ORGANIC CHEMISTRY
6th Edition
ISBN: 9781266633973
Author: SMITH
Publisher: MCG
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Chapter 27.3, Problem 10P
Interpretation Introduction
Interpretation: Among the given
Concept Introduction: Racemic mixture is a mixture of enantiomers in equal amounts. It is optically inactive. Racemic mixture can be resolved by the treatment of enantiomers with chiral reagent. Enantiomers have different chemical properties in chiral environment.
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why are peptide amide bonds exist either as s-cis or s-trans conformation?
A) Both conformations have the large groups anti to each other
B) There is partial double bond character between C and N.
C) There is H-bonding between O and N.
D) The side chains does not affect the conformation
E) None of the above
Cyclic amides are called which of the following?
a. lactams b. lactanes c. lactones d. lactines
name the following amines as primary, secondary,tertiary or quaternary
Chapter 27 Solutions
ORGANIC CHEMISTRY
Ch. 27.1 - Prob. 1PCh. 27.1 - Problem 29.2
What form exists at the isoelectric...Ch. 27.1 - Problem 29.3
Explain why the of the group of an...Ch. 27.1 - Prob. 4PCh. 27.2 - Problem 29.5
What -halo carbonyl compound is...Ch. 27.2 - Problem 29.6
The enolate derived from diethyl...Ch. 27.2 - Problem 29.7
What amino acid is formed when is...Ch. 27.2 - Problem 29.8
What aldehyde is needed to synthesize...Ch. 27.2 - Problem 29.9
Draw the products of each...Ch. 27.3 - Prob. 10P
Ch. 27.3 - Prob. 11PCh. 27.3 - Prob. 12PCh. 27.4 - Problem 29.13
What alkene is needed to synthesize...Ch. 27.5 - Problem 29.14
Draw the structure of each peptide....Ch. 27.5 - Problem 29.15
Name each peptide using both the...Ch. 27 - Draw the product formed when the following amino...Ch. 27 - With reference to the following peptide: a...Ch. 27 - Prob. 31PCh. 27 - Histidine is classified as a basic amino acid...Ch. 27 - Tryptophan is not classified as a basic amino acid...Ch. 27 - What is the structure of each amino acid at its...Ch. 27 - What is the predominant form of each of the...Ch. 27 - 29.37 What is the predominant form of each of the...Ch. 27 - a. Draw the structure of the tripeptide A–A–A, and...Ch. 27 - 29.39 Draw the organic products formed in each...Ch. 27 - 29.40 What alkyl halide is needed to synthesize...Ch. 27 - Prob. 50PCh. 27 - Draw the structure for each peptide: (a) Phe–Ala;...Ch. 27 - 29.52 For the tetrapeptide Asp–Arg–Val–Tyr:
a....Ch. 27 - Prob. 53PCh. 27 - Prob. 54PCh. 27 - 29.55 Draw the amino acids and peptide fragments...Ch. 27 - Prob. 56PCh. 27 - Prob. 57PCh. 27 - Prob. 58PCh. 27 - 29.59 An octapeptide contains the following amino...Ch. 27 - 29.60 Draw the organic products formed in each...Ch. 27 - 29.65 Draw the mechanism for the reaction that...Ch. 27 - 29.66 Which of the following amino acids are...Ch. 27 - 29.67 After the peptide chain of collagen has been...Ch. 27 - Prob. 68PCh. 27 - Prob. 69PCh. 27 - 29.70 The anti-obesity drug orlistat works by...Ch. 27 - Prob. 71P
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- What special role does the amino acid cysteine have in the peptides vasopressin and oxytocin?arrow_forwardWhich of the following are true concerning the chemical bond that forms between the carboxyl (RCOOH) group of one amino acid and the amino (RCNH2) group of another? a.The bond is called a peptide bond. b.It is formed by inserting a water molecule between them. c.It is formed by a dehydration reaction. d.A polypeptide has more of these bonds than a protein.arrow_forwardGive each of the following amines an IUPAC name. a. b. c.arrow_forward
- a. which amino acid can form an N-linked bond with any carbohydrate b. which amino acid would most likely be found at a rigid turn in a protein structure?arrow_forward1arrow_forwardexplain the solubility behavior of each representatives amine in water a. aniline b. diethylamine c. N,N-diethylanilinearrow_forward
- The hydrolysis of an amide in acidic conditions forms A. a carboxylate salt and an alcohol B. a carboxylate salt and an amine C. an alcohol and an amine salt (an ammonium ion) D. a carboxylic acid and an amine salt (an ammonium ion)arrow_forwardIs it possible for primary and secondary amines to act as very weak acids? Explain.arrow_forwardA. 2,4-dihydroxybenzaldehyde reacts with ethylamine to form an imine. B. 2,4-dihydroxybenzaldehyde reacts with ethanamide to form an ester. Are the statements True?arrow_forward
- 5.) Name the following amines (a. and b.) and draw the structural formula(c.). c.) Cyclopentanamine a.) b.) NH2 NH 2 Нзс— сн — сH 2— сн 3arrow_forwardWhy are tertiary amines not soluble in water? O a. Primary amine cannot hydrogen bond with water. O b. Amines are non polar compounds. O c. Tertiary amine cannot hydrogen bond with water O d. Secondary amine cannot hydrogen bond with water. Clear my choicearrow_forwardTertiary Amides can be formed from carboxylic acid v and tertiary amine v compounds at 100°C temperature. A Moving to the next question prevents changes to this answer. Question 17 of 20 9 ENG112 RESEAR..pdt Show All 31arrow_forward
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