ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL
8th Edition
ISBN: 9780134595450
Author: Bruice
Publisher: PEARSON
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Question
Chapter 27.13, Problem 23P
(a)
Interpretation Introduction
Interpretation:
The short segment of polymer of 3-hydroxybutyric acid (PHB) has to be drawn.
Concept introduction:
Monomers combine together to form polymers. Monomers are the repeating units of small molecules which link together to form polymers and the process is called as
Two types of polymers:
- Synthetic and biopolymers.
- DNA is an example for biopolymer and these type of polymers are synthesized by cells.
- Polymers synthesized by scientists are called
synthetic polymers and some examples are nylon, polyester etc.
Two types of synthetic polymers:
- Chain-growth
polymers or addition polymers and Step-growthpolymers or Condensation polymers. - Chain growth polymers are formed by the monomer addition to the end of a growing chain.
- Step-growth polymers are formed by combining monomers by removing small molecules of water or alcohol.
(b)
Interpretation Introduction
Interpretation:
The short segment of polymer biopol (PHBV) with alternating monomers has to be drawn.
Concept introduction:
Polymers:
Monomers combine together to form polymers. Monomers are the repeating units of small molecules which link together to form polymers and the process is called as polymerization.
Two types of polymers:
- Synthetic and biopolymers.
- DNA is an example for biopolymer and these type of polymers are synthesized by cells.
- Polymers synthesized by scientists are called synthetic polymers and some examples are nylon, polyester etc.
Two types of synthetic polymers:
- Chain-growth polymers or addition polymers and Step-growth polymers or Condensation polymers.
- Chain growth polymers are formed by the monomer addition to the end of a growing chain.
- Step-growth polymers are formed by combining monomers by removing small molecules of water or alcohol.
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Chapter 27 Solutions
ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL
Ch. 27.3 - Prob. 1PCh. 27.3 - Prob. 2PCh. 27.3 - Prob. 3PCh. 27.3 - Prob. 4PCh. 27.3 - Prob. 5PCh. 27.3 - Prob. 6PCh. 27.4 - Prob. 7PCh. 27.5 - Rank the following groups of monomers from most...Ch. 27.5 - Why does methyl methacrylate not undergo cationic...Ch. 27.6 - Prob. 10P
Ch. 27.6 - Explain why, when propylene oxide undergoes...Ch. 27.6 - Which monomer and which type of initiator can you...Ch. 27.6 - Prob. 13PCh. 27.8 - Draw a short segment of gutta-percha.Ch. 27.8 - Prob. 15PCh. 27.11 - Prob. 16PCh. 27.11 - Write an equation that explains what happens if a...Ch. 27.11 - What happens to polyester slacks if aqueous NaOH...Ch. 27.11 - a. Propose a mechanism for the formation of the...Ch. 27.11 - Explain why, when a small amount of glycerol is...Ch. 27.12 - Propose a mechanism for the formation of melmac.Ch. 27.12 - Prob. 22PCh. 27.13 - Prob. 23PCh. 27 - Draw short segments of the polymers obtained from...Ch. 27 - Prob. 25PCh. 27 - Prob. 26PCh. 27 - Draw the structure of the monomer or monomers used...Ch. 27 - Prob. 28PCh. 27 - Draw short segments of the polymers obtained from...Ch. 27 - Quiana is a synthetic fabric that feels very much...Ch. 27 - Prob. 31PCh. 27 - Prob. 32PCh. 27 - Prob. 33PCh. 27 - Poly(vinyl alcohol) is a polymer used to make...Ch. 27 - Five different repeating units are found in the...Ch. 27 - Prob. 37PCh. 27 - A particularly strong and rigid polyester used for...Ch. 27 - Prob. 39PCh. 27 - Which Monomer gives a greater yield of polymer,...Ch. 27 - Prob. 41PCh. 27 - Prob. 42PCh. 27 - Why do vinyl raincoats become brittle as they get...Ch. 27 - The polymer shown below is synthesized by...Ch. 27 - Prob. 45PCh. 27 - How can head-to-head poly(vinyl bromide) be...Ch. 27 - Delrin (polyoxymethylene) is a tough...
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- The velocity distribution function of gas moleculesa) is used to measure their velocity, since the small size of gas molecules means that it cannot be measured in any other wayb) is only used to describe the velocity of particles if their density is very high.c) describes the probability that a gas particle has a velocity in a given interval of velocitiesarrow_forwardExplain why in the representation of a one-dimensional velocity distribution function for a particular gas, the maximum occurs for vi = 0 m/s.arrow_forwardExplain why the representation of a one-dimensional velocity distribution function for a particular gas becomes flatter as the temperature increases.arrow_forward
- Draw a Lewis structure for each of the following molecules and assign charges where appropriate. The order in which the atoms are connected is given in parentheses. a. CIFCIF b. BrCNBrCN 0 c. SOCI2 × (CISCIO) SOC₁₂ (CISCI) You can draw both an octet and a valence shell expanded structure. Considering the following structural information, which is the better one: The measured S-OS-O bond length in SOC12SOCl2 is 1.43 Å. For comparison, that in SO2SO2 is 1.43 Å [Exercise 1-9, part (b)], that in CHзSOHCH3 SOH d. CH3NH2CH3NH2 (methanesulfenic acid) is 1.66 A. e. CH3OCH3 CH3 OCH3 NH2 f. N2H2× (HNNH) N2 H2 (HNNH) g. CH2COCH₂ CO h. HN3× (HNNN) HN3 (HNNN) i. N20 × (NNO) N2O (NNO)arrow_forwardbre The reaction sequence shown in Scheme 5 demonstrates the synthesis of a substituted benzene derivative Q. wolsd works 2 NH2 NaNO2, HCI (apexe) 13× (1 HNO3, H2SO4 C6H5CIN2 0°C HOTE CHINO₂ N O *O₂H ( PO Q Я Scheme 5 2 bag abouoqmics to sounde odi WEIC (i) Draw the structure of intermediate O. [2 marks] to noitsmot od: tot meinedogm, noit so oft listsb ni zaupaib bas wa (ii) Draw the mechanism for the transformation of aniline N to intermediate O. Spoilage (b) [6 marks] (iii) Identify the reagent X used to convert compound O to the iodinated compound [tom E P. vueimado oilovonsa ni moitos nolisbnolov ayd toes ai tedw nisiqx (iv) Identify the possible structures of compound Q. [2 marks] [2 marks] [shom 2] (v) bus noires goiribbeolovo xnivollot adj to subora sidab Draw the mechanism for the transformation of intermediate P to compound Q. [5 marks] vi (vi) Account for the regiochemical outcome observed in the reaction forming compound Q. [3 marks]arrow_forwardPROBLEM 4 Solved Show how 1-butanol can be converted into the following compounds: a. PROBLEM 5+ b. d. -C= Narrow_forward
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