Monomers required for the given polymer to be prepared need to be identified. Concept introduction: Polymers can be distinguished based on the functional group it has in the structure. The monomer considered for forming the polymer determines the functional group in the polymer. Few examples are, Acid +alcohol=polyester Acid+ amine =polyamide Alcohol+phosgene=polycarbonate Alcohol+isocyanate=polycarbamate Aldehyde = polyether To draw : To draw the structure of monomers required for preparation of given polymer.

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Answer 1

Question

Chapter 27, Problem 42PP

(a)

Interpretation Introduction

Interpretation:

Monomers required for the given polymer to be prepared need to be identified.

Concept introduction:

Polymers can be distinguished based on the functional group it has in the structure. The monomer considered for forming the polymer determines the functional group in the polymer. Few examples are,

Acid +alcohol=polyester

Acid+amine=polyamide

Alcohol+phosgene=polycarbonate

Alcohol+isocyanate=polycarbamate

Aldehyde= polyether

To draw : To draw the structure of monomers required for preparation of given polymer.

(b)

Interpretation Introduction

Concept introduction:

Polymers can be classified as chain-growth and step-growth polymers. Chain-growth polymers are the one which are formed when monomer is added to the other monomer growing chain one at a time. This growing polymer chain usually has only one reactive site. This site is called growth point. Step-growth polymers are the one when the monomers react with each other to form oligomers. These oligomers are joined together to form polymers. This usually occurs when difunctional monomers are used. This has got two growth points.

(c)

Interpretation Introduction

Concept introduction:

Polymers can be classified as addition polymer and condensation polymer. Addition polymers are the one which are formed without the loss of any small molecules. Usually compounds with vinylic bonds involve in addition polymerization. Condensation polymers are the one which are formed with the loss of small molecules such as water, ammonia etc.

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#1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un- cyclize. Undo the ring into all possible molecules. (2pts, no partial credit) hv

Don't used Ai solution

I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."

Answer 2

Question

Chapter 27, Problem 42PP

(a)

Interpretation Introduction

Interpretation:

Monomers required for the given polymer to be prepared need to be identified.

Concept introduction:

Polymers can be distinguished based on the functional group it has in the structure. The monomer considered for forming the polymer determines the functional group in the polymer. Few examples are,

Acid +alcohol=polyester

Acid+amine=polyamide

Alcohol+phosgene=polycarbonate

Alcohol+isocyanate=polycarbamate

Aldehyde= polyether

To draw : To draw the structure of monomers required for preparation of given polymer.

(b)

Interpretation Introduction

Concept introduction:

Polymers can be classified as chain-growth and step-growth polymers. Chain-growth polymers are the one which are formed when monomer is added to the other monomer growing chain one at a time. This growing polymer chain usually has only one reactive site. This site is called growth point. Step-growth polymers are the one when the monomers react with each other to form oligomers. These oligomers are joined together to form polymers. This usually occurs when difunctional monomers are used. This has got two growth points.

(c)

Interpretation Introduction

Concept introduction:

Polymers can be classified as addition polymer and condensation polymer. Addition polymers are the one which are formed without the loss of any small molecules. Usually compounds with vinylic bonds involve in addition polymerization. Condensation polymers are the one which are formed with the loss of small molecules such as water, ammonia etc.

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Answer 3

Question

Chapter 27, Problem 42PP

(a)

Interpretation Introduction

Interpretation:

Monomers required for the given polymer to be prepared need to be identified.

Concept introduction:

Polymers can be distinguished based on the functional group it has in the structure. The monomer considered for forming the polymer determines the functional group in the polymer. Few examples are,

Acid +alcohol=polyester

Acid+amine=polyamide

Alcohol+phosgene=polycarbonate

Alcohol+isocyanate=polycarbamate

Aldehyde= polyether

To draw : To draw the structure of monomers required for preparation of given polymer.

(b)

Interpretation Introduction

Concept introduction:

Polymers can be classified as chain-growth and step-growth polymers. Chain-growth polymers are the one which are formed when monomer is added to the other monomer growing chain one at a time. This growing polymer chain usually has only one reactive site. This site is called growth point. Step-growth polymers are the one when the monomers react with each other to form oligomers. These oligomers are joined together to form polymers. This usually occurs when difunctional monomers are used. This has got two growth points.

(c)

Interpretation Introduction

Concept introduction:

Polymers can be classified as addition polymer and condensation polymer. Addition polymers are the one which are formed without the loss of any small molecules. Usually compounds with vinylic bonds involve in addition polymerization. Condensation polymers are the one which are formed with the loss of small molecules such as water, ammonia etc.

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Answer 4

Question

Chapter 27, Problem 42PP

(a)

Interpretation Introduction

Interpretation:

Monomers required for the given polymer to be prepared need to be identified.

Concept introduction:

Polymers can be distinguished based on the functional group it has in the structure. The monomer considered for forming the polymer determines the functional group in the polymer. Few examples are,

Acid +alcohol=polyester

Acid+amine=polyamide

Alcohol+phosgene=polycarbonate

Alcohol+isocyanate=polycarbamate

Aldehyde= polyether

To draw : To draw the structure of monomers required for preparation of given polymer.

(b)

Interpretation Introduction

Concept introduction:

Polymers can be classified as chain-growth and step-growth polymers. Chain-growth polymers are the one which are formed when monomer is added to the other monomer growing chain one at a time. This growing polymer chain usually has only one reactive site. This site is called growth point. Step-growth polymers are the one when the monomers react with each other to form oligomers. These oligomers are joined together to form polymers. This usually occurs when difunctional monomers are used. This has got two growth points.

(c)

Interpretation Introduction

Concept introduction:

Polymers can be classified as addition polymer and condensation polymer. Addition polymers are the one which are formed without the loss of any small molecules. Usually compounds with vinylic bonds involve in addition polymerization. Condensation polymers are the one which are formed with the loss of small molecules such as water, ammonia etc.

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Answer 5

Chapter 27, Problem 42PP

(a)

Interpretation Introduction

Interpretation:

Monomers required for the given polymer to be prepared need to be identified.

Concept introduction:

Polymers can be distinguished based on the functional group it has in the structure. The monomer considered for forming the polymer determines the functional group in the polymer. Few examples are,

Acid +alcohol=polyester

Acid+amine=polyamide

Alcohol+phosgene=polycarbonate

Alcohol+isocyanate=polycarbamate

Aldehyde= polyether

To draw : To draw the structure of monomers required for preparation of given polymer.

(b)

Interpretation Introduction

Concept introduction:

Polymers can be classified as chain-growth and step-growth polymers. Chain-growth polymers are the one which are formed when monomer is added to the other monomer growing chain one at a time. This growing polymer chain usually has only one reactive site. This site is called growth point. Step-growth polymers are the one when the monomers react with each other to form oligomers. These oligomers are joined together to form polymers. This usually occurs when difunctional monomers are used. This has got two growth points.

(c)

Interpretation Introduction

Concept introduction:

Polymers can be classified as addition polymer and condensation polymer. Addition polymers are the one which are formed without the loss of any small molecules. Usually compounds with vinylic bonds involve in addition polymerization. Condensation polymers are the one which are formed with the loss of small molecules such as water, ammonia etc.

Answer 6

Chapter 27, Problem 42PP

(a)

Interpretation Introduction

Interpretation:

Monomers required for the given polymer to be prepared need to be identified.

Concept introduction:

Polymers can be distinguished based on the functional group it has in the structure. The monomer considered for forming the polymer determines the functional group in the polymer. Few examples are,

Acid +alcohol=polyester

Acid+amine=polyamide

Alcohol+phosgene=polycarbonate

Alcohol+isocyanate=polycarbamate

Aldehyde= polyether

To draw : To draw the structure of monomers required for preparation of given polymer.

Answer 7

Chapter 27, Problem 42PP

(a)

Interpretation Introduction

Interpretation:

Monomers required for the given polymer to be prepared need to be identified.

Concept introduction:

Polymers can be distinguished based on the functional group it has in the structure. The monomer considered for forming the polymer determines the functional group in the polymer. Few examples are,

Acid +alcohol=polyester

Acid+amine=polyamide

Alcohol+phosgene=polycarbonate

Alcohol+isocyanate=polycarbamate

Aldehyde= polyether

To draw : To draw the structure of monomers required for preparation of given polymer.

Answer 8

(b)

Interpretation Introduction

Concept introduction:

Polymers can be classified as chain-growth and step-growth polymers. Chain-growth polymers are the one which are formed when monomer is added to the other monomer growing chain one at a time. This growing polymer chain usually has only one reactive site. This site is called growth point. Step-growth polymers are the one when the monomers react with each other to form oligomers. These oligomers are joined together to form polymers. This usually occurs when difunctional monomers are used. This has got two growth points.

Answer 9

(b)

Interpretation Introduction

Concept introduction:

Polymers can be classified as chain-growth and step-growth polymers. Chain-growth polymers are the one which are formed when monomer is added to the other monomer growing chain one at a time. This growing polymer chain usually has only one reactive site. This site is called growth point. Step-growth polymers are the one when the monomers react with each other to form oligomers. These oligomers are joined together to form polymers. This usually occurs when difunctional monomers are used. This has got two growth points.

Answer 10

(c)

Interpretation Introduction

Concept introduction:

Polymers can be classified as addition polymer and condensation polymer. Addition polymers are the one which are formed without the loss of any small molecules. Usually compounds with vinylic bonds involve in addition polymerization. Condensation polymers are the one which are formed with the loss of small molecules such as water, ammonia etc.

Answer 11

(c)

Interpretation Introduction

Concept introduction:

Polymers can be classified as addition polymer and condensation polymer. Addition polymers are the one which are formed without the loss of any small molecules. Usually compounds with vinylic bonds involve in addition polymerization. Condensation polymers are the one which are formed with the loss of small molecules such as water, ammonia etc.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 27.2 - Prob. 1CC Ch. 27.2 - Prob. 2CC Ch. 27.3 - Prob. 3CC Ch. 27.3 - Prob. 4CC Ch. 27.3 - Prob. 5CC Ch. 27.4 - Prob. 1LTS Ch. 27.4 - Prob. 6PTS Ch. 27.4 - Prob. 7ATS Ch. 27.4 - Prob. 8ATS Ch. 27.4 - Prob. 9ATS

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Chapter 27 Solutions