer 11

Interpretation Introduction

c) Br₂, FeBr₃

Interpretation:

The product formed when estradiol reacts with Br₂, FeBr₃ to be given.

Concept introduction:

Phenols undergo electrophilic substitution reaction (bromination) when treated with Br₂, FeBr₃ in the ortho and para positions.

To give:

The product formed when estradiol reacts with Br₂, FeBr₃.

Answer 12

Interpretation Introduction

d) Dess-Martin periodinane

Interpretation:

The product formed when estradiol reacts with Dess-Martin periodinate is to be given.

Concept introduction:

Secondary alcohols are oxidized to ketones by Dess-Martin periodinate. Tertiary alcohols are not oxidized by Dess-Martin periodinate.

To give:

The product formed when estradiol reacts with Dess-Martin periodinate.

Answer 13

Interpretation Introduction

d) Dess-Martin periodinane

Interpretation:

The product formed when estradiol reacts with Dess-Martin periodinate is to be given.

Concept introduction:

Secondary alcohols are oxidized to ketones by Dess-Martin periodinate. Tertiary alcohols are not oxidized by Dess-Martin periodinate.

To give:

The product formed when estradiol reacts with Dess-Martin periodinate.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 27.1 - Carnauba wax, used in floor and furniture...Ch. 27.1 - Draw structures of glyceryl tripalmitate and...Ch. 27.2 - Prob. 3P Ch. 27.2 - Write the saponication reaction of glyceryl...Ch. 27.4 - Prob. 5P Ch. 27.5 - Prob. 6P Ch. 27.5 - Prob. 7P Ch. 27.6 - Draw the following molecules in chair...Ch. 27.6 - Lithocholic acid is an Aâ€“B cis steroid found in...Ch. 27.7 - Prob. 10P

Solution Summary: The author explains the product formed when estradiol reacts with NaH and then with CH 3 I.

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